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Development of the advanced oxidation process using zeolite compounds as solid catalysts

Research Project

Project/Area Number 25410196
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionFukuoka Institute of Technology

Principal Investigator

Kitayama Mikito  福岡工業大学, 工学部, 教授 (10330945)

Co-Investigator(Renkei-kenkyūsha) OHTA YOSHIO  福岡工業大学, 工学部, 教授 (00140806)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2014: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2013: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords促進酸化処理 / オゾン / 排水処理 / 不均一触媒 / ゼオライト / 活性酸素 / 固体触媒 / 水処理 / 促進酸化処理法
Outline of Final Research Achievements

For the development of the advanced oxidation process (AOP) using zeolite compounds as solid catalysts, the evolution of active oxygen species by the catalytic decomposition of aqueous ozone was identified using the ESR-spin trapping method. It was confirmed that the hydrophilic zeolite was an effective catalyst for converting aqueous ozone into active oxygen species like hydroxyl radical or atomic oxygen. When applying the AOP using zeolite compounds as solid catalysts for the decomposition of humic acid, decolorization proceeded quickly, and the catalytic effect was clearly observed. However, complete decomposition, namely mineralization, was found to be sluggish, and the catalytic effect was much smaller than for the decolorization. It was confirmed that carboxylic acids formed through the decomposition of organic compound were the radical scavenger.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (9 results)

All 2015 2014 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 2 results) Presentation (7 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] 水中オゾン分解に対するイオン交換ゼオライトの触媒活性2014

    • Author(s)
      楠田愛、太田能生、北山幹人
    • Journal Title

      福岡工業大学環境科学研究所所報

      Volume: 8 Pages: 3-7

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 固体触媒としてゼオライトを用いた促進酸化処理に関する研究2014

    • Author(s)
      北山幹人、太田能生
    • Journal Title

      西日本腐食防食研究会例会会報

      Volume: 179 Pages: 11-12

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] ゼオライト触媒を用いた促進酸化処理法による水質浄化2015

    • Author(s)
      森永良樹, 原口絵美子, 太田 能生, 北山 幹人
    • Organizer
      第62回材料と環境討論会-腐食防食学会秋季全国大会
    • Place of Presentation
      福岡工業大学
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Advanced oxidation process using zeolite compounds as the inhomogeneous catalyst2015

    • Author(s)
      Mikito Kitayama and Yoshio Ohta
    • Organizer
      11th International Conference on Ceramic Materials and Components for Energy and Environmental Applications (CMCee)-ACerS
    • Place of Presentation
      Vancouver
    • Year and Date
      2015-06-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体触媒としてゼオライトを用いた促進酸化処理に関する研究2014

    • Author(s)
      北山幹人、太田能生
    • Organizer
      西日本腐食防食研究会
    • Place of Presentation
      九州工業大学
    • Year and Date
      2014-12-05
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン交換ゼオライトを用いた水中オゾン分解の特性

    • Author(s)
      楠田愛、北山幹人、太田能生
    • Organizer
      資源・素材学会九州支部平成25年度春季例会
    • Place of Presentation
      熊本大学(熊本県)
    • Related Report
      2013 Research-status Report
  • [Presentation] イオン交換ゼオライトの水中オゾン分解特性に関する研究

    • Author(s)
      楠田愛、太田能生、北山幹人、鈴木秀悦
    • Organizer
      日本素材物性学会年会
    • Place of Presentation
      秋田大学(秋田県)
    • Related Report
      2013 Research-status Report
  • [Presentation] 触媒としてゼオライトを用いる促進酸化処理法に関する研究

    • Author(s)
      楠田愛、北山幹人、太田能生
    • Organizer
      表面処理協会第128回講演大会
    • Place of Presentation
      福岡工業大学(福岡県)
    • Related Report
      2013 Research-status Report
  • [Presentation] Catalytic Activities of Zeolite for Decomposing Aqueous Ozone

    • Author(s)
      楠田愛、北山幹人、太田能生
    • Organizer
      The 7th International Conference on Materials Engineering for Resources
    • Place of Presentation
      秋田大学(秋田県)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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