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Zero-strain Li insertion materials for advanced lithium-ion batteries

Research Project

Project/Area Number 25410207
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy-related chemistry
Research InstitutionToyota Central R&D Lab., Inc.

Principal Investigator

MUKAI KAZUHIKO  株式会社豊田中央研究所, 戦略先端研究領域 機能性Si低次元材料プログラム, 主任研究員 (50394812)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsリチウムイオン電池 / リチウムチタン酸化物 / スピネル構造 / 負極活物質 / 結晶構造 / 電気化学反応 / 磁性 / 相転移 / Li導電率 / Liイオン電池 / インサーション材料 / エネルギー関連
Outline of Final Research Achievements

A series of lithium iron titanium oxides of Li1/2+1/2xFe5/2-3/2xTixO4 with 0 <= x <= 1.666 was prepared by a conventional solid-state reaction technique, and was examined as a negative electrode material for advanced lithium-ion batteries. Powder X-ray diffraction measurements and Raman spectroscopy clarified that the crystal structure of Li1/2+1/2xFe5/2-3/2xTixO4 is divided as two regions; the region at x <= 1 with cation order between Li and Fe ions and the region at x > 1 with cation order between Li and Ti ions. Structural and electrochemical studies were also performed for Li[Ni1/2Mn3/2]O4 and LiCo1-xNixO2, which are suitable as a positive electrode material for lithium-ion batteries using the Li1/2+1/2xFe5/2-3/2xTixO4 materials.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (23 results)

All 2015 2014 2013

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (14 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] Magnetic anomalies and itinerant character of electrochemically Li-inserted Li[Li1/3Ti5/3]O42015

    • Author(s)
      Kazuhiko Mukai and Jun Sugiyama
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 17 Issue: 35 Pages: 22652-22658

    • DOI

      10.1039/c5cp02999f

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Relevance between the bulk density and Li+-ion conductivity in a porous electrolyte: The case of Li[Li1/3Ti5/3]O42015

    • Author(s)
      Kazuhiko Mukai, Naoyoshi Nunotani, and Ryuta Moriyasu
    • Journal Title

      ACS Applied Materials & Interfacs

      Volume: 7 Issue: 36 Pages: 20314-20321

    • DOI

      10.1021/acsami.5b05952

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Role of Oxide Ions in Thermally Activated Lithium Diffusion of Li[Li1/3Ti5/3]O4: X-ray Diffraction Measurements and Raman Spectroscopy2015

    • Author(s)
      Kazuhiko Mukai and Yuichi Kato
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 119 Issue: 19 Pages: 10273-10281

    • DOI

      10.1021/acs.jpcc.5b02179

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Factors Affecting the Volumetric Energy Density of Lithium-Ion Battery Materials: Particle Density Measurements and Cross-Sectional Observations of Layered LiCo1-xNixO2 with 0 <= x <= 12014

    • Author(s)
      Kazuhiko Mukai and Hideyuki Nakano
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 6 Issue: 13 Pages: 10583-10592

    • DOI

      10.1021/am502242z

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Spin fluctuations above 100 K in stoichiometric LiCoO22014

    • Author(s)
      Kazuhiko Mukai, Yoshifumi Aoki, Daniel Andreica, Alex Amato, Isao Watanabe, and Sean R. Giblin, and Jun Sugiyama
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 551 Pages: 012008-012008

    • DOI

      10.1088/1742-6596/551/1/012008

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Understanding the Zero-Strain Lithium Insertion Scheme of Li[Li1/3Ti5/3]O4: Structural Changes at Atomic Scale Clarified by Raman Spectroscopy2014

    • Author(s)
      Kazuhiko Mukai, Yuichi Kato, and Hideyuki Nakano
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 118 Issue: 6 Pages: 2992-2999

    • DOI

      10.1021/jp412196v

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermally activated spin fluctuations in stoichiometric LiCoO2 clarified by electron paramagnetic resonance and muon-spin rotation and relaxation measurements2014

    • Author(s)
      Kazuhiko Mukai, Yoshifumi Aoki, Daniel Andreica, Alex Amato, Isao Watanabe, Sean R. Giblin, and Jun Sugiyama
    • Journal Title

      Physical Review B

      Volume: 89 Issue: 9

    • DOI

      10.1103/physrevb.89.094406

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] The gradient distribution of Ni ions in cation-disordered Li[Ni1/2Mn3/2]O4 clarified by muon-spin rotation and relaxation (muSR)2013

    • Author(s)
      Kazuhiko Mukai, Yutaka Ikedo, Kazuya Kamazawa, Jess H. Brewer, Eduardo J. Ansaldo, Kim H. Chow, Martin Mansson and Jun Sugiyama
    • Journal Title

      RSC Advances

      Volume: 3 Issue: 29 Pages: 11634-11639

    • DOI

      10.1039/c3ra40878g

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Phase Transition from Rhombohedral (R-3m) to monoclinic (C2/m) Symmetry in Lithium Overstoichiometric Li1+\deltaCo1+\deltaO2-\delta2013

    • Author(s)
      Kazuhiko Mukai, Yoshihiro Kishida, Hiroshi Nozaki, and Kazuhiko Dohmae
    • Journal Title

      Chemistry of Materials

      Volume: 25 Issue: 14 Pages: 2828-2837

    • DOI

      10.1021/cm4012348

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Towards high-volumetric energy density lithium-ion batteries: Particle density measurements of layered LiCo1-xNixO2 with 0 <= x <=x 12015

    • Author(s)
      Kazuhiko Mukai and Hideyuki Nakano
    • Organizer
      American Chemical Society他
    • Place of Presentation
      Hawaii Convention Center(ホノルル、ハワイ州、米国)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Li1+x[Li1/3Ti5/3]O4の帯磁率とその反応機構2015

    • Author(s)
      向和彦、杉山純
    • Organizer
      第41回固体イオニクス学会
    • Place of Presentation
      北海道大学(北海道、札幌)
    • Year and Date
      2015-11-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Li[Li1/3Ti5/3]O4における高速Li拡散に果たす酸化物イオンの役割2014

    • Author(s)
      向和彦、加藤雄一、布谷直義、中野秀之
    • Organizer
      第40回固体イオニクス討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2014-11-16 – 2014-11-18
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis and Crystal Structure of Lithium Iron Titanium Oxides Li1/2+1/2xFe5/2-3/2xTixO4 with 0 <= x <= 1.6662014

    • Author(s)
      Kazuhiko Mukai, Yuichi Kato, Kayo Horibuchi, and Hideyuki Nakano
    • Organizer
      226th Meeting of The Electrochemical Society
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-10-05 – 2014-10-09
    • Related Report
      2014 Research-status Report
  • [Presentation] リチウムイオン電池材料の体積エネルギー密度に関する考察 -LiCo1-xNixO2 (0 <= x <= 1)の粉体密度測定-2014

    • Author(s)
      向和彦、中野秀之
    • Organizer
      2014年電気化学会秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 高速Li拡散に果たす材料の“軟らかさ”及び酸化物イオンの役割2014

    • Author(s)
      向和彦、中野秀之、杉山純
    • Organizer
      固体イオニクスセミナー
    • Place of Presentation
      プラザホテル山麓荘
    • Year and Date
      2014-08-31 – 2014-09-02
    • Related Report
      2014 Research-status Report
  • [Presentation] 加速器を用いたリチウムイオン電池材料の評価2014

    • Author(s)
      向和彦
    • Organizer
      第10回放射光表面科学研究部会、第13回顕微ナノ材料科学研究会合同シンポジウム
    • Place of Presentation
      あいち産業科学技術総合センター
    • Year and Date
      2014-07-31 – 2014-08-01
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] リチウム鉄チタン酸化物Li1+1/2xFe5/2-3/2xTixO4(0 <= x <= 1.666)の結晶構造2014

    • Author(s)
      向和彦、堀渕嘉代、中野秀之
    • Organizer
      第52回セラミックス基礎科学討論会
    • Place of Presentation
      ウインク愛知(愛知県名古屋市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Raman spectroscopy on zero-strain lithium insertion material Li[Li1/3/Ti5/3]O4 during charge and discharge reaction2014

    • Author(s)
      Kazuhiko Mukai, Yuichi Kato, and Hideyuki Nakano
    • Organizer
      Electrochemical Conference on Energy & the Environment
    • Place of Presentation
      InterContinental Puxi, Shanghai (中華人民共和国上海)
    • Related Report
      2013 Research-status Report
  • [Presentation] ラマン測定からみた無歪みLiインサーション材料Li[Li1/3Ti5/3]O4の構造変化2014

    • Author(s)
      向和彦、加藤雄一、中野秀之
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Related Report
      2013 Research-status Report
  • [Presentation] 化学量論組成LiCoO2におけるゆらぎ磁性2013

    • Author(s)
      向和彦、青木良文、Daniel Andreica, Alex Amato, 渡邊功雄、Sean R. Giblin, 杉山純
    • Organizer
      電気化学会秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Research-status Report
  • [Presentation] X-ray Diffraction Measurements below Ambient Temperature on Over-stoichiometric LiCoO22013

    • Author(s)
      Kazuhiko Mukai
    • Organizer
      224th ECS Meeting
    • Place of Presentation
      The Hilton San Francisco Hotel (米国サンフランシスコ)
    • Related Report
      2013 Research-status Report
  • [Presentation] リチウムイオン電池材料のラマンスペクトロスコピー:無歪みリチウムインサーション材料Li[Li1/3Ti5/3]O42013

    • Author(s)
      向和彦、加藤雄一、中野秀之
    • Organizer
      日本分光学会 年次講演会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府豊中市)
    • Related Report
      2013 Research-status Report
  • [Presentation] リチウム鉄チタン酸化物Li1+1/2xFe5/2-3/2xTixO4の結晶構造解析2013

    • Author(s)
      向和彦、加藤雄一、堀渕嘉代、中野秀之
    • Organizer
      日本セラミックス協会東海支部学術研究会発表会
    • Place of Presentation
      名城大学天白キャンパス(愛知県名古屋市)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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