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Development of natural pigment-based photochromic material by a composite of anthocyanin and mesoporous material

Research Project

Project/Area Number 25410213
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionTokyo University of Technology

Principal Investigator

SHIBATA Masashi  東京工科大学, 応用生物学部, 教授 (00513657)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2014: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2013: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsフォトクロミック材料 / アントシアニン / 3-デオキシアントシアニジン / ルテオリニジン / 光着消色 / 多孔質シリカ / メソポーラスシリカ / 複合体 / ルテオリニジン色素
Outline of Final Research Achievements

Aiming to develop non-toxic and safe photochromic pigments for food, toys and cosmetics, we have studied composites of plant extract pigments and nontoxic cosmetic/ food ingredients.
3-deoxy-anthocyanidins which are classified to anthocyanin pigments are isolated and purified from edible sorghum by using HPLC and were dissolved in a mixed solvent of butylene glycol and aqueous citric acid. This solution exhibited photochromic properties; it became vivid red by UV-A irradiation and discolored under light-shielding condition.
When the dye solution was absorbed into the pores of porous silica particle, the obtained powder exhibiting a photochromic behavior under high humidity conditions.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (23 results)

All 2016 2015 2014 2013 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) Remarks (2 results)

  • [Journal Article] Fixation and stability enhancement of beta-carotene by organo-modified mesoporous silica2016

    • Author(s)
      Yoshiumi Kohno, Yasushi Kato, Masashi Shibata, Choji Fukuhara, Yasuhisa Maeda, Yasumasa Tomita, and Kenkichiro Kobayashi
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 220 Pages: 1-6

    • DOI

      10.1016/j.micromeso.2015.08.019

    • NAID

      120006457910

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Composite Comprising Anthocyanidin Dye and HMS-Type Mesoporous Silica and its Color Properties2015

    • Author(s)
      Y.-H. Lin, H. Murakami, Y. Kohno, M. Shibata
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 88 Issue: 11 Pages: 371-377

    • DOI

      10.4011/shikizai.88.371

    • NAID

      130005126237

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced stability of natural anthocyanin incorporated in Fe-containing mesoporous silica2014

    • Author(s)
      Yoshiumi Kohno, Yasushi Kato, Masashi Shibata, Choji Fukuhara, Yasuhisa Maeda, Yasumasa Tomita and Kenkichiro Kobayashi
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 203 Pages: 232-237

    • DOI

      10.1016/j.micromeso.2014.10.042

    • NAID

      120005531426

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Pickering Emulsification using MCM41-Type Mesoporous Silica2014

    • Author(s)
      Ayaka TAKATA, Bin WU, Yoshimune NONOMURA, Masashi SHIBATA
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 87 Pages: 393-397

    • NAID

      130004736502

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Improved photostability of hydrophobic natural dye incorporated in organo-modified hydrotalcite2014

    • Author(s)
      Yoshiumi Kohno, Saeko Asai, Masashi Shibata, Choji Fukuhara, Yasuhisa Maeda, Yasumasa Tomita, and Kenkichiro Kobayashi
    • Journal Title

      J. Phys. Chem. Solids

      Volume: 75 Issue: 8 Pages: 945-50

    • DOI

      10.1016/j.jpcs.2014.04.010

    • NAID

      120005531425

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Adsorption behavior of natural anthocyanin dye on mesoporous silica2014

    • Author(s)
      Yoshiumi Kohno, Eriko Haga, Keiko Yoda, Masashi Shibata, Choji Fukuhara, Yasumasa Tomita, Yasuhisa Maeda, Kenkichiro Kobayashi
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 75 Issue: 1 Pages: 48-51

    • DOI

      10.1016/j.jpcs.2013.08.007

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fluorescent colored material made of clay mineral and phycoerythrin pigment derived from seaweed2014

    • Author(s)
      Yi-Hung Lin, Yumiko Hori, Saki Hoshino, Chiho Miyazawa, Yoshiumi Kohno, and Masashi Shibata
    • Journal Title

      Dyes Pigm.

      Volume: 100 Pages: 97-103

    • DOI

      10.1016/j.dyepig.2013.08.022

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Anthocyanidin Dye and Al/Fe-Containing Mesoporous Silica Composites and their Color Properties2013

    • Author(s)
      Yi-Hung Lin, Aya Saotome, Yoshiumi Kohno, and Masashi Shibata
    • Journal Title

      Journal of the Japan Society of Colour Material

      Volume: 86 Issue: 11 Pages: 397-402

    • DOI

      10.4011/shikizai.86.397

    • NAID

      130004516231

    • ISSN
      0010-180X, 1883-2199
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ゲル化剤および溶媒がフィコエリスリン色素の安定性におよぼす影響2016

    • Author(s)
      イジェウォン、柴田雅史
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 植物色素を用いた安全性の高いフォトクロミック材料の開発2015

    • Author(s)
      三原麻衣、柴田雅史
    • Organizer
      第7回大学コンソーシアム八王子学生発表会
    • Place of Presentation
      学園都市センター(東京都八王子市)
    • Year and Date
      2015-12-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 各種溶媒を用いたアントシアニン系ルテオリニジン色素溶液のフォトクロミック特性2015

    • Author(s)
      八木下優貴、三原麻衣、小笹葉月、河野芳海、柴 田雅史
    • Organizer
      2015年度色材研究発表会
    • Place of Presentation
      千葉工業大学津田沼キャンパス(千葉県習志野市)
    • Year and Date
      2015-10-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機溶媒含有水性ゲルの物性と色素担体としての性質2015

    • Author(s)
      イジェウォン、柴田雅史
    • Organizer
      2015年度色材研究発表会
    • Place of Presentation
      千葉工業大学津田沼キャンパス(千葉県習志野市)
    • Year and Date
      2015-10-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] コウリャンから分離精製したアントシアニン色素のフォトクロミック挙動2015

    • Author(s)
      三原麻衣、八木下優貴、河野芳海、柴田雅史
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2015-10-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] メソポーラスシリカとの複合化におけるアントシアニン色素水溶液の濃度効果2015

    • Author(s)
      村上 穂高・榎本 未央子・河野 芳海・柴田 雅史
    • Organizer
      日本化学会第95年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 水・エタノール・グリセリン混合溶媒でのルテオリニジン色素のフォトクロミック特性2015

    • Author(s)
      八木下優貴・林怡宏・手島綾乃・河野芳海・柴田雅史
    • Organizer
      日本化学会第95年会
    • Place of Presentation
      日本大学船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] アオバナ色素コンメリニンのハイドロタルサイトへの吸着と安定化2014

    • Author(s)
      村上優花・河野芳海・柴田雅史
    • Organizer
      2014年度色材研究発表会
    • Place of Presentation
      名古屋市工業研究所(愛知県名古屋市)
    • Year and Date
      2014-10-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Al含有HMS型メソポーラスシリカへの吸着によるアントシアニジン色素の安定化2014

    • Author(s)
      林怡宏・河野芳海・柴田雅史
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学神楽坂キャンパス(東京都新宿区)
    • Year and Date
      2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 合成後処理によってFeをドープしたメソポーラスシリカの紫外線吸収特性2014

    • Author(s)
      村上優花,河野芳海,柴田雅史
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学神楽坂キャンパス(東京都新宿区)
    • Year and Date
      2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] アオバナ色素コンメリニンとイオン交換処理層状粘土鉱物の複合化

    • Author(s)
      村上優花, 河野芳海, 柴田雅史
    • Organizer
      色材協会85周年記念国際会議
    • Place of Presentation
      東京都江戸川区タワーホール船堀
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機修飾をしたメソポーラスシリカのピッカリング乳化特性

    • Author(s)
      高田彩加, 柴田雅史
    • Organizer
      色材協会85周年記念国際会議
    • Place of Presentation
      東京都江戸川区タワーホール船堀
    • Related Report
      2013 Research-status Report
  • [Presentation] 粘土層間での2- ヒドロキシカルコンからフラビリウ ムへの光着色反応

    • Author(s)
      河野芳海, 伊藤真紀, 倉田充, 柴田雅史, 松島良華, 前田康久
    • Organizer
      色材協会85周年記念国際会議
    • Place of Presentation
      東京都江戸川区タワーホール船堀
    • Related Report
      2013 Research-status Report
  • [Remarks] 化粧品材料化学研究室

    • URL

      http://www.shibatalab.org/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 化粧品材料化学研究室

    • URL

      http://www.shibatalab.org/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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