Synthesis and Function of Chiral Organic-Inorganic Nanohybrid Plasmonic Materials
| Project/Area Number |
25410215
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Multi-year Fund |
|---|
| Section | 一般 |
|---|
| Research Field |
Organic and hybrid materials
|
|---|
| Research Institution | Kinki University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
NAKAHODO Tsukasa 近畿大学, 理工学部, 講師 (10375371)
|
|---|
| Project Period (FY) |
2013-04-01 – 2016-03-31
|
| Project Status |
Completed (Fiscal Year 2015)
|
| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
|---|
| Keywords | ハイブリッド / 有機無機ナノ材料 / ナノチューブ / プラズモン / ポリマーナノチューブ / ポルフィリン / 酸化チタンナノ粒子 / キラル / 光アンテナ / 金属ナノ粒子 / 有機無機ハイブリッド |
|---|
| Outline of Final Research Achievements |
The novel hybrid nanotubes (2-C60-PT-NT, Ag-C60-PT-NT, and Au-C60-PT-NT) involves the following new aspects: i) the template-based electropolymerization of 2-C60 produced the fullerene C60-polythiophene NTs (2-C60-PT-NT) which showed the reversible redox behaviour of the fullerene C60, and ii) the plasmonic hybrid NTs (Ag-C60-PT-NT and Au-C60-PT-NT) show a significant SERS compared to that of the NTs (2-C60-PT-NT) which were prepared from the template-based electropolymerization of 2-C60. It is worth pointing out that our approach to preparing a metal-polymer NT composite completely differs from all previous studies on the deposition of metal NPs onto the surface of polymer NTs. We observed a fluorescence enhancement and photostability for the polythiophene of the hybrid NTs (1-Ag-PT-NT) in solution, while no enhancement of the polythiophene fluorescence was observed in the mixture of the polythiophene NTs (1-PT-NT) and terthiophene-modified silver NPs (1-AgNP).
|
Report
(4 results)
Research Products
(17 results)
