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Electrical and optical properties of novel conductive oxides derived by reduction of lithium borates.

Research Project

Project/Area Number 25410244
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionKanazawa Institute of Technology

Principal Investigator

Tsuyumoto Isao  金沢工業大学, バイオ・化学部, 教授 (60282571)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords還元 / ホウ酸 / フラックス / 鉄 / 酸化鉄 / 分離 / 固溶体 / リサイクル / 水素 / 導電性酸化物 / 非晶質
Outline of Final Research Achievements

We found that hydrogen reduction of trace amount of iron or cobalt oxide contained as a solid solution in aluminosilicate was enhanced by adding sodium borate as a flux and that iron or cobalt metal was easily deposited on the surface. Iron with metallic luster was deposited by heating aluminosilicate containing 0.50 wt% of iron as a solid solution in hydrogen at 950°C with a sodium borate (3Na2O・B2O3) flux. Furthermore, it was suggested that cobalt and indium could be also separated by the reduction according to the thermodynamic control. It is expected our findings will lead to the separation of rare metals from industrial wastes and low-temperature refining process of high melting metals.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (35 results)

All 2016 2015 2014 2013 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (23 results) (of which Int'l Joint Research: 2 results,  Invited: 5 results) Book (6 results)

  • [Journal Article] Iron Deposition from Aluminosilicate Containing Trace Amount of Iron Oxide by Borate - Enhanced Hydrogen Reduction2015

    • Author(s)
      Isao Tsuyumoto
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 98 Issue: 12 Pages: 3666-3669

    • DOI

      10.1111/jace.13987

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis and lithium insertion properties of ramsdellite LixTiO2 anode materials2015

    • Author(s)
      Isao Tsuyumoto, Takumi Moriguchi
    • Journal Title

      Materials Research Bulletin

      Volume: 70 Pages: 748-752

    • DOI

      10.1016/j.materresbull.2015.06.014

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Nano-sized Layered LiVO2 Prepared from Peroxo-polyvanadic Acid and its Electrochemical Properties2014

    • Author(s)
      Isao Tsuyumoto, Yuya Nakakura, Satoru Yamaki
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 97 Issue: 11 Pages: 3374-3377

    • DOI

      10.1111/jace.13267

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Lithium Ion Insertion Properties of Nanocrystalline Anatase Titanium Oxides Prepared from Peroxo-Polytitanic Acid.2014

    • Author(s)
      Isao Tsuyumoto, Kazuki Kobayashi
    • Journal Title

      Solid State Ionics

      Volume: 255 Pages: 60-64

    • DOI

      10.1016/j.ssi.2013.11.048

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Characterization and Charge Discharge Properties of Layer Structure Lithium Zinc Borate, LiZnBO3.2013

    • Author(s)
      Isao Tsuyumoto, Akihiro Kihara
    • Journal Title

      Materials Sciences and Applications

      Volume: 4 Issue: 04 Pages: 246-249

    • DOI

      10.4236/msa.2013.44030

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Amorphous and Nanocrystalline Anatase Titanium Dioxides Prepared from Peroxo-Polytitanic Acid and Their Electrochemical Properties2013

    • Author(s)
      Isao Tsuyumoto, Kazuki Kobayashi
    • Journal Title

      ECS Transactions

      Volume: 50 Issue: 48 Pages: 17-24

    • DOI

      10.1149/05048.0017ecst

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] New Sodium Borate-Based Flame Retardants for Wood and Polyurethane Foam2015

    • Author(s)
      Isao Tsuyumoto
    • Organizer
      1st Asia-Oceania Symposium on Fire Safety Materials
    • Place of Presentation
      Suzhou, China
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] パワーエレクトロニクス応用に向けたBi系酸化物MOCVD膜の配向制御2015

    • Author(s)
      河合伸哉,和田倫明,土屋哲男,有沢俊一,露本伊佐男,金子 俊幸,舘野康史,Petre Badica,遠藤和弘
    • Organizer
      日本セラミックス協会 第28回秋季シンポジウム
    • Place of Presentation
      富山
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Orientation Engineering for the Growth of c-axis and Non-c-axis Epitaxial Bi2Sr2CaCu2O8+δ Thin Films by MOCVD2015

    • Author(s)
      Kazuhiro Endo, Shunich Arisawa, Toshiyuki Kaneko, Isao Tsuyumoto, Yasushi Tateno, Hirofumi Yamasaki, Petre Badica
    • Organizer
      12th European Conference on Applied Superconductivity
    • Place of Presentation
      Lyon, France
    • Year and Date
      2015-09-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 革新的な電池開発と高校化学の深い関係2015

    • Author(s)
      露本伊佐男
    • Organizer
      第6回夢ナビライブ
    • Place of Presentation
      大阪
    • Year and Date
      2015-06-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ビスマス系銅酸化物超伝導薄膜の配向制御2014

    • Author(s)
      ○金子俊幸・有沢俊一・山崎裕文・露本伊佐男・Petre Badica・遠藤和弘
    • Organizer
      フィジカルセンサ研究会・電気学会
    • Place of Presentation
      石川・金沢工業大学
    • Year and Date
      2014-12-19
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリホウ酸ナトリウムを用いたポリアクリロニトリル系樹脂の難燃化技術2014

    • Author(s)
      ○能登雄祐,露本伊佐男
    • Organizer
      日本セラミックス協会北陸支部秋季研究発表会
    • Place of Presentation
      富山・富山大学工学部
    • Year and Date
      2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] ラムスデライト型チタン酸リチウムの合成とその電気化学的性質の評価2014

    • Author(s)
      ○森口拓文・露本伊佐男
    • Organizer
      日本セラミックス協会北陸支部秋季研究発表会
    • Place of Presentation
      富山・富山大学工学部
    • Year and Date
      2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] ビスマス系銅酸化物超伝導薄膜の配向制御技術2014

    • Author(s)
      ○金子俊幸・館野康史・有沢俊一・Petre Badica・露本伊佐男・遠藤和弘
    • Organizer
      日本セラミックス協会北陸支部秋季研究発表会
    • Place of Presentation
      富山・富山大学工学部
    • Year and Date
      2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリホウ酸ナトリウムを用いたポリアクリロニトリル系樹脂の難燃化2014

    • Author(s)
      ○能登雄佑・露本伊佐男
    • Organizer
      第4回CSJ化学フェスタ2014(日本化学会主催)
    • Place of Presentation
      東京・タワーホール船堀
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Research-status Report
  • [Presentation] MOCVD法による非c軸配向Bi2Sr2CaCu2O8+δ薄膜の作製と評価2014

    • Author(s)
      ○金子俊幸・館野康史・有沢俊一・Petre, Badica・露本伊佐男・遠藤和弘
    • Organizer
      第4回CSJ化学フェスタ2014(日本化学会主催)
    • Place of Presentation
      東京・タワーホール船堀
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Research-status Report
  • [Presentation] 革新的な電池開発と高校化学の深い関係2014

    • Author(s)
      露本伊佐男
    • Organizer
      第5回夢ナビライブ2014」(文部科学省後援)
    • Place of Presentation
      名古屋・名古屋ポートメッセ
    • Year and Date
      2014-07-22
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ホウ酸塩を使った新しい難燃技術 ―不燃木材からプラスチック用難燃塗布膜まで2014

    • Author(s)
      露本伊佐男
    • Organizer
      「難燃・共同セミナー」(日本難燃剤協会・難燃材料研究会主催)
    • Place of Presentation
      東京・連合会館
    • Year and Date
      2014-06-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Nanocrystalline TiO2 and LiVO2 Derived from Peroxo-polyacid and Their Electrochemical Properties.

    • Author(s)
      Isao Tsuyumoto
    • Organizer
      23rd Annual Meeting of MRS - J
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Preparation and Evaluation of Bi2Sr2CaCu2O8+δ Superconducting Films by MOCVD.

    • Author(s)
      T. Kaneko, H. Yamasaki, S. Arisawa, P. Badica, I. Tsuyumoto, K. Endo
    • Organizer
      23rd Annual Meeting of MRS - J
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] ラムスデライト型チタン酸リチウムの合成とリチウムイオン電池負極材料への応用

    • Author(s)
      ○森口拓文・露本伊佐男
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] ホウ酸ナトリウムとケイ酸アルミニウムを原料とした新規導電性酸化物の開発

    • Author(s)
      ○大和隆之・亀田光平・露本伊佐男
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機金属化学気相成長法を用いたビスマス系銅酸化物超伝導薄膜の作製と構造評価

    • Author(s)
      ○金子俊幸・井上裕貴・露本伊佐男・南戸秀仁・竹井義法・遠藤和弘・有沢俊一・P. Badica
    • Organizer
      日本セラミックス協会北陸支部秋季研究発表会
    • Place of Presentation
      金沢・文教会館
    • Related Report
      2013 Research-status Report
  • [Presentation] ケイ酸塩とデンプンを複合化した難燃塗布膜の開発とその評価

    • Author(s)
      ○茶木健志,露本伊佐男
    • Organizer
      日本セラミックス協会北陸支部秋季研究発表会
    • Place of Presentation
      金沢・文教会館
    • Related Report
      2013 Research-status Report
  • [Presentation] 層状岩塩型LiVO2ナノ結晶の合成とその電気化学的性質

    • Author(s)
      ○露本伊佐男
    • Organizer
      日本セラミックス協会北陸支部秋季研究発表会
    • Place of Presentation
      金沢・文教会館
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機金属化学気相成長法によるBi2Sr2CaCu2O8+δ薄膜の作製と評価

    • Author(s)
      ○金子俊幸・山崎裕文・露本伊佐男・有沢俊一・Petre Badica・遠藤和弘
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      東京・タワーホール船堀
    • Related Report
      2013 Research-status Report
  • [Presentation] 過酸化ポリバナジン酸を原料としたLiVO3の合成と電気化学的性質

    • Author(s)
      ○八巻 悟・露本 伊佐男
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学 長野キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機金属化学気相成長法によるビスマス系銅酸化物超伝導薄膜の作製

    • Author(s)
      ○金子俊幸・池永訓昭・森口拓文・井上裕貴・露本伊佐男・南戸秀仁・竹井義法・遠藤和弘・山崎裕文・有沢俊一・Petre Badica
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学 長野キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 電子伝導性を有する新しいホウ酸リチウム還元体の開発とその応用

    • Author(s)
      ○亀田 光平・露本 伊佐男
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学 長野キャンパス
    • Related Report
      2013 Research-status Report
  • [Book] 理工系の基礎化学2016

    • Author(s)
      露本伊佐男(分担執筆)
    • Total Pages
      200
    • Publisher
      培風館
    • Related Report
      2015 Annual Research Report
  • [Book] 基礎から学ぶ機器分析化学2016

    • Author(s)
      露本伊佐男(分担執筆)
    • Total Pages
      250
    • Publisher
      化学同人
    • Related Report
      2015 Annual Research Report
  • [Book] 難燃剤・難燃化材料の最前線2015

    • Author(s)
      露本伊佐男(分担執筆)
    • Total Pages
      265
    • Publisher
      シーエムシー出版
    • Related Report
      2015 Annual Research Report
  • [Book] 地球環境の教科書10講 改訂版2014

    • Author(s)
      露本伊佐男(分担執筆)
    • Total Pages
      287
    • Publisher
      東京書籍
    • Related Report
      2014 Research-status Report
  • [Book] 次世代自動車(EV・HV)に向けた自動車材料の樹脂化による車体軽量化 -新材料開発・加工技術の事例とこれからの展開-2013

    • Author(s)
      露本伊佐男(分担執筆)
    • Total Pages
      798
    • Publisher
      技術情報協会
    • Related Report
      2013 Research-status Report
  • [Book] 難燃化の最新技術と難燃剤の選定・使用法2013

    • Author(s)
      露本伊佐男(分担執筆)
    • Total Pages
      324
    • Publisher
      R&Dサポートセンター
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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