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Control of Redox Process of Iron for Application on Secondary Batteries

Research Project

Project/Area Number 25410250
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Device related chemistry
Research InstitutionNihon University

Principal Investigator

EGASHIRA Minato  日本大学, 生物資源科学部, 准教授 (20304842)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords鉄電極 / アルカリ二次電池 / 二次電池 / 繊維状ナノ炭素 / 鉄の利用効率 / ナノ材料
Outline of Final Research Achievements

Iron negative electrode for alkaline secondary batteries suffers fromits low utilization due to passivation. In order improve the utilization of iron, composite electrodes based on nano-particles of iron species and carbon nano-fiber (CNF). The sol-gel precipitation compositization is favorable for iron utilization until 0.45 mass ratio of iron, while the mixing of nano-sized Fe3O4 with CNF is effective for higher iron loading. The iron content above where iron utilization abruptly increase exists regardless of the compositizing method. Further investigation on this phenomenon indicates some accerelation effect of intermediate ferrous species on the oxidation (discharge) process.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (10 results)

All 2015 2014 2013 Other

All Journal Article (5 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results) Presentation (4 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results) Book (1 results)

  • [Journal Article] Factors Influencing Iron utilization of Iron Compound/Carbon Nanofiber Composite Electrode2015

    • Author(s)
      Minato Egashira
    • Journal Title

      Electrochemistry

      Volume: 83 Issue: 11 Pages: 984-988

    • DOI

      10.5796/electrochemistry.83.984

    • NAID

      130005107649

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of Cation Mixing on Utility of Iron in Iron/Carbon Nano-Fiber Composite Electrode2015

    • Author(s)
      Minato Egashira
    • Journal Title

      Electrochemistry

      Volume: 83 Issue: 5 Pages: 354-356

    • DOI

      10.5796/electrochemistry.83.354

    • NAID

      130005067087

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Influence of Preparation Condition of Iron Hydroxide/Nano-Carbon Composite on Its Properties2014

    • Author(s)
      Minato Egashira, Satoshi Nakayama, Nobuko Yoshimoto, Masayuki Morita
    • Journal Title

      Electrochemistry

      Volume: 82 Issue: 4 Pages: 273-275

    • DOI

      10.5796/electrochemistry.82.273

    • NAID

      130003396387

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrode Properties of Nickel Phthalocyanine/Carbon Nanotube Composite in Ionic Liquid Electrolyte2013

    • Author(s)
      江頭 港,齋藤 渉,鴇田真広,吉本信子,森田昌行
    • Journal Title

      Electrochemistry

      Volume: 81 Issue: 10 Pages: 783-786

    • DOI

      10.5796/electrochemistry.81.783

    • NAID

      10031191940

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Capacitor Properties of Carbon Electrodes Derived from α-Cyclodextrin2013

    • Author(s)
      鴇田真広,江頭 港,吉本信子,森田昌行
    • Journal Title

      Electrochemistry

      Volume: 81 Issue: 10 Pages: 804-807

    • DOI

      10.5796/electrochemistry.81.804

    • NAID

      10031191947

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] On the Design of Iron/Fibrous Nano-Carbon Composite Electrodes for Alkaline Secondary Batteries2015

    • Author(s)
      Minato Egashira
    • Organizer
      The International Conference on Small Science (ICSS 2015)
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2015-11-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 鉄/ナノ炭素複合電極の高容量化への試み2014

    • Author(s)
      江頭 港
    • Organizer
      電気化学会秋季大会
    • Place of Presentation
      北海道大学高等教育推進機構(北海道札幌市北区)
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Design of Iron/Nano-fibrous Carbon Composite Electrode in Alkaline Electrolyte2014

    • Author(s)
      Minato Egashira, Nobuko Yoshimoto, Masayuki Morita
    • Organizer
      The 10th Japan-France Joint Seminar on Battery
    • Place of Presentation
      ホテル大箱根(神奈川県足柄北郡仙北町)
    • Year and Date
      2014-09-22 – 2014-09-24
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 鉄/ナノ炭素複合電極のアルカリ電解液中での電極特性に及ぼす調製条件の影響

    • Author(s)
      江頭 港
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学千里山キャンパス
    • Related Report
      2013 Research-status Report
  • [Book] リチウム空気電池の最前線2013

    • Author(s)
      江頭 港,周 豪慎(監修),他17名
    • Publisher
      株式会社シーエムシー出版
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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