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study on high efficiency solar cell driven by metal workfunction

Research Project

Project/Area Number 25420282
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

Sameshima Toshiyuki  東京農工大学, 工学(系)研究科(研究院), 教授 (30271597)

Co-Investigator(Kenkyū-buntansha) MIZUNO Tomohisa  神奈川大学, 理学部, 教授 (60386810)
Co-Investigator(Renkei-kenkyūsha) HASUMI Masahiko  東京農工大学, 大学院工学研究院, 助教 (60261153)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsソーラーセル / パッシベーション膜 / 低温プロセス技術 / キャリヤライフタイム / マイクロ波吸収 / 加熱水 / 水蒸気熱処理 / 光誘起フリーキャリヤ / キャリアライフタイム / 光誘起フリーキャリア / パッシベション膜
Outline of Final Research Achievements

We developed two kinds of surface passivation technologies for crystalline silicon: ① a combination of oxygen radical treatment at room temperature with 260℃、1.3MPa H2O vapor heat treatment for 3 h and ② heat treatment in liquid water at 110℃ for 1h. Those treatment form 1 nm thick oxide layers at the silicon surfaces and reduce the density of surface recombination defects resulting in increasing the effective minority carrier lifetime. Especially the heat treatment in liquid water at 110℃ for 1h achieved the effective minority carrier lifetime as high as that of thermally grown oxide layer coating the silicon surfaces. MIS diodes were fabricated with those passivation technologies and Au and Al metals. Good diode characteristics were observed. Solar cell characteristics with efficiencies of 8-9% were also obtained.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (26 results)

All 2016 2015 2014 2013 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Open Access: 4 results,  Acknowledgement Compliant: 4 results) Presentation (17 results) (of which Int'l Joint Research: 5 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Heat treatment in 110oC liquid water used for passivating siliconsurfaces2016

    • Author(s)
      T. Nakamura, T. Motoki, J. Ubukata, T. Sameshima, M. Hasumi and T. Mizuno
    • Journal Title

      Appl. Phys. A.

      Volume: 122 Issue: 4

    • DOI

      10.1007/s00339-016-9976-z

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Behavior of Photo Induced Minority Carrier Lifetime in PN Junction with Different Bias Voltages2015

    • Author(s)
      T. Sameshima and M. Hasumi
    • Journal Title

      Energy Procedia

      Volume: 84 Pages: 110-117

    • DOI

      10.1016/j.egypro.2015.12.303

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Passivation of silicon surfaces by heat treatment in liquid water at 110oC2015

    • Author(s)
      T. Nakamura, T. Sameshima, M. Hasumi, and T. Mizuno
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 54 Issue: 10 Pages: 106503-106503

    • DOI

      10.7567/jjap.54.106503

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photoinduced carrier annihilation in silicon pn junction2015

    • Author(s)
      T. Sameshima, T. Motoki, K. Yasuda, T. Nakamura, M. Hasumi, and T. Mizuno
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 54 Issue: 8 Pages: 081302-081302

    • DOI

      10.7567/jjap.54.081302

    • NAID

      210000145492

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Crystal direction dependence of quantum confinement effects of two-dimensional Si layers fabricated on silicon-on-quartz substrates: modulation of phonon spectra and energy-band structures2014

    • Author(s)
      T. Mizuno, Y. Nagata, Y. Suzuki, Y. Nakahara, T. Aoki, and T. Sameshima
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 4S Pages: 04EC09-04EC09

    • DOI

      10.7567/jjap.53.04ec09

    • NAID

      210000143563

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Quantum confinement effects in doped two-dimensional Si layers: novel device design for two-dimensional pn-junction structures2014

    • Author(s)
      T. Mizuno, Y. Nakahara, Y. Nagata, Y. Suzuki, T. Aoki, and T. Sameshima
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 4S Pages: 04EC08-04EC08

    • DOI

      10.7567/jjap.53.04ec08

    • NAID

      210000143562

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photo induced minority carrier annihilation at crystalline silicon surface in metal oxide semiconductor structure2014

    • Author(s)
      Toshiyuki Sameshima, Jun Furukawa, Tomohiko Nakamura, Satoshi Shigeno, Tomohito Node, Shinya Yoshidomi, and Masahiko Hasumi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 53 Issue: 3 Pages: 031301-031301

    • DOI

      10.7567/jjap.53.031301

    • NAID

      210000143406

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] PN接合の電圧印加による光誘起少数キャリヤライフタイム挙動の研究2015

    • Author(s)
      鮫島俊之, 中村友彦, 蓮見真彦
    • Organizer
      Thin Film Materials & Devices Meeting
    • Place of Presentation
      龍谷大学アバンティ響都ホール(京都府京都市)
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] マイクロ波急速加熱によるシリコンの活性化とドーピングの検討2015

    • Author(s)
      太田康介, 木村駿介, 蓮見真彦, 鈴木歩太, 牛島満, 鮫島俊之
    • Organizer
      Thin Film Materials & Devices Meeting
    • Place of Presentation
      龍谷大学アバンティ響都ホール(京都府京都市)
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] Microwave-Induced Rapid Heating Used to Crystallize Thin Silicon Films2015

    • Author(s)
      S. Kimura, K. Ohta, T. Nakamura, M. Hasumi, A. Suzuki, M. Ushijima, T. Sameshima
    • Organizer
      第76回応用物理学会学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Heat treatment in 110oC liquid water used for Passivating silicon surfaces2015

    • Author(s)
      T. Nakamura, T. Sameshima, M. Hasumi, T. Mizuno
    • Organizer
      Active Matrix Flat Panel Displays
    • Place of Presentation
      龍谷大学アバンティ響都ホール(京都府京都市)
    • Year and Date
      2015-07-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Annihilation Properties of Photo-Induced Carrier in Silicon PN Junction2015

    • Author(s)
      M. Hasumi, T. Sameshima, T. Motoki, T. Nakamura and T. Mizuno
    • Organizer
      Active Matrix Flat Panel Displays
    • Place of Presentation
      龍谷大学アバンティ響都ホール(京都府京都市)
    • Year and Date
      2015-07-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Laser Induced Minority Carrier Lifetime in PN Junction2015

    • Author(s)
      T. Sameshima, T. Nakamura, S. Yoshidomi, M. Hasumi
    • Organizer
      Symposium on Laser Precision Microfabrication
    • Place of Presentation
      北九州国際会議場(福岡県北九州 市)
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Behavior of Photo Induced Minority Carrier Lifetime in PN Junction with Different Bias Voltages2015

    • Author(s)
      T. Sameshima, M. Hasumi
    • Organizer
      E-Mater. Res. Soc. Symp.
    • Place of Presentation
      France, Lille
    • Year and Date
      2015-05-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Passivation of Silicon Surfaces by Treatment in Water at 110oC2015

    • Author(s)
      T. Nakamura, T. Sameshima, M. Hasumi, T. Mizuno
    • Organizer
      Mater. Res. Soc. Symp. Proc.
    • Place of Presentation
      USA, San Francisco
    • Year and Date
      2015-04-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Passivation of Silicon Surfaces by Heat Treatment in Boiled Water and its Application of2014

    • Author(s)
      Tomohiko Nakamura, Shinya Yoshidomi, Masahiko Hasumi, and Toshiyuki Sameshima
    • Organizer
      2014 Workshop on Active Matrix Flat Panel Displays
    • Place of Presentation
      京都府京都市、龍谷大学アバンティ響都ホール
    • Year and Date
      2014-07-02 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Passivation of Silicon Surfaces by Oxygen Radical followed by High Pressure H2O Vapor2014

    • Author(s)
      Toshiyuki Sameshima, Shinya Yoshidomi, Tomohiko Nakamura, Satoshi Shigeno, and Masahiko Hasumi
    • Organizer
      2014 Workshop on Active Matrix Flat Panel Displays
    • Place of Presentation
      京都府京都市、龍谷大学アバンティ響都ホール
    • Year and Date
      2014-07-02 – 2014-07-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Activation of Silicon Implanted with Phosphorus Atoms by Microwave Heating2013

    • Author(s)
      S. Yoshidomi, C. Akiyama, J. Furukawa, M. Hsumi, T. Ishii, T. Sameshima, Y. Inouchi, and M. Naito
    • Organizer
      Active-Matrix Flatpanel Displays and Devices
    • Place of Presentation
      龍谷大学アバンティ響都ホール
    • Related Report
      2013 Research-status Report
  • [Presentation] Minority Carrier Annihilation at Crystalline Silicon Surface in MOS Structure2013

    • Author(s)
      J. Furukawa, S. Yoshidomi, M. Hasumi, and T. Sameshima
    • Organizer
      Active-Matrix Flatpanel Displays and Devices
    • Place of Presentation
      龍谷大学アバンティ響都ホール
    • Related Report
      2013 Research-status Report
  • [Presentation] Annihilation of Photo-Induced Minority Carrier Caused by Ion Implantation and Rapid Thermal Annealing2013

    • Author(s)
      T. Sameshima and S. Shibata
    • Organizer
      Active-Matrix Flatpanel Displays and Devices
    • Place of Presentation
      龍谷大学アバンティ響都ホール
    • Related Report
      2013 Research-status Report
  • [Presentation] Passivation of Silicon Surface by Laser Rapid Heating2013

    • Author(s)
      T. Sameshima, H. Abe, M. Hasumi, T. Mizuno, and N. Sano
    • Organizer
      レーザー先端材料加工国際会議
    • Place of Presentation
      朱鷺メッセ新潟コンベンションセンター
    • Related Report
      2013 Research-status Report
  • [Presentation] Silicon Surface oxidation and Passivation by Remote Induction-Coupled Oxygen Plasma2013

    • Author(s)
      鮫島俊之,蓮見真彦,吉冨真也,中村友彦, 滋野聖
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Microwave Annealing of Phosphorus Implanted ptype Silicon2013

    • Author(s)
      M. Hasumi , S. Yoshidomi and T. Sameshima
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Activation of Silicon Implanted with Dopant Atoms by Microwave Heating2013

    • Author(s)
      T. Sameshima, T. Nakamura, S. Yoshidomi, M. Hasumi, T. Ishii, Y. Inouchi, M. Naito and T. Mizuno
    • Organizer
      Solid State Devices and Materials 2013
    • Place of Presentation
      ヒルトン福岡シーホーク
    • Related Report
      2013 Research-status Report
  • [Remarks] Sameshima Lab.

    • URL

      http://web.tuat.ac.jp/~sameken/

    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 光誘起キャリヤライフタイム測定方法及び光誘起キャリヤライフタイム測定装置2016

    • Inventor(s)
      鮫島俊之
    • Industrial Property Rights Holder
      鮫島俊之
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-025808
    • Filing Date
      2016-02-15
    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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