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Development of phosphor single crystals for high-brightness lighting applications

Research Project

Project/Area Number 25420308
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

Shimamura Kiyoshi  国立研究開発法人物質・材料研究機構, 光・電子材料ユニット, グループリーダー (90271965)

Co-Investigator(Kenkyū-buntansha) Víllora García  国立研究開発法人 物質・材料研究機構, 光・電子材料ユニット, 主任研究員 (70566760)
ビジョラ ガルシア  国立研究開発法人物質・材料研究機構, 光・電子材料ユニット, 主任研究員 (90421411)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords高輝度白色LED / 蛍光体 / 単結晶 / 量子効率 / 高輝度白色LED/LD
Outline of Final Research Achievements

For applications requiring a high-brightness, current white light emitting diodes present overheating problems, which drastically decrease their emission efficiency, color quality and lifetime. In this work, single crystal phosphors (SCPs), which are proposed as novel alternative to conventional ceramic powder phosphors (CPPs), have been investigated. This totally new approach takes advantage of the superior properties of single crystals in comparison with ceramic materials. SCPs exhibit an outstanding conversion efficiency and thermal stability up to 300℃. Furthermore, compared with encapsulated CPPs, SCPs possess a superior thermal conductivity, so that generated heat can be released efficiently. Therefore, SCPs represent the ideal, long-demanded all-inorganic phosphors for high-brightness white light sources, especially those involving the use of high-density laser-diode beams. Promising green SCP Ce:Lu3Al5O12 is demonstrated as well as yellow SCP Ce:Y3Al5O12.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (40 results)

All 2016 2015 2014 2013 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results) Presentation (23 results) (of which Int'l Joint Research: 6 results,  Invited: 17 results) Remarks (1 results) Patent(Industrial Property Rights) (11 results) (of which Overseas: 3 results)

  • [Journal Article] Single-crystal phosphors for high-brightness white LEDs/LDs2016

    • Author(s)
      E. G. Villora, S. Arjoca, D. Inomata, K. Shimamura
    • Journal Title

      Proc. of SPIE, Light-Emitting Diodes: Materials, Devices, and Applications for Solid State Lighting XX

      Volume: 9768 Pages: 976805-976805

    • DOI

      10.1117/12.2212233

    • NAID

      40020842531

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Temperature dependence of Ce:YAG single-crystal phosphors for high-brightness white LEDs/LDs2015

    • Author(s)
      S. Arjoca, E.G. Villora, D. Inomata, K. Aoki, Y. Sugahara, K. Shimamura
    • Journal Title

      Materials Research Express

      Volume: 2 Issue: 5 Pages: 0555031-9

    • DOI

      10.1088/2053-1591/2/5/055503

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Single-Crystal Phosphors for High-Brightness White LEDs and LDs2015

    • Author(s)
      E. G. Villora, S. Arjoca, D. Inomata, K. Aoki, K. Shimamura
    • Journal Title

      日本結晶成長学会誌

      Volume: 42 Pages: 119-129

    • NAID

      40020842531

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ce:(Y1-xLux )3Al5O12 single-crystal phosphor plates for high-brightness white LEDs/LDs with high-color rendering (Ra > 90) and temperature stability2014

    • Author(s)
      Stelian Arjoca, Encarnacion G Villora, Daisuke Inomata, Kazuo Aoki, Yoshiyuki Sugahara and Kiyoshi Shimamura
    • Journal Title

      Mat. Res. Exp.

      Volume: 1 Issue: 2 Pages: 025041-025041

    • DOI

      10.1088/2053-1591/1/2/025041

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] β-Ga2O3 and single-crystal phosphors for high-brightness white LEDs & LDs, and β-Ga2O3 potential for next generation of power devices2014

    • Author(s)
      E.G.Villora, S.Arjoca, K.Shimamura, D.Inomata and K. Aoki
    • Journal Title

      Proceedings of SPIE Photonic West

      Volume: 8787U Pages: 1-12

    • DOI

      10.1117/12.2039305

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Single Crystal Phosphors for High-Power White LEDs and LDs2016

    • Author(s)
      K. Shimamura, E.G. Villora, S. Arjoca, D. Inomata, K. Aoki, J. Hayashi
    • Organizer
      Phosphor Global Summit 2016
    • Place of Presentation
      California, USA
    • Year and Date
      2016-03-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single Crystal phosphors for high-brightness white LEDs/LDs2016

    • Author(s)
      E.G. Villora, S. Arjoca, D. Inomata, K. Shimamura
    • Organizer
      SPIE Photonics West 2016
    • Place of Presentation
      San Fransisco, USA
    • Year and Date
      2016-02-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel single crystals for eletro-optical application2016

    • Author(s)
      K. Shimamura, E.G. Villora and N. Ohashi
    • Organizer
      40th International Conference and Expo on Advanced Ceramics
    • Place of Presentation
      Daytona Beach, USA
    • Year and Date
      2016-01-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single Crystal Phosphors for High-Power LEDs and LDs2015

    • Author(s)
      K. Shimamura, E.G. Villora, S. Arjoca, D. Inomata, K. Aoki and J. Hayashi
    • Organizer
      5th workshop NIMS-UR1-CNRA-Saint Gobain
    • Place of Presentation
      Rennes, France
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Electro-Optic Single Crystal Materials2015

    • Author(s)
      K. Shimamura, E.G. Villora
    • Organizer
      9th International Physics Conference of the Balkan Physical Union
    • Place of Presentation
      Istanbul, Turkey
    • Year and Date
      2015-08-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Electro-Optoc Single Crystal Materials2015

    • Author(s)
      K. Shimamura, E.G. Villora
    • Organizer
      The 7th International Conference on Information Optics and Photonics
    • Place of Presentation
      Nanjing, China
    • Year and Date
      2015-07-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Yellow-Green phosphors based on Ce:(Y,Lu)AG single-crystals for high-brightness / high-power white LEDs & LDs2015

    • Author(s)
      E. G Villora, S. Arjoca and K. Shimamura
    • Organizer
      MCARE2015
    • Place of Presentation
      Jeju Korea
    • Year and Date
      2015-02-24 – 2015-02-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Garnet singke crystals for efficient phosphor and optical isolator applications2015

    • Author(s)
      K.Shimamura, and E.G.Villora
    • Organizer
      39th International Conference and Expo on Advanced Ceramics and Composites
    • Place of Presentation
      Florida, USA
    • Year and Date
      2015-01-25 – 2015-01-30
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Temperature dependence of single-crystal phosphors for high-brightness/high-power white LEDs/LDs2014

    • Author(s)
      Stelian Arjoca, Encarnacion G Villora, Daisuke Inomata, Kazuo Aoki, Yoshiyuki Sugahara and Kiyoshi Shimamura
    • Organizer
      Japan Electronic Materials Society (JEMS) Conference
    • Place of Presentation
      Tokyo
    • Year and Date
      2014-11-13
    • Related Report
      2014 Research-status Report
  • [Presentation] NOVEL SINGLE CRYSTALS FOR EFFICIENT OPTICAL ISOLATOR AND PHOSPHORS APPLICATION2014

    • Author(s)
      K. Shimamura and E. G. Villora
    • Organizer
      2014ISCGCT
    • Place of Presentation
      Wonju Korea
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Temperature dependence of emission in Ce:YAG single-crystal phosphors for HB wLEDs2014

    • Author(s)
      Stelian Arjoca, Encarnacion G Villora, Daisuke Inomata, Kazuo Aoki, Yoshiyuki Sugahara and Kiyoshi Shimamura
    • Organizer
      NCCG-14 (Japan National Conference for Crystal Growth)
    • Place of Presentation
      Tokyo
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Garnet single crystals for efficient optical isolator and phosphor application2014

    • Author(s)
      K. Shimamura, E.G. Villora and S. Arjoca
    • Organizer
      The 4th NIMS-UR1Workshop 2014
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2014-10-27 – 2014-10-29
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Single Crystal Phosphors for High-Brightness White LEDs and LDs2014

    • Author(s)
      K. Shimamura, E.G. Villora, S. Arjoca, D. Inomata, K.Aoki, J. Hayashi
    • Organizer
      MS&T14
    • Place of Presentation
      Pittsburgh, USA
    • Year and Date
      2014-10-12 – 2014-10-16
    • Related Report
      2014 Research-status Report
  • [Presentation] High-brightness and high color rendering index white LEDs/LDs based on Ce:(Y,Lu)AG single-crystal phosphors2014

    • Author(s)
      Stelian Arjoca, Encarnacion G Villora, Daisuke Inomata, Kazuo Aoki, Yoshiyuki Sugahara and Kiyoshi Shimamura
    • Organizer
      The Electrochemical Society of Japan
    • Place of Presentation
      Sapporo
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Single Crystal Phosphors for High-Brightness White LEDs and LDs2014

    • Author(s)
      K.Shimamura, E.G.Villora, S.Arjoca, D.Inomata,K.Aoki,and J.hayashi
    • Organizer
      The 17th International Conference on Luminescence
    • Place of Presentation
      Walclaw Poland
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Ce:(Y1-xLux)3Al5O12 SHINGLE CRYSTAL PHOSPHORS FOR HIGH-BRIGHTNESS WHITE LEDS2014

    • Author(s)
      K.Shimamura, E.G.Villira, S.Arjoca, D.Inomata, K.Aoki, and J.Hayashi
    • Organizer
      The 14th International Balkan Workshop on Applied Physics
    • Place of Presentation
      Constanta, Romania
    • Year and Date
      2014-07-02 – 2014-07-04
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] High-brightness and high color rendering white LEDs/LDs based on Ce:(Y1-xLux)3Al5O12 single-crystal phosphor plates2014

    • Author(s)
      Stelian Arjoca, Encarnacion G Villora, Daisuke Inomata, Kazuo Aoki, Yoshiyuki Sugahara and Kiyoshi Shimamura
    • Organizer
      STAC-8 (The Eighth International Conference on the Science and Technology for Advanced Ceramics)
    • Place of Presentation
      Yokohama
    • Year and Date
      2014-06-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Bulk single crystal growth of oxides and fluorides for optical applications2014

    • Author(s)
      K. Shimamura, and E. G. Villora
    • Organizer
      CIMTEC 2014/ 13th International Ceramics Congress
    • Place of Presentation
      Tuscany, Italy
    • Year and Date
      2014-06-08 – 2014-06-20
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] High-brightness and high color rendering white LEDs/LDs based on Ce:(Y1-xLux)3Al5O12 single-crystal phosphor plates2014

    • Author(s)
      Stelian Arjoca, Encarnacion G Villora, Daisuke Inomata, Kazuo Aoki, Yoshiyuki Sugahara and Kiyoshi Shimamura
    • Organizer
      Materials Science Society of Japan Annual Meeting
    • Place of Presentation
      Tokyo
    • Year and Date
      2014-06-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Development of electro-optical single crystals for energy saving2014

    • Author(s)
      Kiyoshi Shimamura and Encarnacion G. Villora
    • Organizer
      38th International Conference and Exposition on Advanced Ceramics and Composites
    • Place of Presentation
      Daytona Beach Florida, USA
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Crystal growth of novel single crystals for electro-optical applications2013

    • Author(s)
      Kiyoshi Shimamura and Encarnacion G. Villora
    • Organizer
      17th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Warsaw, Poland
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Crystal growth and optical characteristics of novel single crystals2013

    • Author(s)
      Kiyoshi Shimamura and Encarnacion G. Villora
    • Organizer
      CST International Symposium 2013 on Inorganic Functional Materials for Constructing a Sustainable Development
    • Place of Presentation
      日本大学理工学部
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Crystal growth and optical characteristics of novel single crystals2013

    • Author(s)
      Kiyoshi Shimamura and Encarnacion G. Villora
    • Organizer
      The 3rd NIMS-UR1 Workshop
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Research-status Report
    • Invited
  • [Remarks] 蛍光体単結晶

    • URL

      http://www.nims.go.jp/group/oscg/research/YAG.html

    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 蛍光体含有部材及び発光装置2014

    • Inventor(s)
      島村 清史、ガルシア ビジョラ エンカルナシオン アントニア、他
    • Industrial Property Rights Holder
      島村 清史、ガルシア ビジョラ エンカルナシオン アントニア、他
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-09-18
    • Acquisition Date
      2015-05-22
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] YAG単結晶の製造方法2014

    • Inventor(s)
      島村清史、E.G.Villora、東海林利男、福岡昭弘、林潤一他
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、東海林利男、福岡昭弘、林潤一他
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-109581
    • Filing Date
      2014-05-27
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 蛍光体及び発光装置2014

    • Inventor(s)
      島村清史、E.G.Villora、渡邊誠、猪俣大介、青木和夫
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、渡邊誠、猪俣大介、青木和夫
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-191774
    • Filing Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 単結晶蛍光体及び発光装置2014

    • Inventor(s)
      島村清史、E.G.Villora、猪股大介、新井祐輔、青木和夫他
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、猪股大介、新井祐輔、青木和夫他
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-189952
    • Filing Date
      2014-09-18
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 発光装置2014

    • Inventor(s)
      島村清史、E.G.Villora、猪股大介、佐野広明、青木和夫他
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、猪股大介、佐野広明、青木和夫他
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-08-08
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 単結晶蛍光体及び発光装置2014

    • Inventor(s)
      島村清史、E.G.Villora、猪股大介、新井祐輔、青木和夫他
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、猪股大介、新井祐輔、青木和夫他
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-10-22
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 単結晶蛍光体及び発光装置2014

    • Inventor(s)
      島村清史、E.G.Villora、猪股大介、青木和夫
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、猪股大介、青木和夫
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-10-20
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 単結晶蛍光体及び発光装置2013

    • Inventor(s)
      島村清史、E.G.Villora、猪股大介、新井祐輔、青木和夫他
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、猪股大介、新井祐輔、青木和夫他
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-10-23
    • Acquisition Date
      2014-09-26
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 蛍光体及びその製造方法、並びに発光装置2013

    • Inventor(s)
      島村清史、E.G.Villora、渡邊誠、猪俣大介、青木和夫
    • Industrial Property Rights Holder
      島村清史、E.G.Villora、渡邊誠、猪俣大介、青木和夫
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-18
    • Acquisition Date
      2014-11-21
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 単結晶蛍光体及び発光装置2013

    • Inventor(s)
      ガルシアビジョラエンカルナシオンアントニア/島村清史/他
    • Industrial Property Rights Holder
      ガルシアビジョラエンカルナシオンアントニア/島村清史/他
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-220681
    • Filing Date
      2013-10-23
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 単結晶蛍光体及び発光装置2013

    • Inventor(s)
      島村清史/ガルシアビジョラエンカルナシオンアントニア/他
    • Industrial Property Rights Holder
      島村清史/ガルシアビジョラエンカルナシオンアントニア/他
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-220682
    • Filing Date
      2013-10-23
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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