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Fabrication of new material controlled composition and structure using external field and analysis of mechanism

Research Project

Project/Area Number 25420709
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionToyohashi University of Technology

Principal Investigator

NAKANO Hiromi  豊橋技術科学大学, 研究基盤センター, 教授 (00319500)

Co-Investigator(Kenkyū-buntansha) SUZUKI Tohru  物質・材料研究機構, 先端材料プロセスユニット, 主席研究員 (50267407)
Co-Investigator(Renkei-kenkyūsha) MABUCHI Mamoru  京都大学, エネルギー科学研究科, 教授 (00358061)
Research Collaborator SAJI Tasaburo  ミリ波研究所, 研究者
MIYAKE Shoji  大阪大学, 名誉教授
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords構造・組織制御 / 粒子配向 / ミリ波加熱法 / 高磁場 / TEM / 構造・組成制御 / ミリ波 / 蛍光体材料 / 配向 / TEM / 配向異方性材料 / ミリ波合成
Outline of Final Research Achievements

We fabricated new materials controlled composition and structure using external fields to promote the property and/or obtain new property. As the external-field, millimeter-wave field for green-processing and high-magnetic field for grain orientation are used in our experiment. The obtained materials were characterized by several analytical devices (TEM, SEM, XRD-Rietveld, etc) and simulated by a first-principles calculation. The mechanism for the property and the relationship between property and crystal structure were clarified. In the experimental period, we published numerous papers about new materials.We expect that our investigation will have an influence on the inorganic material field.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (50 results)

All 2016 2015 2014 2013 Other

All Journal Article (18 results) (of which Peer Reviewed: 17 results,  Open Access: 8 results,  Acknowledgement Compliant: 8 results) Presentation (28 results) (of which Invited: 5 results) Book (1 results) Remarks (3 results)

  • [Journal Article] Enhancement of photoluminescence intensity and structural change by doping of P5+ ion for Ca2-x/2(Si1-xPx)O4:Eu2+ green phosphor2016

    • Author(s)
      S. Furuya, H.Nakano, N. Yokoyama, H. Banno, K. Fukuda
    • Journal Title

      J. Alloys and Compd.

      Volume: 658 Pages: 147-151

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis and Photoluminescence of New Phosphor Ba0.79Al10.9O17.14:Eu2+”2016

    • Author(s)
      S. Furuya, A. Okuzumi, H. Nakano
    • Journal Title

      J. Soc. of Powder Tech., Jpn.

      Volume: 53 Pages: 226-280

    • NAID

      130005153275

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 新規蛍光体材料とダイバーシティ社会に向けて2016

    • Author(s)
      中野裕美
    • Journal Title

      東三河懇話会会報誌

      Volume: 70 Pages: 6-7

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Crystal structures and enhancement of photoluminescence intensities by effective doping for lithium tantalate phosphors2015

    • Author(s)
      H. Ichioka, S.Furuya, T. Asaka, H. Nakano, and K. Fukuda
    • Journal Title

      Powder Diffr. J.

      Volume: 30(4) Pages: 326-332

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Microstructural comparison between Nb- and Ta-systems in Li1+x-yM1-x-3yTix+4yO3 (M = Nb5+, Ta5+) solid solution with superstructure2015

    • Author(s)
      H. Nakano, S. Suehiro, S. Furuya, K. Fukuda,
    • Journal Title

      J. Alloy. Compd.,

      Volume: 618 Pages: 504-507

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Extraordinary diffusion in Co/Cu grain boundaries2015

    • Author(s)
      H. Nakano, M. Yuasa, H. Miyamoto, N. Miyazawa, M. Mabuchi
    • Journal Title

      Scripta Mater.,

      Volume: 101 Pages: 52-55

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Microstructural comparison between Nb- and Ta-systems in Li1+x-yM1-x-3yTix+4yO3 (M = Nb5+, Ta5+) solid solution with superstructure2015

    • Author(s)
      H. Nakano, S. Suehiro, S. Furuya, K. Fukuda
    • Journal Title

      J. Alloy. Compd.

      Volume: 618 Pages: 504-507

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis and structural analysis of Li1+x-yM1-x-3yTix+4yO3 (M: Ta, Nb) solid solutions with superstructure2014

    • Author(s)
      S. Suehiro, H. Nakano
    • Journal Title

      J. Soc. Powder. Tech., Jpn.

      Volume: 51 (3) Pages: 136-141

    • NAID

      130004545886

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and luminescence enhancement of Eu3+, Sm3+ co-doped Li1.11Ta0.89Ti0.11O3 phosphor2014

    • Author(s)
      H. Nakano, S. Furuya, K. Fukuda, S. Yamada
    • Journal Title

      Mater. Res. Bull.

      Volume: 60 Pages: 766-770

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] {10-12} twins in rolled Mg-Zn-Ca alloy with high formability2014

    • Author(s)
      H. Nakano, M. Yuasa, M. Mabuchi, Y. Chino
    • Journal Title

      J. Mater. Res.

      Volume: 29(24) Pages: 3024-3031

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 白色LED用近紫外励起赤色蛍光体の創成と母体構造の特徴2014

    • Author(s)
      中野裕美、福田功一郎
    • Journal Title

      ケミカルエンジニアリング

      Volume: 49(12) Pages: 1-5

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Synthesis of a rare-earth doped LNT (Li-Nb-Ti-O) phosphor by millimeter-wave heating2013

    • Author(s)
      H. Nakano, S. Suehiro, T. Saji, and S. Miyake
    • Journal Title

      J. Alloys and Compds.

      Volume: 552 Pages: 475-479

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure and Oxide-Ion Diffusion of Nano-Crystalline,Compositionally Homogeneous Ceria-Zirconia Ce0.5Zr0.5O2 up to 1176 K2013

    • Author(s)
      M. Yashima , T. Sekikawa , D. Sato , H. Nakano , and K. Omoto
    • Journal Title

      Cryst. Growth and Design

      Volume: 13(2) Pages: 829-837

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Rapid synthesis of Eu3+-doped LNT (Li-Nb-Ti-O) phosphor by millimeter-wave heating2013

    • Author(s)
      H. Nakano, K. Ozono, T. Saji, S. Miyake, H. Hayashi
    • Journal Title

      Opt. Mater.

      Volume: 35 Pages: 2045-2048

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of new RE3+ doped Li1+xTa1-xTixO3 (RE: Eu, Sm, Er, Tm, and Dy) phosphors with various emission colors2013

    • Author(s)
      H. Nakano, S. Suehiro, S. Furuya, H. Hayashi, and S. Fujihara
    • Journal Title

      Materials

      Volume: 6 Pages: 2768-2776

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Syntheses and crystal structures of Li(Ta0.89Ti0.11)O2.945 and (Li0.977Eu0.023)(Ta0.89Ti0.11)O2.9682013

    • Author(s)
      T. Uchida, S. Suehiro, T. Asaka, H. Nakano, K. Fukuda
    • Journal Title

      Powder Diffraction Journal

      Volume: 28(3) Pages: 178-183

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and structural analysis of Li1+x-yM1-x-3yTix+4yO3(M: Ta, Nb)solid solutions with superstructure2013

    • Author(s)
      S. Suehiro, H. Nakano
    • Journal Title

      Journal of the Society of Powder Technology

      Volume: 51(3) Pages: 136-141

    • NAID

      130004545886

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Softening due to disordered grain boundaries in nanocrystalline Co2013

    • Author(s)
      M. Yuasa, M. Hakamada, H. Nakano, M. Mabuchiand Y.Chino
    • Journal Title

      J. Phys.: Condens. Matter

      Volume: 25(34)

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ミリ波加熱法によるセラミックス蛍光体合成への応用と課題2016

    • Author(s)
      中野裕美
    • Organizer
      EMAP 研究会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-18
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 組成・構造制御によるBa-Al-O系新蛍光体材料の合成2016

    • Author(s)
      古谷彰平,奥住明日香,楠美智子,林裕之,中野裕美
    • Organizer
      日本セラミックス協会年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 36.錯体重合法を用いたZn2TixSn1−xO4:Eu (0≤x≤1) 蛍光体の合成2016

    • Author(s)
      平靖之,中村稀星,寺澤みゆり,中野裕美
    • Organizer
      日本セラミックス協会年会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 研究は正確な観察・解析からはじまる2016

    • Author(s)
      中野裕美
    • Organizer
      若手研究者・技術者を対象とした工場見学および交流会 化学工学会
    • Place of Presentation
      三井化学(株)名古屋工場厚生会館
    • Year and Date
      2016-01-19
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 37.シリケート蛍光体 (Ca2-x/2-yEuy□x/2)(Si1-xPx)O4の結晶構造制御と緑色発光強度2015

    • Author(s)
      横山宣幸,古谷彰平,中野裕美,坂野広樹,福田功一郎
    • Organizer
      日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-12-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] 組成制御によるBa-Al-O系新蛍光体材料の合成と評価2015

    • Author(s)
      奥住明日香,古谷彰平,中野裕美
    • Organizer
      粉体工学会秋期研究発表会
    • Place of Presentation
      大阪南港ATC
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 39.c-軸配向Si3N4セラミックスの異方的な焼結収縮挙動と微構造発達2015

    • Author(s)
      高橋 拓実,多々見 純一,田中 諭,中野 裕美
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 40.緑色発光シリケート蛍光体 (Ca2-x/2(Si1-xPx)O4: Eu2+) のP5+イオン添加による発光強度向上と結晶構造変化2015

    • Author(s)
      横山宣幸,古谷彰平,中野裕美,坂野広樹,福田功一郎
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 41.近紫外及び青色励起Li1.11Ta0.89Ti0.11O3:Eu3+ 赤色蛍光体のSm3+恭添加による発光強度向上とそのメカニズム2015

    • Author(s)
      古谷彰平,中野裕美,林裕之,福田功一郎
    • Organizer
      セラミック材料部門委員会学術講演会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2015-07-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 42.共沈法を用いたZn2TixSn1-xO4:Eu (o < x < 1) 蛍光体の合成2015

    • Author(s)
      平靖之,三村和仙,中野裕美
    • Organizer
      セラミック材料部門委員会学術講演会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2015-07-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 液相法を用いたZn2TixSn1−xO4:Eu (0≤x≤1) 蛍光体の合成2015

    • Author(s)
      平靖之・三村和仙・中村稀星・鈴木瞭汰・中野裕美
    • Organizer
      日本セラミックス協会 年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 近紫外線励起赤色蛍光体Li(Ta0.89Ti0.11)O2.945:Sm3+のMgO添加発光特性の向上と結晶構造2015

    • Author(s)
      市岡裕晃・古谷彰平・中野裕美・浅香透・福田功一郎・中野裕美
    • Organizer
      日本セラミックス協会 年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 超構造を形成するLi(- M, Sb)-Ti-O(M: Nb, Ta)系固溶体と赤色蛍光体の合成2015

    • Author(s)
      末廣志穂・古谷彰平・中野裕美・林裕之
    • Organizer
      日本セラミックス協会 年会
    • Place of Presentation
      岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 赤色蛍光体Li1.11Ta0.89Ti0.11:Eu3+の共添加(Sm3+ or Pr3+)による発光強度向上2014

    • Author(s)
      古谷彰平, 横山宣幸, 中野裕美,林裕之, 山田鈴弥
    • Organizer
      日本セラミックス協会 東海支部学術講演会
    • Place of Presentation
      名工大
    • Year and Date
      2014-12-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis and luminescence property of Li1.11Ta0.89Ti0.11O3: Eu3+, Sm3+ red phosphor2014

    • Author(s)
      Hiromi Nakano, Syohei Furuya, Suzuya Yamada
    • Organizer
      K-J ceramics 31
    • Place of Presentation
      Changwon, Korea
    • Year and Date
      2014-11-26 – 2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis and luminescence property of RE3+doped Li1.11(Ta1-zNbz)0.89Ti0.11O3 (0 < z <1.0, RE: Sm, Dy, Tm or Er) phosphor2014

    • Author(s)
      Syohei Furuya1, Hiromi Nakano, Hiroyuki Hayashi, Suzuya Yamada
    • Organizer
      K-J ceramics 31
    • Place of Presentation
      Changwon, Korea
    • Year and Date
      2014-11-26 – 2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 近紫外励起Li-Ta-Ti-O系赤色蛍光体のSm3+共添加による発光強度向上2014

    • Author(s)
      古谷彰平・中野裕美・福田功一郎・山田鈴弥
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Research-status Report
  • [Presentation] Nanoscale phenomena by in-situ TEM observation2014

    • Author(s)
      H. Naknao
    • Organizer
      ELECTROCERAM XIV
    • Place of Presentation
      Bucharest
    • Year and Date
      2014-06-16 – 2014-06-20
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Synthesis of c-axis oriented LNT(Li-Nb-Ti-O)solid solution for anisotropic electric property2014

    • Author(s)
      Suehiro, H. Nakano, T. Suzuki
    • Organizer
      ELECTROCERAM XIV
    • Place of Presentation
      Bucharest
    • Year and Date
      2014-06-16 – 2014-06-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 蛍光体セラミックスのミリ波加熱法による低温短時間合成に関する研究2014

    • Author(s)
      中野裕美、佐治他三郎、三宅正司
    • Organizer
      第52回セラミックス基礎科学討論会
    • Place of Presentation
      ウインクあいち
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 高配向LNT セラミックス作製のための粉砕条件の検討2014

    • Author(s)
      末廣志穂・中野裕美・武田忠彦・木村善衛・鈴木達・目義雄
    • Organizer
      日本セラミックス協会年会
    • Place of Presentation
      慶應大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 構造制御されたLi-M-Ti-O系(M:Ta, Nb) 固溶体の合成と構造解析2013

    • Author(s)
      中野裕美、末廣志穂
    • Organizer
      第49回夏期シンポジウム講演
    • Place of Presentation
      ホテルマウント富士
    • Related Report
      2013 Research-status Report
  • [Presentation] 近紫外励起用蛍光体の発光特性に及ぼすMgO添加効果2013

    • Author(s)
      古谷彰平・末廣志穂・中野裕美・林裕之・山田鈴弥
    • Organizer
      第26回秋季シンポジウム
    • Place of Presentation
      信州大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Li-M-Ti-O (M:Nb,Ta)系固溶体を母体とした近紫外励起蛍光体の合成2013

    • Author(s)
      古谷彰平、末廣志穂、中野裕美、林裕之、山田鈴弥
    • Organizer
      日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名城大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of textured LiNbTiO3 solid solution in a high magnetic field and sintering by millimeter-wave heating2013

    • Author(s)
      H, Nakano, S.Shiho, T. Susuki, T. Saji, S. Miyake
    • Organizer
      Intl’ Conf. on Processing and manufacturing of advanced materials (THERMEC)
    • Place of Presentation
      ラスベガス(USA)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Synthesis and structural analysis of Li2O-Ta2O5-TiO2 (LTT) phosphor2013

    • Author(s)
      S. Suehiro, H. Nakano, T. Uchida, T. Asaka, and K. Fukuda
    • Organizer
      ECERS2013
    • Place of Presentation
      リモージュ(フランス)
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis and structural analysis of Li1+x-yM1-x-3yTix+4yO3(M:Ta, Nb)solid solutions with superstructure2013

    • Author(s)
      S. Suehiro and H. Nakano
    • Organizer
      ECERS2013
    • Place of Presentation
      リモージュ(フランス)
    • Related Report
      2013 Research-status Report
  • [Presentation] Preparation of oriented Li1+x-yNb1-x-3yTix+4yO3 solid solution with superstructure by slip casting in a high magnetic field2013

    • Author(s)
      H. Nakano, S. Suehiro, Tohru S. Suzuki and Yoshio Sakka
    • Organizer
      ECERS2013
    • Place of Presentation
      リモージュ(フランス)
    • Related Report
      2013 Research-status Report
  • [Book] 新版 入門機器分析化学2015

    • Author(s)
      編著者, 庄野利之脇田久伸ほか(共著)
    • Total Pages
      251
    • Publisher
      三共出版
    • Related Report
      2015 Annual Research Report
  • [Remarks] 豊橋技術科学大学 無機材料研究室 研究活動

    • URL

      http://www.crfc.tut.ac.jp/nakano/index.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] 無期材料研究室中野Lab

    • URL

      http://www.crfc.tut.ac.jp/nakano/

    • Related Report
      2014 Research-status Report
  • [Remarks] 無機材料研究室 中野Lab.

    • URL

      http://www.crfc.tut.ac.jp/nakano/written.html

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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