| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Outline of Final Research Achievements |
Zinc(II) dithiocarbamate complexes having terminal carboxyl moieties which were derived from amino acids behave as a bridging ligand, and can give a novel porous coordination polymer with flexible structure from the reaction with zinc(II) or nickel(II) ions in solution.
Further, novel porous inorganic/organic hybrids can be obtained from the reactions of these zinc complexes with polymers possessing hydrogen acceptors such as polyvinylpyridine or polyvinylpyrrolidone through intermolecular hydrogen bonding. It is also found that crystals of the complexes can be grown onto the surface of such polymers.
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