Immobilization of crystalline nano-porous structures on the surface of solid materials
| Project/Area Number |
25420719
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic materials/Physical properties
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| Research Institution | Osaka Institute of Technology |
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Principal Investigator |
NOMURA Ryoki 大阪工業大学, 工学部, 教授 (00156233)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 柔軟な多孔性配位高分子 / アミノ酸骨格 / 相補的水素結合 / ジチオカーバマート錯体 / ポリビニルピリジン / ポリビニルピロリドン / 無機／有機複合体 / 水素結合 / 機能高分子 / 無機／有機複合材料 / ジチオカー^バマート錯体 / アミノ酸残基 / 異核多孔姓錯体 / 固体表面 / 共結晶形成 / 分子間水素結合 / アミノ酸 / 異核多孔性錯体 / 透過赤外分光法 / 水素終端化 / OH終端化 |
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| Outline of Final Research Achievements |
Zinc(II) dithiocarbamate complexes having terminal carboxyl moieties which were derived from amino acids behave as a bridging ligand, and can give a novel porous coordination polymer with flexible structure from the reaction with zinc(II) or nickel(II) ions in solution.
Further, novel porous inorganic/organic hybrids can be obtained from the reactions of these zinc complexes with polymers possessing hydrogen acceptors such as polyvinylpyridine or polyvinylpyrrolidone through intermolecular hydrogen bonding. It is also found that crystals of the complexes can be grown onto the surface of such polymers.
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Report
(4 results)
Research Products
(13 results)
