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Development of transparent conductive materials from composites of conductive polymers and graphene

Research Project

Project/Area Number 25420727
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionNagoya Industrial Science Research Institute (2015)
Nagoya University (2013-2014)

Principal Investigator

Konagaya Shigeji  公益財団法人名古屋産業科学研究所, その他部局等, 研究員 (30418785)

Co-Investigator(Renkei-kenkyūsha) YAMADA Toshiro  金沢大学, 自然システム学系, 教授 (60272952)
SANADA Kazuaki  富山県立大学, 工学部, 准教授 (20363872)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords導電性高分子 / 酸化グラフェン / 複合材料 / 透明導電 / ポリアニリン / PEDOT / 薄膜 / 熱還元 / グラフェン / フェノール / 導電性 / 透明性 / 透明導電膜 / セルロースナノファイバー
Outline of Final Research Achievements

The effect of graphene oxide (GO) content and heat treatment temperature on the conductivity of the composites from conductive polymers such as poly(aniline)(PANI) doped with dodecylbenzene sulfonic acid (DBSA), poly(aniline sulfonic acid) and poly(3,4-ethylenedioxythiophene) (PEDOT) doped with poly(stylene sulfonic acid) (PSS) and GO was studied. It was found that the moderate ratio of above conductive polymer to GO and higher heat treatment temperature than 150℃ enhanced the conductivity of the composites such as PANI:DBSA/GO, PAS/GO and PEDOT:PSS/GO. It was made clear that such conductivity enhancement resulted from the increase of C(sp2) bonds due to O-removal reaction of GO, which was promoted by sulfonic acid group (SO3H) as a dopant.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (24 results)

All 2016 2015 2014 2013

All Journal Article (6 results) (of which Peer Reviewed: 3 results) Presentation (9 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Book (1 results) Patent(Industrial Property Rights) (8 results) (of which Overseas: 3 results)

  • [Journal Article] 表面修飾シリカナノ粒子が導電性高分子複合材に与える導電性向上効果について2016

    • Author(s)
      大澤六合豊、小長谷重次、山田敏郎、多田薫、沼田修
    • Journal Title

      成形加工

      Volume: 28 Pages: 75-81

    • NAID

      130006647047

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 導電性フィルムの開発動向2015

    • Author(s)
      小長谷重次
    • Journal Title

      プラスチックスエージ

      Volume: 61 Pages: 45-50

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Influence of Cellulose Nano-Fiber Diameter on Conductivity of Poly(Aniline Sulfonic Acid) Composites2013

    • Author(s)
      Shigeji Konagaya, Kanehiro Shimizu, Mariko Terada, Toshirou Yamada,
    • Journal Title

      Proceedings of 13th Japan international SAMPE symposium and exhibition in Nagoya

      Volume: 2013 Pages: 1-5

    • Related Report
      2013 Research-status Report
  • [Journal Article] Conductivity of Poly (3, 4-EthyleneDioxy Thiophene): Poly (Styrene Sulfonic Acid) / Cellulose Nano-Fiber Composites2013

    • Author(s)
      Shigeji Konagaya, Mariko Terada, Hiroki Atago, Toshirou Yamada
    • Journal Title

      Proceedings of 13th Japan international SAMPE symposium and exhibition in Nagoya

      Volume: 2013 Pages: 1-6

    • Related Report
      2013 Research-status Report
  • [Journal Article] Effect of cellulosic nano-fiber on conductivity of PEDOT:PSS composites2013

    • Author(s)
      Shigeji Konagaya, Hiroki Atago, Mariko Terada, Toshirou Yamada
    • Journal Title

      Proceedings of 29th international conference of the Polymer Processing Society July 15-19, 2013, Nuremberg (Germany)

      Volume: 2013 Pages: 1-5

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of diameter of cellulosic nano-fiber on conductivity of poly(aniline sulfonic acid) composites2013

    • Author(s)
      Shigeji Konagaya, Kanehiro Shimizu, Mariko Terada, Toshirou Yamada
    • Journal Title

      Proceedings of 29th international conference of the Polymer Processing Society July 15-19, 2013, Nuremberg (Germany)

      Volume: 2013 Pages: 1-5

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Effect of heat treatment on conductivity of doped poly(aniline)/graphene oxide(GO) composites2015

    • Author(s)
      S. Konagaya, M.Terada
    • Organizer
      20th International Conference on Composite Materials (ICCM20)
    • Place of Presentation
      Copenhagen, Denmark
    • Year and Date
      2015-07-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Conductivity Enhancement of Conductive Polymer Composites by Addition of Cellulose Nano-Fiber(CeNF)2015

    • Author(s)
      S. Konagaya
    • Organizer
      World Congress and Expo on Nanotechnology and Materials Science
    • Place of Presentation
      Dubai UAE
    • Year and Date
      2015-04-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] PEDOT:PSSとフェノール誘導体の複合化による高導電性透明導電膜の開発2015

    • Author(s)
      俵由一、小長谷重次
    • Organizer
      2014年度分子・物質合成プラットフォームシンポジウム
    • Place of Presentation
      名古屋大学ES館(名古屋)
    • Year and Date
      2015-03-05 – 2015-03-06
    • Related Report
      2014 Research-status Report
  • [Presentation] PEDOT:PSSとフェノール誘導体の複合化による高導電性透明導電膜の開発2014

    • Author(s)
      俵由一、小長谷重次
    • Organizer
      第22回フィラーシンポジウム
    • Place of Presentation
      ニューウェルシティ湯河原(熱海)
    • Year and Date
      2014-11-20 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] PEDOT:PSSとフェノール誘導体の複合化による高導電性透明導電膜の開発2014

    • Author(s)
      俵由一、小長谷重次
    • Organizer
      第23回ポリマー材料フォーラム
    • Place of Presentation
      奈良県新公会堂(奈良)
    • Year and Date
      2014-11-06 – 2014-11-07
    • Related Report
      2014 Research-status Report
  • [Presentation] Conductivity Enhancement of Doped Polyaniline by Graphene Oxide (GO)2014

    • Author(s)
      S. Konagayaa, M. Terada, M. Sunahara, T. Yamada
    • Organizer
      ACS 2014 Fall
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2014-08-10 – 2014-08-14
    • Related Report
      2014 Research-status Report
  • [Presentation] Conductivity enhancement of conductive polymer composites2014

    • Author(s)
      S. Konagaya, K. Shimizu, T. Yamada, M. Terada
    • Organizer
      ICBMC’14
    • Place of Presentation
      Montreal (Canada)
    • Year and Date
      2014-05-13 – 2014-05-16
    • Related Report
      2014 Research-status Report
  • [Presentation] セルロースナノファイバー(CeNF)充填導電性高分子複合材料の導電性2013

    • Author(s)
      清水 金洋,小長谷 重次,山田 敏郎,多田 薫,寺田 真利子
    • Organizer
      第20回秋季大会 成形加工学会シンポジア
    • Place of Presentation
      倉敷市芸文館
    • Related Report
      2013 Research-status Report
  • [Presentation] セルロースナノファイバー(CeNF)充填導電性高分子複合材料の導電性2013

    • Author(s)
      清水 金洋,小長谷 重次,山田 敏郎,多田 薫,寺田 真利子
    • Organizer
      第21回フィラーシンポジウム
    • Place of Presentation
      ホテル・グランテラス富山
    • Related Report
      2013 Research-status Report
  • [Book] 導電性フィラー、導電助剤の分散性向上、評価、応用 第1章 導電性フィラー、導電助剤の概要―種類、特性、用途などー2015

    • Author(s)
      小長谷重次
    • Total Pages
      7
    • Publisher
      技術情報協会
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 透明導電性フィルム及びタッチパネル2015

    • Inventor(s)
      周 宏晃,小長谷重次、俵由一
    • Industrial Property Rights Holder
      日本ゼオン、旭有機材
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-197224
    • Filing Date
      2015-10-02
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 導電性組成物及びその製造方法2015

    • Inventor(s)
      小長谷重次、猿山俊夫、渋谷仁志
    • Industrial Property Rights Holder
      富士高分子工業、名古屋大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 熱伝導性組成物及びその製造方法2015

    • Inventor(s)
      小長谷重次、猿山俊夫、渋谷仁志
    • Industrial Property Rights Holder
      富士高分子工業、名古屋大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 導電膜及びその製造法2015

    • Inventor(s)
      小長谷重次、猿山俊夫、渋谷仁志
    • Industrial Property Rights Holder
      富士高分子工業、名古屋大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-139920
    • Filing Date
      2015-07-13
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 導電性フィルム2014

    • Inventor(s)
      小長谷重次、俵由一
    • Industrial Property Rights Holder
      小長谷重次、俵由一
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-08-19
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] セルロースナノファイバーと微小粒子を主成分とする組成物2014

    • Inventor(s)
      小長谷重次、渋谷仁志、猿山俊夫
    • Industrial Property Rights Holder
      小長谷重次、渋谷仁志、猿山俊夫
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 導電性組成物及びそのコーティング方法と用途2014

    • Inventor(s)
      小長谷重次、渋谷仁志、猿山俊夫
    • Industrial Property Rights Holder
      小長谷重次、渋谷仁志、猿山俊夫
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-12-24
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 導電性組成物及びそのコーティング方法と用途2014

    • Inventor(s)
      小長谷重次、猿山俊夫
    • Industrial Property Rights Holder
      小長谷重次、猿山俊夫
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-028654
    • Filing Date
      2014-02-18
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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