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Developments of environment-friendly semiconductor clathrate for thermoelectric materials and their thermoelectric generator devices

Research Project

Project/Area Number 25420763
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionTokyo University of Science, Yamaguchi

Principal Investigator

ANNO Hiroaki  山口東京理科大学, 工学部, 教授 (60279106)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords未利用熱利用 / 熱電変換 / ゼーベック効果 / シリコン / クラスレート / 同時ドーピング / 熱電的特性 / 機械的特性 / 排熱有効利用 / 同時添加 / ゼーベック係数 / 弾性定数 / 電極接合 / 熱電素子 / 元素置換
Outline of Final Research Achievements

In order to improve the thermoelectric figure of merit for a thermoelectric silicon-based clathrate system, an environment-friendly semiconductor system, we investigated the optimization of the silicon-based clathrate system by a codoping approach, and revealed the effect of parameters of codoping, such as combinations of codoping elements and doping level, on the thermoelectric properties for silicon-based clathrate system. We succeeded in improving the thermoelectric performance by a factor of 17 %, compared to previous value, by the codoping approach. Moreover, we investigated in detail the thermal stability in air, oxidation resistance, elastic properties, and mechanical properties, such as the fracture toughness, Vickers hardness, which were not known for silicon-based clathrate system. Consequently, it was found that silicon-based clathrate system had good thermal stability in air, high oxidation resistance, and sufficient mechanical strength for thermoelectric applications.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (38 results)

All 2016 2015 2014 2013 Other

All Journal Article (8 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 6 results) Presentation (27 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Mechanical Properties of Thermoelectric Ba8Al15Si31 Clathrate Prepared by Combining Arc Melting and Spark Plasma Sintering Techniques2016

    • Author(s)
      Hiroaki Anno, Takahiro Ueda, Shusaku Hirata, Tomoki Kameyama, Tsutomu Iida, and Yasuo Kogo
    • Journal Title

      Journal of Electronic Materials

      Volume: 45 Issue: 3 Pages: 1803-1812

    • DOI

      10.1007/s11664-015-4230-6

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Heat Treatment in Air on Thermoelectric Properties of Polycrystalline Type-I Silicon-Based Clathrate: Ba8Al15Si312015

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Journal Title

      Journal of Electronic Materials

      Volume: 44 Issue: 6 Pages: 1413-1419

    • DOI

      10.1007/s11664-014-3385-x

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] シリコンクラスレートの熱電特性に及ぼす同時ドーピングの効果2015

    • Author(s)
      阿武宏明, 上田貴大, 佐久間裕教
    • Journal Title

      紛体および粉末冶金

      Volume: 62 Pages: 194-199

    • NAID

      130005066966

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Heat Treatment in Air on the Surface of a Sintered Ba8Al16Si30-Based Clathrate2014

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Journal Title

      Journal of Electronic Materials

      Volume: 43 Issue: 6 Pages: 1847-1856

    • DOI

      10.1007/s11664-013-2887-2

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermal stability and oxidation resistance of polycrystalline Ba8Al16Si30-based clathrates2014

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Journal Title

      Physica Status Solidi A

      Volume: 211 Issue: 6 Pages: 1288-1292

    • DOI

      10.1002/pssa.201300145

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of Heat Treatment in Air on Thermoelectric Silicon Clathrate2014

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Journal Title

      Key Engineering Materials

      Volume: 617 Pages: 243-246

    • DOI

      10.4028/www.scientific.net/kem.617.243

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 環境に優しいシリコン・クラスレート熱電材料2013

    • Author(s)
      阿武宏明
    • Journal Title

      金属

      Volume: 83 Pages: 33-39

    • Related Report
      2013 Research-status Report
  • [Journal Article] THERMAL STABILITY AND THERMOELECTRIC PROPERTIES OF SILICON CLATHRATES FOR WASTE HEAT RECOVERY2013

    • Author(s)
      H. ANNO and R. SHIRATAKI
    • Journal Title

      Proceedings of the 24th International Symposium on Transport Phenomena (ISTP-24)

      Volume: なし Pages: 946-951

    • Related Report
      2013 Research-status Report
  • [Presentation] Si系クラスレートにおけるAg置換と熱電特性2016

    • Author(s)
      前島理佐,上田貴大,岡本和也,阿武宏明
    • Organizer
      2016年(平成28年)第63 回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ga-P同時添加によるBa8Al16Si30クラスレートの機械的特性への影響2016

    • Author(s)
      岡本和也,上田貴大,江本優紀,阿武宏明
    • Organizer
      2016年(平成28年)第63 回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] シリコン系クラスレート熱電変換素子の設計と評価2016

    • Author(s)
      江本優紀,岡本和也,阿武宏明
    • Organizer
      山口東京理科大学第16回液晶研究所シンポジウム・第13回先進材料研究所シンポジウム・合同シンポジウム
    • Place of Presentation
      山口東京理科大学(山口県山陽小野田市)
    • Year and Date
      2016-03-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ga-Ag置換Si系クラスレートの熱電気的特性2016

    • Author(s)
      前島理佐,岡本和也,阿武宏明
    • Organizer
      山口東京理科大学第16回液晶研究所シンポジウム・第13回先進材料研究所シンポジウム・合同シンポジウム
    • Place of Presentation
      山口東京理科大学(山口県山陽小野田市)
    • Year and Date
      2016-03-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Si系クラスレートにおける同時ドーピングによる熱電気的および機械的特性への影響2016

    • Author(s)
      上田貴大,岡本和也,阿武宏明
    • Organizer
      山口東京理科大学第16回液晶研究所シンポジウム・第13回先進材料研究所シンポジウム・合同シンポジウム
    • Place of Presentation
      山口東京理科大学(山口県山陽小野田市)
    • Year and Date
      2016-03-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Thermoelectric and mechanical properties of Ba-Al-Si-based clathrates2015

    • Author(s)
      Hiroaki Anno
    • Organizer
      International Conference on Thermoelectric Materials Science 2015 (TMS2015)
    • Place of Presentation
      Nagoya University, Nagoya (Japan)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Elastic Properties, Hardness and Fracture Toughness of Thermoelectric Silicon Clathrate2015

    • Author(s)
      H. Anno, T. Ueda, K. Okamoto, S. Hirata, T. Kameyama, T. Iida, Y. Kogo
    • Organizer
      14th International Union of Materials Research Societies-International Conference on Advanced Materials (IUMRS-ICAM2015)
    • Place of Presentation
      Jeju (Korea)
    • Year and Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノインデンテーション法によるBa8Al15Si31の機械的特性評価2015

    • Author(s)
      上田貴大, 阿武宏明, 亀山知季, 飯田努, 向後保雄, 長谷川宗平, 長塚祐真, 岡本和也
    • Organizer
      2015年 (平成27年)第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ba8Al15Si31 系クラスレートのヤング率およびビッカース硬さの評価2015

    • Author(s)
      上田貴大,阿武宏明,岡本和也,亀山知季,長塚祐真,飯田努,長谷川宗平,向後保雄
    • Organizer
      第12回日本熱電学会学術講演会(TSJ2015)
    • Place of Presentation
      九州大学筑紫地区総合研究棟(福岡県春日市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mechanical properties of thermoelectric Ba8Al15Si31 clathrate2015

    • Author(s)
      H. Anno, T. Ueda, S. Hirata, T. Kameyama, T. Iida, Y. Kogo
    • Organizer
      The 34th Annual International Conference on Thermoelectrics (ICT 2015) and 13th European Conference on Thermoelectrics (ECT 2015)
    • Place of Presentation
      Dresden (Germany)
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ba8Al16Si30系クラスレートにおける同時ドーピング効果2015

    • Author(s)
      上田貴大,佐久間裕教,阿武宏明
    • Organizer
      2015年(平成27年)第62 回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県・平塚市)
    • Year and Date
      2015-03-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Ba8Al16Si30系クラスレート焼結体の機械的特性2015

    • Author(s)
      阿武宏明,上田貴大,平田柊作,藤田恒輝,飯田努,向後保雄
    • Organizer
      2015年(平成27年)第62 回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県・平塚市)
    • Year and Date
      2015-03-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Ba8Al16Si30系クラスレートにおけるGa-P同時ドーピングおよび熱電特性の評価2015

    • Author(s)
      佐久間裕教,上田貴大,阿武宏明
    • Organizer
      山口東京理科大学第15回液晶研究所シンポジウム・第12回先進材料研究所シンポジウム・合同シンポジウム
    • Place of Presentation
      山口東京理科大学(山口県・山陽小野田市)
    • Year and Date
      2015-03-09
    • Related Report
      2014 Research-status Report
  • [Presentation] シリコン系クラスレート熱電変換素子の設計と評価2015

    • Author(s)
      藤田恒輝,上田貴大,阿武宏明
    • Organizer
      山口東京理科大学第15回液晶研究所シンポジウム・第12回先進材料研究所シンポジウム・合同シンポジウム
    • Place of Presentation
      山口東京理科大学(山口県・山陽小野田市)
    • Year and Date
      2015-03-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Rattling Silicide: Ba-Al-Si-Based Clathrates2015

    • Author(s)
      Hiroaki Anno
    • Organizer
      1st Symposium for the Promotion of Applied Reserarch Collaboration in Asia (SPARCA2015)
    • Place of Presentation
      Sunworld Dynasty Hotel, Taipei (Taiwan)
    • Year and Date
      2015-02-09
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Ba8AlxSi46-xクラスレートの熱電特性に及ぼす同時ドーピングの効果2014

    • Author(s)
      阿武宏明, 上田貴大, 佐久間裕教
    • Organizer
      一般社団法人紛体粉末冶金協会講演平成26年度秋季大会(第114回講演大会)
    • Place of Presentation
      大阪大学コンベンションセンター(大阪府・吹田市)
    • Year and Date
      2014-10-28
    • Related Report
      2014 Research-status Report
  • [Presentation] Ba8Al16Si30系クラスレートにおける同時ドーピングと熱電特性2014

    • Author(s)
      上田貴大,佐久間裕教,阿武宏明
    • Organizer
      第11回日本熱電学会学術講演会(TSJ2014)
    • Place of Presentation
      独立行政法人物質・材料研究機構(茨城県・つくば市)
    • Year and Date
      2014-09-29 – 2014-09-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Investigation of Thermoelectric Properties of P-Type CuFeS2 Chalcopyrite2014

    • Author(s)
      Hiroaki Anno and Shou Fujii
    • Organizer
      The 15th International Union of Materials Research Societies - International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学(福岡県・福岡市)
    • Year and Date
      2014-08-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of Heat Treatment in Air on Thermoelectric Properties of Ba8Al16Si30-Based Clathrate2014

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Organizer
      The 33rd International Conference on Thermoelectrics (ICT2014)
    • Place of Presentation
      Nashville, TN (USA)
    • Year and Date
      2014-07-08 – 2014-07-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Thermal stablity and oxidation resistance of polycrystalline Ba8Al16Si30-Based clathrates

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Organizer
      E-MRS 2013 Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Related Report
      2013 Research-status Report
  • [Presentation] Impact of heat treatment in air on thermoelectric properties of sintered Ba8Al16Si30-based clathrate

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Organizer
      The 32nd International Conference on Thermoelectrics (ICT2013)
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Development of Thermoelectric Silicon Clathrates

    • Author(s)
      Hiroaki Anno
    • Organizer
      4th International Workshop on Thermoelectrics
    • Place of Presentation
      Awaji Island, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] 空気中熱処理によるBa8Al16Si30 系クラスレートの表面酸化と熱電特性への影響評価

    • Author(s)
      阿武宏明,白瀧律子
    • Organizer
      第10回日本熱電学会学術講演会(TSJ2013)
    • Place of Presentation
      名古屋大学(豊田講堂)、名古屋市
    • Related Report
      2013 Research-status Report
  • [Presentation] Influence of Heat Treatment in Air on Thermoelectric Silicon Clathrate

    • Author(s)
      Hiroaki Anno and Ritsuko Shirataki
    • Organizer
      The International Symposium on Inorganic and Environmental Materials 2013 (ISIEM 2013)
    • Place of Presentation
      The University of Rennes, France
    • Related Report
      2013 Research-status Report
  • [Presentation] THERMAL STABILITY AND THERMOELECTRIC PROPERTIES OF SILICON CLATHRATES FOR WASTE HEAT RECOVERY

    • Author(s)
      H. ANNO and R. SHIRATAKI
    • Organizer
      The 24th International Symposium on Transport Phenomena (ISTP-24)
    • Place of Presentation
      Tokyo University of Science, Yamaguchi, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Investigation of Thermoelectric Properties of Chalcopyrite Semiconductor

    • Author(s)
      S. Fujii and H. Anno
    • Organizer
      山口東京理科大学第14回液晶研究所シンポジウム・第11回先進材料研究所シンポジウム・合同シンポジウム, The 3rd International Workshop on Green Innovation
    • Place of Presentation
      山口東京理科大学、山陽小野田市
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of Host Substitution on Thermoelectric Properties of Ba8Al16Si30 Clathrate System: Examination of Co-doping

    • Author(s)
      T. Ueda, R. Shirataki, and H. Anno
    • Organizer
      山口東京理科大学第14回液晶研究所シンポジウム・第11回先進材料研究所シンポジウム・合同シンポジウム, The 3rd International Workshop on Green Innovation
    • Place of Presentation
      山口東京理科大学、山陽小野田市
    • Related Report
      2013 Research-status Report
  • [Book] ADVANCED MATERIALS FOR CLEAN ENERGY2015

    • Author(s)
      Ryoji Funahashi, Chunlei Wan, Feng Dang, Hiroaki Anno, Ryosuke O. Suzuki, Takeyuki Fujisaka, and Kunihito Koumoto
    • Total Pages
      617
    • Publisher
      CRC Press
    • Related Report
      2014 Research-status Report
  • [Remarks] 東京理科大学 研究者情報データベース RIDAI

    • URL

      http://www.tus.ac.jp/ridai/

    • Related Report
      2014 Research-status Report
  • [Remarks] 学校法人東京理科大学の研究者情報データベース RIDAI

    • URL

      http://www.tus.ac.jp/ridai/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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