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Exploring the Nature and Origin of Long-range Force between Solvophobic Surfaces in Liquids

Research Project

Project/Area Number 25420803
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionOkayama University

Principal Investigator

Ishida Naoyuki  岡山大学, 自然科学研究科, 准教授 (80344133)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords疎水性引力 / 原子間力顕微鏡 / 疎液性引力 / キャビテーション / エントロピー力 / 疎液性
Outline of Final Research Achievements

The interaction forces between hydrophobic surfaces in solutions were measured using atomic force microscopy (AFM) to explore the origin of hydrophobic force, a long-range force acting between hydrophobic surfaces in water. In the obtained force curves between the surfaces without nanobubbles, which had been considered the main origin of the force thus far, an attractive force was found from a distance of 10-20 nm. This force is longer-ranged than typical van der Waals attractions, showing that there still is an additional force between hydrophobic surfaces even without nanoubbules. We also conducted the force measurements between the fluorinated silica surfaces in formamide and found an attractive force that is stronger than the van der Waals attraction. This result confirms that the ‘solvophobic attraction’, which is very similar to the hydrophobic attraction, exists in some organic solvents. We suggested a few different origins of the forces depending on the conditions.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (21 results)

All 2015 2014 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (19 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] Effect of Surface Hydrophobicity on Short-Range Hydrophobic Attraction between Silanated Silica Surfaces2015

    • Author(s)
      N. Ishida, Y. Soga, H. Imanaka and K. Imamura
    • Journal Title

      Advanced Powder Technology

      Volume: 26 Issue: 6 Pages: 1729-1733

    • DOI

      10.1016/j.apt.2015.10.017

    • NAID

      130004545898

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 水中の疎水化シリカ表面間に働く短距離性疎水性引力に及ぼす表面の疎水性の影響2014

    • Author(s)
      曽我 友平,今中 洋行,今村 維克,石田 尚之
    • Journal Title

      粉体工学会誌

      Volume: 51 Pages: 343-348

    • NAID

      130004545898

    • Related Report
      2014 Research-status Report 2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Interaction Forces between Hydrophobic Surfaces in Water-Organic Solvent Binary Mixtures2015

    • Author(s)
      Naoyuki Ishida, Kengo Terada, Hiroyuki Imanaka, Koreyoshi Imamura
    • Organizer
      The 6th Asian Conference on Colloid and Interface Science (ACCIS2015 Japan)
    • Place of Presentation
      Sasebo, Japan
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interaction Force between Hydrophobized Silica Surfaces in Water-Organic Solvent Mixtures2015

    • Author(s)
      Naoyuki Ishida, Kengo Terada, Hiroyuki Imanaka, Koreyoshi Imamura
    • Organizer
      The Western Pacific Colloids Meeting 2015 (WPC 2015)
    • Place of Presentation
      Siem Reap, Cambodia
    • Year and Date
      2015-11-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水中の疎水化シリカ表面間に働く短距離性疎水性引力に及ぼす表面の疎水性の影響2015

    • Author(s)
      曽我 友平,今中 洋行,今村 維克,石田 尚之
    • Organizer
      粉体工学会2015年度秋期研究発表会
    • Place of Presentation
      大阪
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 異なる疎水度をもつ粒子-基板間相互作用力のAFM測定2015

    • Author(s)
      松尾 康平,今中 洋行,今村 維克,石田 尚之
    • Organizer
      粉体工学会2015年度秋期研究発表会
    • Place of Presentation
      大阪
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水-水溶性有機溶媒中での疎水性表面間相互作用の直接測定2015

    • Author(s)
      寺田 健悟,今中 洋行,今村 維克,石田 尚之
    • Organizer
      粉体工学会2015年度秋期研究発表会
    • Place of Presentation
      大阪
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 異なる疎水度をもつ疎水性表面間に働く相互作用力の AFM 直接測定2015

    • Author(s)
      松尾 康平, 今中 洋行, 今村 維克, 石田 尚之
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水-水溶性有機溶媒混合溶液中における疎水性表面間の相互作用2015

    • Author(s)
      寺田 健悟, 今中 洋行, 今村 維克, 石田 尚之
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] 微小表面間に働く疎水性引力の直接測定2015

    • Author(s)
      石田 尚之, 池田 享平, 曽我 友平, 今中 洋行, 今村 維克
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Interaction force between silanated silica surfaces in organic solvents2015

    • Author(s)
      Naoyuki Ishida, Yuhei Soga, Hiroyuki Imanaka, Koreyoshi Imamura
    • Organizer
      The seventh biennial Australian Colloid and Interface Symposium
    • Place of Presentation
      ホバート(オーストラリア)
    • Year and Date
      2015-02-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 疎水性引力の直接測定とその発現機構2015

    • Author(s)
      石田尚之
    • Organizer
      平成26年度物理化学インターカレッジセミナー 兼日本油化学会界面科学部会九州地区講演会
    • Place of Presentation
      福岡大学セミナーハウス(福岡県福岡市)
    • Year and Date
      2015-01-07
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 微粒子表面の疎水性と表面間の相互作用力との相関の検討2014

    • Author(s)
      石田 尚之, 曽我 友平, 池田 亨平, 今中 洋行, 今村 維克
    • Organizer
      第52回粉体に関する討論会
    • Place of Presentation
      じばさんびる(兵庫県姫路市)
    • Year and Date
      2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] コロイドプローブAFMによる改質シリカ表面間の疎液性引力の直接測定2014

    • Author(s)
      石田 尚之, 曽我 友平, 池田 亨平, 今中 洋行, 今村 維克
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 表面の疎液性と表面間の引力との相関について2014

    • Author(s)
      石田尚之, 曽我 友平, 今中 洋行, 今村 維克
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学(東京都)
    • Year and Date
      2014-09-04
    • Related Report
      2014 Research-status Report
  • [Presentation] ナノバブルを除去した疎水性表面間の相互作用力2014

    • Author(s)
      曽我 友平, 今中 洋行, 今村 維克, 石田 尚之
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学(東京都)
    • Year and Date
      2014-09-04
    • Related Report
      2014 Research-status Report
  • [Presentation] AFM探針と基板表面間に働く疎水性引力の直接測定2014

    • Author(s)
      池田 亨平, 曽我 友平, 今中 洋行, 今村 維克, 石田 尚之
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学(東京都)
    • Year and Date
      2014-09-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 液体中の疎液性表面間に働く引力の直接測定2014

    • Author(s)
      石田 尚之
    • Organizer
      粉体工学会2014年度春期研究発表会
    • Place of Presentation
      メルバルク京都(京都府京都市)
    • Year and Date
      2014-05-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 液体中の疎液性表面間に働く長距離性引力の直接測定

    • Author(s)
      曽我 友平,今中 洋行,今村 維克,石田 尚之
    • Organizer
      粉体工学会2013年度秋期研究発表会
    • Place of Presentation
      大阪
    • Related Report
      2013 Research-status Report
  • [Presentation] Direct Measurement of Solvophobic Attraction between Fluorinated Silica Surfaces by Atomic Force Microscopy

    • Author(s)
      Naoyuki Ishida, Yuuhei Soga, Hiroyuki Imanaka, Koreyoshi Imamura
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] Short-ranged Hydrophobic Attraction between Silanated Silica Surfaces and Solvophobic Attraction

    • Author(s)
      Naoyuki Ishida, Yuuhei Soga, Hiroyuki Imanaka, Koreyoshi Imamura
    • Organizer
      The 27th Conference of the European Colloid and Interface Society
    • Place of Presentation
      Sofia, Bulgaria
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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