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Development of eco-friendly separation techniques for critical metals based on liquid-liquid and solid-liquid extraction systems.

Research Project

Project/Area Number 25420806
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionKyushu University

Principal Investigator

Kubota Fukiko  九州大学, 工学研究院, 助教 (60294899)

Co-Investigator(Kenkyū-buntansha) 後藤 雅宏  九州大学, 工学研究院, 教授 (10211921)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsレアメタル / 分離回収 / 抽出 / 吸着 / イオン交換 / 希土類 / 貴金属 / リサイクル
Outline of Final Research Achievements

Critical metals such as precious metals and rare earth metals are of great importance due to their wide application in various high-tech industries. A highly efficient and eco-friendly separation technique for the recovery of such metals from various resources is required. In this study, novel separation systems based on solvent extraction were developed using ionic liquids (ILs) and novel extractants, which we designed for the critical metals. The ILs were evaluated as an extractant without dilution for the separation of precious metals. A novel amic acid extractant, D2EHAG was shown to be effective for the recovery of the critical metals. These extractants were prepared as an adsorbent or ion exchange resin. It was demonstrated that it was important to create the reaction site favorable for a metal extraction at liquid-liquid or solid-liquid interface for the efficient extraction of the metal ion.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (52 results)

All 2017 2016 2015 2014 2013 Other

All Journal Article (11 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (34 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (4 results) (of which Overseas: 2 results)

  • [Journal Article] Extraction and stripping of behavior of platinum group metals using an amid-acid-type extracting.2017

    • Author(s)
      W. Yoshida, Y. Baba, F. Kubota, N. Kamiya, M. Goto
    • Journal Title

      J. Chem. Eng. Jpn

      Volume: 50

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Development of novel adsorbent bearing aminocarbonylmethylglycine and its application to scandium separation2016

    • Author(s)
      Z. Zhao, Y. Baba, W. Yoshida, F. Kubota, M. Goto
    • Journal Title

      J. Chem. Technol Biotechnol.,

      Volume: 91 Issue: 11 Pages: 2779-2784

    • DOI

      10.1002/jctb.4884

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Selective Extraction of Scandium from Transition Metals by Synergistic Extraction with 2-Thenoyltrifluoroacetone and Tri-<i>n</i>-octylphosphine Oxide2016

    • Author(s)
      Z. Zhao, F. Kubota, N. Kamiya, M. Goto
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 23 Issue: 2 Pages: 137-143

    • DOI

      10.15261/serdj.23.137

    • NAID

      130005152881

    • ISSN
      1341-7215, 2188-4765
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Development of novel adsorbent bearing aminocarbonylmethylglycine and its application to scandium separation2016

    • Author(s)
      Z. Zhao, Y. Baba, W. Yoshida, F. Kubota, M. Goto
    • Journal Title

      J. Chem. Technol Biotechnol.

      Volume: 91

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Selective Extraction of Scandium from Transition Metals by Synergistic Extraction with 2-Thenoyltrifluoroacetone and Tri-n-octylphosphine Oxide2016

    • Author(s)
      Z. Zhao, F. Kubota, N. Kamiya, M. Goto
    • Journal Title

      Solv. Ext. Res. Dev., Jpn

      Volume: 23

    • NAID

      130005152881

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] イオン液体を用いた希土類 元素の最先端分離技術2016

    • Author(s)
      後藤雅宏、久保田富生子
    • Journal Title

      化学と工業

      Volume: 69 Pages: 315-317

    • Related Report
      2015 Research-status Report
  • [Journal Article] Separation of Gold(III) in Acidic Chloride Solution Using Porous Polymeric Ionic Liquid Gel2015

    • Author(s)
      J. Yang, F. Kubota, Y. Baba, N. Kamiya, M. Goto
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 48 Issue: 3 Pages: 197-201

    • DOI

      10.1252/jcej.14we162

    • NAID

      130004862064

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Application of cellulose acetate to the selective adsorption and recovery of Au(III)2014

    • Author(s)
      Jian Yang, Fukiko Kubota, Yuzo Baba, Noriho Kamiya, Masahiro Goto
    • Journal Title

      Carbohydrate Polymers

      Volume: 111 Pages: 768-774

    • DOI

      10.1016/j.carbpol.2014.05.003

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] One Step Effective Separation of Platinum and Palladium in an Acidic Chloride Solution by Using Undiluted Ionic Liquids2014

    • Author(s)
      J. Yang, F. Kubota, Y. Baba, N. Kamiya, M. Goto,
    • Journal Title

      Solv. Ext. Res. Dev., Jpn

      Volume: 21 Pages: 129-135

    • NAID

      130004669671

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synergistic Extraction of Rare-Earth Metals and Separation of Scandium Using 2-Thenoyltrifluoroacetone and Tri-<i>n</i>-octylphosphine Oxide in an Ionic Liquid System2014

    • Author(s)
      Zhigang Zhao, Yuzo Baba, Fukiko Kubota, Noriho Kamiya, Masahiro Goto
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 47 Issue: 8 Pages: 656-662

    • DOI

      10.1252/jcej.14we360

    • NAID

      130004677521

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Separation of precious metals by using undiluted ionic liquids2014

    • Author(s)
      J. Yang, F. Kubota, Y. Baba, N. Kamiya, M.Goto
    • Journal Title

      Solvent Extraction Research and Development

      Volume: 21 Pages: 89-94

    • NAID

      130005056986

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 新規アミド酸型官能基を導入したイオン 交換樹脂の開発とレアメタル分離回収2016

    • Author(s)
      久保田富生子、趙志鋼、吉田航、馬場雄三、後藤雅宏
    • Organizer
      第32回イオン交換研究発表会
    • Place of Presentation
      関西大学
    • Year and Date
      2016-09-28
    • Related Report
      2016 Annual Research Report
  • [Presentation] レアメタル回収のための新規アミド酸型官能基を導入したイオン交換樹脂の開発2016

    • Author(s)
      久保田富生子、趙志鋼、吉田航、馬場雄三、後藤雅宏
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] アミノ酸とアルキルアミドを有する新規抽出剤の開発と白金族金属の分離回収への応用2016

    • Author(s)
      吉田航、馬場雄三、久保田富生子、神谷典穂、後藤雅宏
    • Organizer
      分離技術会2016
    • Place of Presentation
      日本大学津田沼キャンパス
    • Year and Date
      2016-05-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオン液体抽出剤による貴金属の分離2016

    • Author(s)
      久保田富生子, 執行英子, Jian Yang, 後藤雅宏
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学
    • Year and Date
      2016-03-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Development of new extractant applicable to industrial solvent extraction for the recovery of precious metals2015

    • Author(s)
      W. Yoshida, Y. Baba, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      The 28th Int. Symp. Chem. Eng.
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-12-04
    • Related Report
      2015 Research-status Report
  • [Presentation] Extraction performance of novel amino acid derivative extractant for precious metal ions2015

    • Author(s)
      W. Yoshida, Y. Baba, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      2015 Taiwan/Korea/Japan Joint Meeting on Chemical Engineering
    • Place of Presentation
      Gaoxing, Taiwan
    • Year and Date
      2015-11-05
    • Related Report
      2015 Research-status Report
  • [Presentation] グリシンを官能基に導入したアミド酸型抽出剤による白金族の抽出および逆抽出挙動2015

    • Author(s)
      吉田航、馬場雄三、久保田富生子、神谷典穂、後藤雅宏
    • Organizer
      日本イオン交換学会・日本溶媒抽出学会連合年会
    • Place of Presentation
      金沢工業大学
    • Year and Date
      2015-10-23
    • Related Report
      2015 Research-status Report
  • [Presentation] 新規アミド酸型抽出剤の開発とレアメタルリサイクルへの利用2015

    • Author(s)
      久保田富生子・吉田 航・引野幸枝・馬場雄三・後藤雅宏
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] 新規アミド酸型抽出剤による貴金属の抽出特性2015

    • Author(s)
      吉田航、馬場雄三、久保田富生子、神谷典穂、後藤雅宏
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2015-09-09
    • Related Report
      2015 Research-status Report
  • [Presentation] Extraction of precious metals using novel amic acid-type extractant2015

    • Author(s)
      W. Yoshida, Y. Baba, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      3rd Int. Symp. on Host Compounds for Separation and Functionality in Saga
    • Place of Presentation
      佐賀大学
    • Year and Date
      2015-07-29
    • Related Report
      2015 Research-status Report
  • [Presentation] アミド酸型抽出剤を用いた希土類金属の新規リサイクルシステム2015

    • Author(s)
      久保田富生子, 楊帆, 馬場雄三, 後藤雅宏
    • Organizer
      第32回希土類討論会
    • Place of Presentation
      鹿児島県民交流センター
    • Year and Date
      2015-05-21
    • Related Report
      2015 Research-status Report
  • [Presentation] アミック酸型新規抽出剤D2EHAGを用いたスカンジウムの抽出特性2014

    • Author(s)
      久保田富生子、馬場雄三、深見有沙, 後藤雅宏
    • Organizer
      第33回溶媒抽出討論会
    • Place of Presentation
      ホテルプラザ神戸
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Research-status Report
  • [Presentation] グリシンとアミド構造を有する三座配位子型抽出剤を用いたIn(III), Ga(III), Zn(II)の抽出分離2014

    • Author(s)
      馬場雄三, 久保田富生子, 神谷典穂, 後藤雅宏
    • Organizer
      第33回溶媒抽出討論会
    • Place of Presentation
      ホテルプラザ神戸
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Separation of scandium by a synergistic extraction system with aβ-diketone HTTA and TOPO2014

    • Author(s)
      Z. Zhao, F. Kubota, Y.Baba, N. Kamiya, M. Goto
    • Organizer
      6th Int. Conf. Ion Exch., 2014
    • Place of Presentation
      沖縄コンベンションセンター
    • Year and Date
      2014-11-09 – 2014-11-12
    • Related Report
      2014 Research-status Report
  • [Presentation] New Extractants for Separation of Rare Earth Metals2014

    • Author(s)
      A. Fukami, Y. Baba, F. Kubota, M. Goto
    • Organizer
      6th Int. Conf. Ion Exch., 2014
    • Place of Presentation
      沖縄コンベンションセンター
    • Year and Date
      2014-11-09 – 2014-11-12
    • Related Report
      2014 Research-status Report
  • [Presentation] Sorption properties of rare earth elements on chemically modified E. coli2014

    • Author(s)
      Y. Hosomomi, R. Wakabayashi, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      6th Int. Conf. Ion Exch., 2014
    • Place of Presentation
      沖縄コンベンションセンター
    • Year and Date
      2014-11-09 – 2014-11-12
    • Related Report
      2014 Research-status Report
  • [Presentation] アセトアミド型新規抽出剤によるスカンジウムの分離2014

    • Author(s)
      深見有沙、馬場雄三、久保田富生子、神谷典穂、後藤雅宏
    • Organizer
      第46回化学工学会秋季大会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] アミド酸型新規キャリアを用いたポリマー包含膜によるレアメタルの高効率膜分離2014

    • Author(s)
      馬場雄三, 久保田富生子, 後藤雅宏, R.W. Cattral, S. D. Kolev
    • Organizer
      第46回化学工学会秋季大会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン液体を用いたレアメタルの抽出分離2014

    • Author(s)
      久保田富生子, Yang Jian, 馬場雄三,後藤雅宏
    • Organizer
      資源・素材学会熊本大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2014-09-15 – 2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] Separation of rare earth metal ions by synergistic system with 2-thenoyltrifluoroacetone and TOPO2014

    • Author(s)
      F. Kubota, Z. Zhao, Y. Baba, N. Kamiya, M. Goto
    • Organizer
      Int. Solv. Extrn. Cof., 2014
    • Place of Presentation
      Wurzburg, Germany
    • Year and Date
      2014-09-07 – 2014-09-11
    • Related Report
      2014 Research-status Report
  • [Presentation] アミド酸型新規抽出剤による希土類金属の抽出分離特性2014

    • Author(s)
      久保田富生子,深見有沙, 馬場雄三, 神谷典穂,後藤雅宏
    • Organizer
      第31回希土類討論会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2014-05-22 – 2014-05-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 大腸菌の化学修飾を利用した希土類金属の新規バイオ吸着剤の開発2014

    • Author(s)
      細樅侑貴穂、若林里衣、久保田富生子、神谷典穂、後藤雅宏
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 新規アミド酸型抽出剤によるレアアースの抽出分離2014

    • Author(s)
      久保田富生子、深見有沙、馬場雄三, 神谷典穂、後藤雅宏
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 希土類金属の新規吸着剤としての大腸菌の応用2013

    • Author(s)
      細樅侑貴穂, 馬場雄三, 久保田富生子,神谷 典穂,後藤 雅宏
    • Organizer
      第30回希土類討論会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] Development of Membrane Separation System for Rare Metals Based on Ionic Liquids2013

    • Author(s)
      J.YANG, Y.BABA, F.KUBOTA, N.KAMIYA, M.GOTO
    • Organizer
      Conference of Aseanian Membrane Society(AMS8)
    • Place of Presentation
      Xi’an, China
    • Related Report
      2013 Research-status Report
  • [Presentation] Selective Transport of Rare Earth Metals through a Supported Liquid Membrane Using Ionic Liquids2013

    • Author(s)
      F. Kubota, Y. Baba, N. Kamiya, M. Goto
    • Organizer
      Conference of Aseanian Membrane Society(AMS8)
    • Place of Presentation
      Xi’an, China
    • Related Report
      2013 Research-status Report
  • [Presentation] Development of bacterial biosorbent for rare earth elements2013

    • Author(s)
      Y. Hosomomi, Y. Baba, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      International Symposium on Cell Surface Structures and Functions
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 趙志鋼、久保田富生子、馬場雄三、神谷典穂、後藤雅宏2013

    • Author(s)
      イオン液体中における希土類金属の協同抽出
    • Organizer
      化学工学会 第45回秋季大会
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 久保田富生子、楊 帆、馬場雄三、神谷典穂、後藤雅宏2013

    • Author(s)
      イオン液体を利用した廃蛍光管からのレアアースの分離回収
    • Organizer
      化学工学会 第45回秋季大会
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] イオン液体中の協同効果を利用した希土類の抽出分離2013

    • Author(s)
      趙志鋼、久保田富生子、馬場雄三、神谷典穂、後藤雅宏
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 実用化に資する新規抽出剤の開発と課題 -ニッケル、コバルト抽出を例として-2013

    • Author(s)
      馬場雄三、久保田富生子、後藤雅宏
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] アセトアミド型新規抽出剤による希土類金属の抽出特性2013

    • Author(s)
      深見有沙、馬場雄三、久保田富生子、神谷典穂、後藤雅宏
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Effective Separation and Recovery of Rare Earth Metals by Using Supported Ionic Liquid Membrane System2013

    • Author(s)
      Y. Baba, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      8th Int. Membr. Sci. & Technol. Conf. (IMSTEC2013)
    • Place of Presentation
      Australia(Melbourne)
    • Related Report
      2013 Research-status Report
  • [Presentation] Chemical modification of E. coli for recovery of rare earth elements2013

    • Author(s)
      Y. Hosomomi, Y. Baba, F. Kubota, N. Kamiya, M. Goto
    • Organizer
      26th Int. Symp. Chem. Eng.,Daejeon/Chungnam-Kyushu(Japan
    • Place of Presentation
      Busan, Korea
    • Related Report
      2013 Research-status Report
  • [Book] Application of Ionic Liquids on Rare Earth Green Separation and Utilization (Chap.4)2016

    • Author(s)
      F. Kubota, J. Yang, M. Goto
    • Total Pages
      11
    • Publisher
      Springer
    • Related Report
      2015 Research-status Report
  • [Book] RIEAE叢書 環境問題解決のための先進的技法 (第2章)2015

    • Author(s)
      久保田富生子, 後藤雅宏
    • Total Pages
      19
    • Publisher
      花書院
    • Related Report
      2014 Research-status Report
  • [Remarks] Goto & Kamiya Lab

    • URL

      http://www.bioeng.cstm.kyushu-u.ac.jp

    • Related Report
      2015 Research-status Report 2014 Research-status Report
  • [Patent(Industrial Property Rights)] Ion-exchange resin used in separation of metal2015

    • Inventor(s)
      M. Goto, F. Kubota
    • Industrial Property Rights Holder
      Univ Kyushu;SMM Co Ltd
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-06-26
    • Acquisition Date
      2015-12-30
    • Related Report
      2015 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] 希土類抽出剤及び抽出方法2014

    • Inventor(s)
      後藤雅宏、久保田富生子
    • Industrial Property Rights Holder
      九州大学、住友金属鉱山
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-07-23
    • Related Report
      2014 Research-status Report
    • Overseas
  • [Patent(Industrial Property Rights)] イオン交換樹脂及び金属の吸着分離方法2014

    • Inventor(s)
      後藤雅宏、久保田富生子
    • Industrial Property Rights Holder
      九州大学、住友金属鉱山
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-06-26
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 希土類抽出剤及び抽出方法2013

    • Inventor(s)
      後藤雅宏、久保田富生子
    • Industrial Property Rights Holder
      九州大学、住友金属鉱山
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-11-26
    • Acquisition Date
      2015-01-23
    • Related Report
      2014 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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