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Development of process of synthesis of micron polymeric particle and its applications

Research Project

Project/Area Number 25420817
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionNagoya University (2014-2015)
Hiroshima University (2013)

Principal Investigator

Yamamoto Tetsuya  名古屋大学, 工学(系)研究科(研究院), 准教授 (10432684)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsソープフリー乳化重合 / ミクロン粒子 / 共重合 / 両親媒性モノマー / 油溶性開始剤 / 高濃度化 / 炭素繊維強化プラスチック / 界面接着性 / 電気泳動 / 高分子ミクロン粒子 / 低環境負荷型プロセス / 電解質 / 芳香族ビニルモノマー / 高分子微粒子
Outline of Final Research Achievements

This study investigated the development of micron-sized polymeric particle by soap-free emulsion polymerization using oil-soluble initiator, and its application. As a result, the particle size was varied from 300 nm to 20 μm changing the ionic strength by electrolyte for short reaction time. Amphipathic monomer, N-vinylacetamide, was used for the copolymerization to enhance the particle concentration. These techniques was applied to synthesize carbon fiber reinforced plastic (CFRP). The carbon fibers was coated with polymeric particles to improve the surface adhesion between the carbon fiber and the resin. This method was useful to enhance the performance of CFRP.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (27 results)

All 2016 2015 2014 2013 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 6 results) Presentation (16 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Relationship between Surface Potential and Particle Size in Soap-free Emulsion Copolymerization of Styrene and Methyl Methacrylate using a Water- or Oil-soluble Initiator2016

    • Author(s)
      Tetsuya Yamamoto, and Kan Kawaguchi
    • Journal Title

      Colloid & Polymer Science

      Volume: 294 Issue: 2 Pages: 281-284

    • DOI

      10.1007/s00396-015-3780-8

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Particle Size Control in the Soap-free Emulsion Polymerization of Styrene by an Oil-soluble Initiator with a Weakly Acidic Water-soluble Initiator2016

    • Author(s)
      Tetsuya Yamamoto, Kan Kawaguchi, Yuya Takahashi
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: in press Pages: 1-5

    • DOI

      10.1016/j.colsurfa.2016.04.048

    • NAID

      120005866828

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhancement of Surface Adhesion between Thermoplastic Resin and Carbon Fiber Using Polymer Colloids2016

    • Author(s)
      Tetsuya Yamamoto, Katsumasa Uematsu, Toshihira Irisawa, Yasuhiro Tanabe
    • Journal Title

      The Journal of Adhesion

      Volume: in press

    • NAID

      120006473513

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Amount of Pi Electrons in Aromatic Monomer on Surface Potential of Polymeric Particle through Soap-Free Emulsion Polymerization Using AIBN2015

    • Author(s)
      Tetsuya Yamamoto
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 11 Pages: 1555-1556

    • DOI

      10.1246/cl.150759

    • NAID

      130005108101

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Counter Ionic Radius in Initiator on Particle Size in Soap-free Emulsion Polymerization of Styrene2015

    • Author(s)
      Tetsuya Yamamoto, and Taichi Yokoyama
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 6 Pages: 824-825

    • DOI

      10.1246/cl.150148

    • NAID

      130005074589

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of electrolyte species on size of particle through soap-free emulsion polymerization of styrene using AIBN and electrolyte2015

    • Author(s)
      Tetsuya Yamamoto, Kan Kawaguchi
    • Journal Title

      Colloid & Polymer Science

      Volume: 293 Issue: 3 Pages: 1003-1006

    • DOI

      10.1007/s00396-015-3511-1

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of nearly micron-sized particles by soap-free emulsion polymerization of methacrylic monomer using an oil-soluble initiator2013

    • Author(s)
      Tetsuya Yamamoto
    • Journal Title

      Colloid and Polymer Science

      Volume: 291 Issue: 11 Pages: 2741-2744

    • DOI

      10.1007/s00396-013-3059-x

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 炭素繊維複合樹脂材料の高性能化を実現するコロイド技術2016

    • Author(s)
      山本徹也, 上松克匡, 入澤寿平
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学 千里山キャンパス
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] カーボンナノチューブ複合高分子微粒子の合成2016

    • Author(s)
      川口 勘,山本 徹也
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学 千里山キャンパス
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 両親媒性モノマーを利用したソープフリー乳化共重合の高効率化2016

    • Author(s)
      高橋 侑椰,川口 勘,山本 徹也
    • Organizer
      第18回化学工学会学生発表会(浜松大会)
    • Place of Presentation
      静岡大学浜松キャンパス
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 架橋性開始剤を用いたソープフリー乳化重合の微粒子表面形態2016

    • Author(s)
      金 スルチャン,山本 徹也
    • Organizer
      第18回化学工学会学生発表会(浜松大会)
    • Place of Presentation
      静岡大学浜松キャンパス
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリマーコロイドを利用した炭素繊維強化プラスチックの高性能化2016

    • Author(s)
      上松 克匡,山本 徹也,入澤 寿平
    • Organizer
      第18回化学工学会学生発表会(浜松大会)
    • Place of Presentation
      静岡大学浜松キャンパス
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] ソープフリー乳化重合による高濃度ミクロン粒子の調製2015

    • Author(s)
      山本徹也, 川口勘, 高橋侑椰
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学 札幌キャンパス
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 40nmから20μmまでの 高分子微粒子界面活性剤フリー調製法2015

    • Author(s)
      山本徹也
    • Organizer
      2015年度 第1回 粉体操作に伴う諸現象に関する勉強会
    • Place of Presentation
      琵琶湖畔近江白浜旅館
    • Year and Date
      2015-07-30
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Synthesis of Micron-Sized Particles Through Soap-Free Emulsion Polymerization Using Oil-Soluble Initiator2015

    • Author(s)
      Tetsuya Yamamoto, Kan Kawaguchi, Taichi Yokoyama
    • Organizer
      15th Conference of the International Association of Colloid and Interface Scientists
    • Place of Presentation
      Mainz, Germany
    • Year and Date
      2015-05-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ソープフリー乳化重合系における対イオンの効果2015

    • Author(s)
      山本徹也
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] ソープフリー乳化重合による高分子ナノ粒子の合成と粒子径制御2015

    • Author(s)
      横山太一,川口勘,山本徹也
    • Organizer
      第17回化学工学会学生発表会(八戸大会)
    • Place of Presentation
      八戸工業高等専門学校
    • Year and Date
      2015-03-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 油溶性開始剤を用いたソープフリー乳化重合における電解質添加の影響2015

    • Author(s)
      川口勘,横山太一,山本徹也
    • Organizer
      第17回化学工学会学生発表会(八戸大会)
    • Place of Presentation
      八戸工業高等専門学校
    • Year and Date
      2015-03-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 油溶性開始剤を用いたソープフリー 乳化重合によるミクロスフェアの調製2014

    • Author(s)
      山本徹也
    • Organizer
      第18回高分子ミクロスフェア討論会
    • Place of Presentation
      福井大学
    • Year and Date
      2014-11-05 – 2014-11-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 油溶性開始剤を用いたソープフリー重合法によるミクロン粒子の合成2014

    • Author(s)
      山本徹也
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] 油溶性開始剤を用いたソープフリー乳化重合によるミクロン粒子の合成2014

    • Author(s)
      山本徹也
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 低環境負荷型高分子ミクロン粒子の合成法2013

    • Author(s)
      山本徹也
    • Organizer
      第7回中四国若手CE合宿
    • Place of Presentation
      ホテル常盤
    • Related Report
      2013 Research-status Report
  • [Presentation] 微粒子表面物性を利用した粉体プロセスの開発2013

    • Author(s)
      山本徹也
    • Organizer
      化学工学会中国地区平成25年度総会・記念講演会
    • Place of Presentation
      広島ガーデンパレス
    • Related Report
      2013 Research-status Report
    • Invited
  • [Book] ナノ粒子の表面修飾と分析評価技術 ~各種特性を向上するための ナノ粒子表面関連技術とその評価~2016

    • Author(s)
      山本徹也 他
    • Total Pages
      425
    • Publisher
      株式会社 情報機構
    • Related Report
      2015 Annual Research Report
  • [Remarks] 低環境負荷型高分子ナノ・ミクロン粒子合成プロセスの開発

    • URL

      http://www.nuce.nagoya-u.ac.jp/e5/images/yamamoto-labo.jpg

    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 炭素繊維強化プラスチック製造用コロイド溶液、粒子吸着炭素繊維及びその製造方法、炭素繊維強化プラスチック、並びに制御方法2016

    • Inventor(s)
      山本徹也,上松克匡,入澤寿平
    • Industrial Property Rights Holder
      名古屋大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-03-04
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] ポリマーコロイド溶液及びそれを用いた分析マーカー、ナノカーボン溶液、樹脂粒子吸着炭素繊維、及び炭素繊維強化プラスチック2015

    • Inventor(s)
      山本徹也,上松克匡,入澤寿平
    • Industrial Property Rights Holder
      名古屋大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-10-26
    • Related Report
      2015 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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