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Development and Reaction Mechanism Clarification on Hybrid Photocatalyst Having High Light Absorption and Carbon Dioxide Reforming Performance

Research Project

Project/Area Number 25420921
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy engineering
Research InstitutionMie University

Principal Investigator

Nishimura Akira  三重大学, 工学(系)研究科(研究院), 准教授 (60345999)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords光触媒 / 二酸化炭素改質 / 可視光応答 / 還元剤 / 重ね合わせ / 二酸化炭素 / 金属担持 / 可視光吸収 / 地球温暖化対策 / 可視光応答光触媒 / 二酸化炭素還元
Outline of Final Research Achievements

This study carried out the development of new visible light-driven photocatalyst realizing CO2 Reforming/Recycling as well as H2 Stock at the same time for the system CO2/H2O/H2. Transparent porous fiber (TPF) was selected as a basis and a loaded transition metal and Ps were coated with TiO2 inside the porous of TPF. The aim of this study is to evaluate and improve the high light absorption, CO2 reforming and H2 stock performance of the developed photocatalyst. As a result, the following conclusions have been obtained: (1) CO2/H2O system: It is acknowledged that the CO2 reforming performance of prepared photocatalyst was improved by metal loading. The overlapping effect on CO2 reforming performance was not obtained well. (2) CO2/H2 system, CO2/H2O/H2 system: Though the effect of Fe loading on the CO2 reforming performance improvement was obtained, the effect of H2 addition on the improvement was not obtained.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (7 results)

All 2016 2015 2014

All Presentation (7 results)

  • [Presentation] 異種基材コーティング金属担持TiO2の配置条件がCO2改質性能に及ぼす影響2016

    • Author(s)
      西村顕、Zhao Xuyan、石田教晃、立松大智、廣田真史
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 異種基材にコーティングしたFe/TiO2の配置条件がCO2改質性能に及ぼす影響2016

    • Author(s)
      立松大智、西村顕、石田教晃、Zhao Xuyan、廣田真史
    • Organizer
      第18回化学工学会学生発表会
    • Place of Presentation
      静岡大学(静岡県)
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 網目状ガラス繊維にコーティングした金属担持TiO2光触媒のCO2還元特性2015

    • Author(s)
      西村顕、早川拓也、Zhao Xuyan、石田教晃、立松大智、廣田真史、小塩明、小海文夫
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] CO2 Reforming into Fuel by Metal-loaded TiO2 Photocatalyst Driven by Visible Light2015

    • Author(s)
      Akira Nishimura, Takuya Hayakawa, Xuyan Zhao, Taiga Kitazumi, Masafumi Hirota, Akira Koshio and Fumio Kokai
    • Organizer
      The 10th Asia Pacific Conference on Sustainable Energy & Environmental Technologies (APCSEET2015)
    • Place of Presentation
      Seoul (Korea)
    • Year and Date
      2015-07-02 – 2015-07-05
    • Related Report
      2014 Research-status Report
  • [Presentation] CO2 Reforming into Fuel by Metal-loaded TiO2 Photocatalyst Driven by Visible Light2015

    • Author(s)
      Akira Nishimura, Takuya Hayakawa, Xuyan Zhao, Taiga Kitazumi, Masafumi Hirota, Akira Koshio and Fumio Kokai
    • Organizer
      The 10th Asia Pacific Conference on Sustainable Energy & Environmental Technologies
    • Place of Presentation
      ソウル(韓国)
    • Year and Date
      2015-07-02
    • Related Report
      2015 Annual Research Report
  • [Presentation] 異種基材コーティング光触媒Fe/TiO2およびCu/TiO2のCO2改質性能2015

    • Author(s)
      Xuyan Zhao,早川拓也,北住大雅,西村顕,廣田真史
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工大
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 可視光応答型金属担持TiO2光触媒の表面性状とCO2改質性能評価2014

    • Author(s)
      早川拓也,西村顕,Xuyan Zhao,北住大雅,廣田真史
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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