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Innovative production of hydrogen from biomass char loaded with non-agglomerated iron catalyst by steam gasification

Research Project

Project/Area Number 25450236
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Wood science
Research InstitutionKitami Institute of Technology

Principal Investigator

Suzuki Tsutomu  北見工業大学, 工学部, 特任教授 (20125389)

Co-Investigator(Kenkyū-buntansha) OKAZAKI Noriyasu  北見工業大学, 工学部, 准教授 (10213927)
Co-Investigator(Renkei-kenkyūsha) SATO Kazuhisa  東北大学, 金属材料研究所, 助教 (70314424)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥130,000 (Direct Cost: ¥100,000、Indirect Cost: ¥30,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsバイオマス / 水素 / 触媒・化学プロセス / 再生可能エネルギー / 木炭
Outline of Final Research Achievements

Wood char impregnated with iron liquor (abbreviated as FA), which has been used in vegetable dyeing from old times, was subjected to steam gasification in a fixed bed downdraft reactor. According to obtained results, highly efficient production of hydrogen was realized on the following conditions: preparation of wood char at 500°C, 5 wt % loading of FA as iron metal, gasification at 800°C, total gas (steam plus Ar as carrier) flow of 230mlSTP/cm2・min, and steam partial pressure of 0.4-0.5 for initial sample weight of 0.3 g. It was also shown that FeA as an iron-containing complex did not easily decompose into inorganic iron components to be slightly agglomerated. This must be a real reason for excellent catalytic activity of FeA. In addition, how to efficiently make active FeA was examined.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (9 results)

All 2015 2014 2013

All Journal Article (1 results) Presentation (7 results) (of which Invited: 2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] 新たな水素製造の道を拓く木炭の利用技術2014

    • Author(s)
      鈴木 勉
    • Journal Title

      ケミカルエンジニアリング

      Volume: 59 Pages: 813-823

    • Related Report
      2014 Research-status Report
  • [Presentation] Wood refinery by iron-catalyzed carbonization for coproduction of functional carbon and fluid fuels2015

    • Author(s)
      Tsutomu Suzuki, Kyoko Suzuki
    • Organizer
      25th MRS-J
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2015-12-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 鉄系触媒炭化によるウッドリファイナリー:機能性炭素と流体燃料の併産プロセスの構築を目指して2015

    • Author(s)
      鈴木 勉
    • Organizer
      日本エネルギー学会第24回大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-08-04
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 木炭の鉄触媒水蒸気ガス化による高効率水素製造-自作した鉄触媒の効果2015

    • Author(s)
      大塚 葵, 鈴木京子, 岡崎文保, 鈴木 勉
    • Organizer
      平成27年化学系学協会北海道支部2014年冬季研究発表会
    • Place of Presentation
      北海道大学, 札幌
    • Year and Date
      2015-01-28 – 2015-01-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 新たな水素製造の道を拓く木炭の利用技術2014

    • Author(s)
      鈴木 勉
    • Organizer
      JST新技術説明会
    • Place of Presentation
      JST本部, 東京
    • Year and Date
      2014-09-08 – 2014-09-09
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Highly efficient hydrogen production by steam gasification of wood char loaded with a unique iron catalyst precursor2014

    • Author(s)
      T. Suzuki, T. Hojo, M. Nakayama, K. Yamada, K. Suzuki, N. Okazaki
    • Organizer
      The 2014 Pan Pacific Conference of Tappi
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2014-05-21 – 2014-05-23
    • Related Report
      2014 Research-status Report
  • [Presentation] 木酢酸鉄を後添加した木炭の水蒸気ガス化による高効率水素製造2014

    • Author(s)
      鈴木 勉, 北條貴久, 中山未貴, 山田恭平, 鈴木京子
    • Organizer
      第64回日本木材学会大会
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Highly efficient hydrogen production by steam gasification of wood char loaded with a unique iron catalyst precursor2014

    • Author(s)
      Tsutomu Suzuki, Takahisa Hojo, Miki Nakayama, Kyohei Yamada, Kyoko Suzuki, Noriyasu Okazaki
    • Organizer
      The 2014 Pan Pacific Conference of the Technical Associations of the Pulp and Paper Industry
    • Place of Presentation
      The International Conference Hall, Forestry Research Building, Taiwan Forest Research Institute. 67 Sanyuan St., Taipei, Taiwan.
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 水素製造方法、水素製造用木炭の製造方法及び水素製造用木炭2013

    • Inventor(s)
      鈴木 勉、鈴木京子
    • Industrial Property Rights Holder
      鈴木 勉、鈴木京子
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-04-22
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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