Development of Novel Oxidation System for Organic Synthesis Utilizing Functional Polymer-Gels
| Project/Area Number |
25460027
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Meijo University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
MATSUGI MASATO 名城大学, 農学部, 教授 (90324805)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 有機化学 / 触媒化学 / 酸化反応 / 触媒 / 高分子 / イオン液体 / 有機ニトロキシルラジカル / イオン性ポリマー / 有機ニトロキシラジカル |
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| Outline of Final Research Achievements |
The use of a novel reaction medium provided by functionalized polymer-gels could often bring a new strategy in the design of reagent or catalyst recycling systems. This work focused on the use of ionic acrylamide-based polymer-gel for the development of novel catalytic oxidation systems. The nitroxyl radical (TEMPO: 2,2,6,6-tetramethylpiperidine 1-oxyl) catalyzed alcohol oxidations proceeded smoothly in non-cross-linked or cross-linked ionic acrylamide-based polymer solution or polymer gel medium. In addition, the polymer-immobilized catalyst can be easily recovered from reaction mixtures and was reused without significant loss of catalytic activities.
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Report
(4 results)
Research Products
(46 results)
