• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Study on Catalytic Radical Reaction Process

Research Project

Project/Area Number 25460028
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Chemical pharmacy
Research InstitutionHyogo University of Health Sciences

Principal Investigator

MIYABE Hideto  兵庫医療大学, 薬学部, 教授 (10289035)

Co-Investigator(Kenkyū-buntansha) 甲谷 繁  兵庫医療大学, 薬学部, 准教授 (00242529)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords有機合成 / ラジカル / 光触媒 / 触媒反応 / 還元反応 / 環境調和 / 有機化学 / 触媒 / 合成化学 / 合成反応
Outline of Final Research Achievements

Our laboratory developed the method for the sequential construction of carbon-carbon bonds based on the radical reactions using a photocatalyst in aqueous media. The utility of ruthenium catalyst and rhodamine B as water-soluble photocatalysts was confirmed in aqueous-medium radical addition-cyclization-trapping reactions under visible light irradiation. The electron transfer from rhodamine B in the excited state was studied by the fluorescence quenching of rhodamine B. The use of titanium dioxide adsorbing coumarin dyes successfully extended the UV response of titanium dioxide toward visible light region.

Report

(4 results)
  • 2016 Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (22 results)

All 2015 2014 2013 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Open Access: 7 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 1 results) Book (1 results) Remarks (4 results)

  • [Journal Article] Direct Photoinduced Electron Transfer from Excited State of Rhodamine B for Carbon-Radical Generation2015

    • Author(s)
      E. Yoshioka, S. Kohtani, T. Jichu, T. Fukazawa, T. Nagai, Y. Takemoto, and H. Miyabe
    • Journal Title

      Synlett

      Volume: 26 Issue: 02 Pages: 265-270

    • DOI

      10.1055/s-0034-1379699

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Carbon radical addition-cyclization reaction induced by ruthenium-photocatalyst under visible light irradiation2015

    • Author(s)
      E. Yoshioka, S. Kohtani, E.Tanaka, Y. Hata, and H. Miyabe
    • Journal Title

      Tetrahedron

      Volume: 71 Issue: 5 Pages: 773-781

    • DOI

      10.1016/j.tet.2014.12.068

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Photohydrogenation of acetophenone using coumarin dye-sensitized titanium dioxide under visible light irradiation2015

    • Author(s)
      S. Kohtani, M. Mori, E. Yoshioka, H. Miyabe
    • Journal Title

      Catalysts

      Volume: 5 Issue: 3 Pages: 1417-1424

    • DOI

      10.3390/catal5031417

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Research and Development of Domino Radical Cyclization Reactions2015

    • Author(s)
      宮部 豪人, 吉岡 英斗, 甲谷 繁
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 73 Issue: 9 Pages: 895-901

    • DOI

      10.5059/yukigoseikyokaishi.73.895

    • NAID

      130005104060

    • ISSN
      0037-9980, 1883-6526
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dye-sensitized photo-hydrogenation of aromatic ketones on titanium dioxide under visible light irradiation2014

    • Author(s)
      S. Kohtani, S. Nishioka, E. Yoshioka, and H. Miyabe
    • Journal Title

      Catal. Commun.

      Volume: 15 Pages: 61-65

    • DOI

      10.1016/j.catcom.2013.09.006

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Kinetic study on photocatalytic hydrogenation of acetophenone derivatives on titanium dioxide2014

    • Author(s)
      S. Kohtani, Y. Kamoi, E. Yoshioka, and H. Miyabe
    • Journal Title

      Catalysis Science and Technology

      Volume: 4 Issue: 4 Pages: 1084-1091

    • DOI

      10.1039/c3cy00879g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Cascade Radical Reactions via Carbon-Carbon/Heteroatom Bond-Forming Process2014

    • Author(s)
      Hideto Miyabe, Yoshiji Takemoto
    • Journal Title

      Universal Organic Chemistry

      Volume: 2 Issue: 1 Pages: 1-9

    • DOI

      10.7243/2053-7670-2-1

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Cascade radical reaction of substrates with a carbon-carbon triple bond as a radical acceptor2013

    • Author(s)
      Hideto Miyabe, Ryuta Asada, Yoshiji Takemoto
    • Journal Title

      Beilstein J. Org. Chem.

      Volume: 9 Pages: 1148-1155

    • DOI

      10.3762/bjoc.9.128

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Cascade Carbon-Carbon Bond-Forming Radical Reaction in Aqueous Media2013

    • Author(s)
      E. Yoshioka, S. Kohtani, E. Tanaka, and Hideto Miyabe
    • Journal Title

      Synlett

      Volume: 12 Issue: 12 Pages: 1578-1582

    • DOI

      10.1055/s-0033-1339182

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Photocatalytic carbon-carbon bond forming reaction in aqueous media2015

    • Author(s)
      宮部 豪人
    • Organizer
      2015 環太平洋国際化学会議
    • Place of Presentation
      ハワイコンベンションセンター(米国ハワイ州ホノルル)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ローダミンBの一重項励起状態からの一電子移動を介したラジカル生成と反応2015

    • Author(s)
      吉岡 英斗、寺中 孝久、深澤 拓也、長井 豊和、甲谷 繁、宮部 豪人
    • Organizer
      第45回複素環化学討論会
    • Place of Presentation
      早稲田大学国際会議場(東京都新宿区)
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 色素増感酸化チタン光触媒による芳香族カルボニル化合物の可視光水素化反応2014

    • Author(s)
      甲谷 繁、西岡早希、森みづ穂、吉岡 英斗、宮部 豪人
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] 酸化チタン上で起こるフッ素化アセトフェノン誘導体の光水素化反応と光脱フッ素化反応に関する考察2014

    • Author(s)
      甲谷 繁、黒川 拓哉、吉岡 英斗、宮部 豪人
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] ローダミンBの励起一重項状態からの光誘起電子移動: パーフルオロアルキルラジカル有機反応への応用2014

    • Author(s)
      吉岡 英斗、甲谷 繁、寺中 孝久、深澤 拓也、長井 豊和、中川 僚太郎、竹本 佳司、宮部 豪人
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] 塩化鉄を用いたビシクロラクタム環の構築2014

    • Author(s)
      吉岡 英斗、池田 朋子、井元 勇希、吉川 知宏、中野 博明、甲谷 繁、宮部 豪人
    • Organizer
      第44回複素環化学討論会
    • Place of Presentation
      札幌市民ホール(北海道札幌市)
    • Year and Date
      2014-09-10 – 2014-09-12
    • Related Report
      2014 Research-status Report
  • [Presentation] 色素増感TiO2光触媒による芳香族ケトン類の可視光水素化反応

    • Author(s)
      甲谷 繁、西岡 早希、吉岡 英斗、宮部 豪人
    • Organizer
      第63回日本薬学会近畿支部総会大会
    • Place of Presentation
      同志社女子大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Research-status Report
  • [Presentation] Ru 光酸化還元触媒を用いたラジカルカスケード反応の開発 ―触媒的水中ラジカル反応―

    • Author(s)
      吉岡 英斗、田中 絵理、甲谷 繁、宮部 豪人
    • Organizer
      第63回日本薬学会近畿支部総会大会
    • Place of Presentation
      同志社女子大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Research-status Report
  • [Book] Titanium Dioxide-Induced Photocatalytic Reduction for Organic Synthesis in “Titanium Dioxide: Chemical Properties, Applications and Environmental Effects”2014

    • Author(s)
      Shigeru Kohtani, Hideto Miyabe
    • Publisher
      Nova Science Pub Inc
    • Related Report
      2014 Research-status Report
  • [Remarks] 兵庫医療大学 薬品化学研究室―有機化学・物理化学

    • URL

      http://www2.huhs.ac.jp/~h070012h/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 兵庫医療大学 教員情報

    • URL

      http://ofcach.ofc.huhs.ac.jp/hhshp/KgApp?kyoinId=ymgdgygyggm

    • Related Report
      2015 Annual Research Report
  • [Remarks] 薬品化学研究室―有機化学・物理化学―

    • URL

      http://www2.huhs.ac.jp/~h070012h/

    • Related Report
      2014 Research-status Report
  • [Remarks] 薬品化学研究室―有機化学・物理化学―

    • URL

      http://www2.huhs.ac.jp/~h070012h/

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi