| Project/Area Number |
25600005
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanostructural chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
KONNO TAKUMI 大阪大学, 理学(系)研究科(研究院), 教授 (50201497)
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| Co-Investigator(Renkei-kenkyūsha) |
NAKAZAWA YASUHIRO 大阪大学, 大学院理学研究科, 教授 (60222163)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | イオン結晶 / 自己組織化 |
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| Outline of Final Research Achievements |
In this work, we investigated the development of a new class of nanostructures, in which cations and anions are separately aggregated into an anomalous charge-separated state, by the effective use of ‘coordination molecular force’ that is defined as a sum of con-covalent interactions involved in a metal complex. As a result, we succeeded in the creation of unprecedented nanostructures, in which a number of cationic and anionic species are aggregated into remarkable cluster forms, by the introduction of functional groups that can form coordination bonding, hydrogen bonding, and CH-π interactions into a metal complex.
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