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Development of nano-fractal prous structure aiming at catalyst reaction field

Research Project

Project/Area Number 25600007
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanostructural chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

MORONUKI Nobuyuki  首都大学東京, システムデザイン研究科, 教授 (90166463)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords微粒子 / 自己整列 / 空孔 / フラクタル / 反応場 / 触媒 / 多孔質構造 / 逆オパール構造
Outline of Final Research Achievements

Drying an aqueous suspension in which particles are dispersed, regular assembly of particles can be obtained. Repeating this process while changing the particle size from larger (e.g. 10 micron) to smaller (e.g. 200 nm), complex assembly can be obtained. Dissolving the larger particles selectively, fractal-like porous structure can be obtained which is suitable for catalyst reaction field. The problem is that it is difficult to make regular structure with high repeatability when various particle materials and sizes are taken into account. This study made clear a model for such repeated self-assembly by formularizing the interaction between various particles. In addition, mechanical strength of the structure was examined because such structure is often put in micro-fluidic systems. Finally, gas sensing function was verified showing the effect of the porous structure.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (13 results)

All 2015 2014 Other

All Journal Article (5 results) (of which Peer Reviewed: 3 results,  Open Access: 3 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] テクスチャリングによる表面機能の発現2015

    • Author(s)
      諸貫信行
    • Journal Title

      トライボロジスト

      Volume: 60 Pages: 165-170

    • NAID

      130005628055

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Fabrication of Patterned Ag and Au Inverse Opal Structures Through Repeated Self-Assembly of Fine Particles2014

    • Author(s)
      Manabu Nishio, Nobuyuki Moronuki, and Minoru Abasaki
    • Journal Title

      International Journal of Automation Technology

      Volume: 8 Pages: 755-760

    • NAID

      130007673858

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Self-assembly of fine particle on three dimensional curved structure2014

    • Author(s)
      西尾 学,諸貫 信行
    • Journal Title

      Transactions of the JSME (in Japanese)

      Volume: 80 Issue: 810 Pages: MN0031-MN0031

    • DOI

      10.1299/transjsme.2014mn0031

    • NAID

      130003399127

    • ISSN
      2187-9761
    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 親水・疎水パターンを設けた溝構造への選択的微粒子整列と微粒子整列開始条件のモデル化2014

    • Author(s)
      西尾 学,諸貫 信行,金子 新
    • Journal Title

      精密工学会誌

      Volume: 80 Pages: 172-176

    • NAID

      130003394527

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] 微粒子を用いた多様な構造形成と機能付与2014

    • Author(s)
      諸貫信行
    • Journal Title

      機械の研究

      Volume: 66 Pages: 195-200

    • NAID

      40019996442

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
  • [Presentation] 犠牲粒子と高誘電率粒子の同時自己整列に基づく逆オパール構造の作製とその光学特性評価2015

    • Author(s)
      岡田 直樹,諸貫 信行
    • Organizer
      精密工学会春季大会
    • Place of Presentation
      東京
    • Year and Date
      2015-03-17 – 2015-03-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 複合的材料の付着による表面機能付与2014

    • Author(s)
      諸貫 信行
    • Organizer
      日本機械学会第10回生産加工・工作機械部門講演会
    • Place of Presentation
      徳島
    • Year and Date
      2014-11-15 – 2014-11-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] 繰返し微粒子自己整列によるフラクタル逆オパール構造の作製2014

    • Author(s)
      西尾 学,諸貫 信行
    • Organizer
      日本機械学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Patterned self-assembly of fine particles on three-dimensional structures

    • Author(s)
      M. Nishio and N. Moronuki
    • Organizer
      7th International Conference on Leading Edge Manufacturing in 21st Century
    • Place of Presentation
      Sendai
    • Related Report
      2013 Research-status Report
  • [Presentation] Repeated self-assembly process to produce three-dimensional inverse opal structure for catalysts,

    • Author(s)
      M. Nishio, N. Moronuki, M. Abasaki
    • Organizer
      euspen
    • Place of Presentation
      Berlin, Germany
    • Related Report
      2013 Research-status Report
  • [Presentation] 犠牲微粒子エッチングによる逆オパール構造の空孔率制御

    • Author(s)
      西尾 学,諸貫 信行
    • Organizer
      日本機械学会第21回機械材料・材料加工技術講演会
    • Place of Presentation
      八王子
    • Related Report
      2013 Research-status Report
  • [Presentation] 微粒子自己整列の適応範囲に関する考察

    • Author(s)
      西尾学,諸貫信行,金子新
    • Organizer
      日本機械学会年次大会講演会
    • Place of Presentation
      岡山
    • Related Report
      2013 Research-status Report
  • [Remarks] 年報

    • URL

      http://www.sd.tmu.ac.jp/RDstaff/data/ma/698/H25.html

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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