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Independent control of electric and thermal conductivities by coherent manipulation of electron and phonon transports using three dimensional nanostructures

Research Project

Project/Area Number 25600016
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanostructural physics
Research InstitutionOsaka University

Principal Investigator

NAKAMURA Yoshiaki  大阪大学, 基礎工学研究科, 教授 (60345105)

Co-Investigator(Renkei-kenkyūsha) KIKKAWA Jun  物質・材料研究機構, 先端的共通技術部門, 主任研究員 (20435754)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords熱電ナノ材料 / 半導体 / 分子線エピタキシー / 熱伝導 / ナノドット / 熱電変換材料 / シリコン系材料 / MBE / ユビキタス元素
Outline of Final Research Achievements

In this study, we aimed at independent control of electric and thermal conductivities using Si films including Ge nanodots, where Si layers and Ge nanodots work as carrier transport layers and phonon scatters, respectively. We formed Si films including epitaxial Ge nanodots using the original ultrathin SiO2 film technique for nanodot formation. As a result, we succeeded in drastic reduction of thermal conductivity with small Ge content compared with conventional SiGe alloy. It was found that the reduction effect depended on the Ge ND size. This means that Ge nanodots dominantly determined the thermal conductivity independently of Si layers for carrier transport. This result gives a guideline for independent control of electric and thermal conductivities.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (34 results)

All 2015 2014 2013

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Acknowledgement Compliant: 1 results) Presentation (25 results) (of which Invited: 6 results) Book (1 results)

  • [Journal Article] Fabrication of Si thermoelectric nanomaterials containing ultrasmall epitaxial Ge nanodots with an ultrahigh density2015

    • Author(s)
      Shuto Yamasaka, Yoshiaki Nakamura, Tmohiro Ueda, Shotaro Takeuchi, Yuta Yamamoto, Shigeo, Arai, Takayoshi Tanji, Nobuo Tanaka and Akira Sakai
    • Journal Title

      J. Electron. Mater.

      Volume: 未定 Issue: 6 Pages: 2015-2020

    • DOI

      10.1007/s11664-015-3643-6

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anomalous reduction of thermal conductivity in coherent nanocrystal architecture for silicon thermoelectric materia2015

    • Author(s)
      Yoshiaki Nakamura, Masayuki Isogawa, Tomohiro Ueda, Shuto Yamasaka, Hideki Matsui, Jun Kikkawa, Satoaki Ikeuchi, Takafumi Oyake, Takuma Hori, Junichiro Shiomi, Akira Sakai
    • Journal Title

      Nano Energy

      Volume: 未定 Pages: 845-851

    • DOI

      10.1016/j.nanoen.2014.11.029

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation and optical properties of Ge films grown on Si(111) substrates using nanocontact epitaxy2015

    • Author(s)
      Kazuki Tanaka, Yoshiaki Nakamura, Shuto Yamasaka, Jun Kikkawa,Takenobu Sakai, Akira Sakai
    • Journal Title

      Appl. Surf. Sci.

      Volume: 325 Pages: 170-174

    • DOI

      10.1016/j.apsusc.2014.11.033

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] elf-assembly of Ge clusters on highly oriented pyrolytic graphite surfaces2014

    • Author(s)
      Masayuki Shimonaka, Yoshiaki Nakamura, Jun Kikkawa, and Akira Saka
    • Journal Title

      Sur. Sci.

      Volume: 628 Pages: 82-85

    • DOI

      10.1016/j.susc.2014.05.018

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of epitaxial growth of Fe-based nanocrystals on Si substrates using well-controlled nanometer-sized interface2014

    • Author(s)
      Yoshiaki Nakamura, Ryota Sugimoto, Takafumi Ishibe, Hideki Matsui, Jun Kikkawa, and Akira Sakai
    • Journal Title

      J. Appl. Phys.

      Volume: 115 Issue: 4

    • DOI

      10.1063/1.4862642

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Luminescence properties of Si-capped b-FeSi2 nanodots epitaxially grown on Si(001) and (111) substrates2014

    • Author(s)
      Shogo Amari, Yoshiaki Nakamura, and Masakazu Ichikawa
    • Journal Title

      J. Appl. Phys.

      Volume: 115 Issue: 8

    • DOI

      10.1063/1.4867037

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of Ge films on Si(001) substrates grown by nanocontact epitaxy2013

    • Author(s)
      Wataru Ikeda, Yoshiaki Nakamura, Shogo Okamoto, Shotaro Takeuchi, Jun Kikkawa, Masakazu Ichikawa, and Akira Sakai
    • Journal Title

      Jpn. J. Appl. Phys. 52 095503 (2013).

      Volume: 52 Issue: 9R Pages: 095503-095503

    • DOI

      10.7567/jjap.52.095503

    • NAID

      40019796373

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of nanometer-sized interface on reaction of iron nanocrystals epitaxially grown on silicon substrates with oxygen gas2013

    • Author(s)
      Hironobu Hamanaka, Yoshiaki Nakamura, Takafumi Ishibe, Jun Kikkawa, and Akira Sakai
    • Journal Title

      J. Appl. Phys.

      Volume: 114 Issue: 11

    • DOI

      10.1063/1.4821770

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Si中エピタキシャルGeナノドットを用いた熱抵抗制御2015

    • Author(s)
      山阪 司祐、中村 芳明、上田 智広、竹内 正太郎、酒井 朗
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 鉄シリサイド核/Siを用いた鉄酸化物のエピタキシャル成長2015

    • Author(s)
      松井 秀紀、中村 芳明、中本 悠太、竹内 正太郎、酒井 朗
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 極薄Si酸化膜技術を用いたSi系熱電ナノ材料の開発2015

    • Author(s)
      中村芳明
    • Organizer
      電子情報通信学会研究会 (SDM、ED)「機能ナノデバイスおよび関連技術」
    • Place of Presentation
      北海道
    • Year and Date
      2015-02-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Epitaxial Growth and Thermoelectric Properties of Stacking Structures of Iron Silicide Nanodots/Si2014

    • Author(s)
      Yoshiaki Nakamura, Masayuki Isogawa, Shuto Yamasaka, Shinya Tsurusaki, Shotaro Takeuchi, Akira Sakai
    • Organizer
      Material research society Fall meeting 2014
    • Place of Presentation
      Boston, USA
    • Year and Date
      2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Epitaxial Growth of Nanodots on Si Substrates with Controlled Interfaces and Their Application to Electronics and Thermoelectronics2014

    • Author(s)
      Yoshiaki Nakamura and Akira Sakai
    • Organizer
      Electrochemical Society 226th meeting
    • Place of Presentation
      Cancun Mexico
    • Year and Date
      2014-10-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] エピタキシャルGeナノドットを有するSi熱 電薄膜の形成とその熱電特性2014

    • Author(s)
      山阪司 祐人、中村芳明、上田 智広、竹内 正太郎、酒井 朗
    • Organizer
      第11回日本熱電学会学術講演会
    • Place of Presentation
      独立行政法人物質・材料研究機構 千現地区管理棟
    • Year and Date
      2014-09-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] エピタキシャル鉄シリサイドナノドット積層構造の熱電特性2014

    • Author(s)
      山阪司祐人,中村芳明,鶴崎晋也,竹内正太郎,酒井朗
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Si基板上エピタキシャルFe3O4-δナノドットの抵抗変化特性とそのアニール処理依存性2014

    • Author(s)
      松井秀紀,中村芳明,竹内正太郎,酒井朗
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-14 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Stacking structures of epitaxial Si nanodots and their thermal conductivity2014

    • Author(s)
      Yoshiaki Nakamura, Masayuki Isogawa, Tomohiro Ueda, Jun Kikkawa, and Akira Sakai
    • Organizer
      ICT2014
    • Place of Presentation
      Nashville, Tennessee
    • Year and Date
      2014-07-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Thermal and electrical properties of Si films including epitaxial Ge nanodot phonon-scatterers2014

    • Author(s)
      S. Yamasaka, Y. Nakamura, T. Ueda, S. Takeuchi, and A. Sakai
    • Organizer
      ICT2014
    • Place of Presentation
      Nashville, Tennessee
    • Year and Date
      2014-07-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] エピタキシャルSiナノドットを用いた熱伝導率の低減と熱電材料への応用2014

    • Author(s)
      中村芳明
    • Organizer
      第51回日本伝熱シンポジウム
    • Place of Presentation
      静岡
    • Year and Date
      2014-05-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] エピタキシャルGeナノドットを有するSi熱電薄膜の電気特性評価2014

    • Author(s)
      山阪司祐人,中村芳明,上田智広,竹内正太郎,酒井明
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川 青山学院
    • Related Report
      2013 Research-status Report
  • [Presentation] エピタキシャルSiナノドット積層構造へのドーピング技術開発とその熱電特性2014

    • Author(s)
      上田智広,中村芳明,竹内正太郎,酒井朗
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川 青山学院
    • Related Report
      2013 Research-status Report
  • [Presentation] 極薄Si酸化膜技術を用いてエピタキシャル成長したSi基板上Fe3O4ナノドットの抵抗スイッチング特性2014

    • Author(s)
      松井秀紀,中村芳明,竹内正太郎,酒井朗
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川 青山学院
    • Related Report
      2013 Research-status Report
  • [Presentation] Anomalous reduction of thermal couductivity of stacked epitaxial Si nanodot structures2014

    • Author(s)
      Yoshiaki Nakamura and Akira Sakai
    • Organizer
      1st KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Osaka Senri Life Science Center
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Introduction of Ultrahigh Density Ge Nanodots into Si Films for Si Based Thermoelectric Materials2014

    • Author(s)
      Shuto Yamasaka, Yoshiaki Nakamura, Tomohiro, Ueda, Shotaro Takeuchi, and Akira Sakai
    • Organizer
      1st KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Osaka Senri Life Science Center
    • Related Report
      2013 Research-status Report
  • [Presentation] Si中エピタキシャルGeナノドット散乱体の熱伝導率低減効果2013

    • Author(s)
      山阪司祐人,中村芳明,上田智広,竹内正太郎,酒井朗
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      京都府 同志社大学
    • Related Report
      2013 Research-status Report
  • [Presentation] エピタキシャルSiナノドット積層構造の形成とその熱伝導率2013

    • Author(s)
      中村芳明,五十川雅之,上田智広,山阪司祐人,吉川純,池内賢朗,酒井朗
    • Organizer
      第十回日本熱電学会学術講演会
    • Place of Presentation
      名古屋市 名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ナノドットを用いたSi系熱電材料の開発2013

    • Author(s)
      中村芳明
    • Organizer
      CREST・さきがけ元素戦略領域合同 第1回公開シンポウジム
    • Place of Presentation
      東京都 東京国際フォーラム
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ナノドットを用いたSi熱電材料の開発2013

    • Author(s)
      中村芳明
    • Organizer
      第22回シリサイド系半導体研究会
    • Place of Presentation
      京都 京都大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Formation of ultrahigh density Fe-based nanodots on Si substrates by controlling Ge nuclei on ultrathin SiO2 film2013

    • Author(s)
      R. Sugimoto, Y. Nakamura, H. Matsui, J. Kikkawa and A. Sakai
    • Organizer
      ACSIN-12 & ICSPM21
    • Place of Presentation
      Tsukuba Tsukuba International Congress Center
    • Related Report
      2013 Research-status Report
  • [Presentation] Reduction effect of thermal conductivity by introduction of epitaxial Ge nanodots in Si2013

    • Author(s)
      Shuto Yamasaka, Yoshiaki Nakamura, Tomohiro Ueda, Shotaro Takeuchi, Akira Sakai
    • Organizer
      ACSIN-12 & ICSPM21
    • Place of Presentation
      Tsukuba Tsukuba International Congress Center
    • Related Report
      2013 Research-status Report
  • [Presentation] Epitaxial growth of iron oxide nanodots on Si substrate and their electronic states2013

    • Author(s)
      Takafumi Ishibe, Yoshiaki Nakamura, Hideki Matsui, Shotaro Takeuchi, and Akira Sakai1
    • Organizer
      ACSIN-12 & ICSPM21
    • Place of Presentation
      Tsukuba Tsukuba International Congress Center
    • Related Report
      2013 Research-status Report
  • [Presentation] Epitaxial growth of stacked -FeSi2 nanodots on Si substrates and their thermoelectric properties2013

    • Author(s)
      Masayuki Isogawa, Yoshiaki Nakamura, Jun Kikkawa, Shotaro Takeuchi and Akira Sakai
    • Organizer
      APAC-Silicide 2013
    • Place of Presentation
      Tsukuba Tsukuba University
    • Related Report
      2013 Research-status Report
  • [Presentation] Introduction of Ge nanodots in Si films as phonon scatterers and the thermal conductivity reduction2013

    • Author(s)
      Shuto Yamasaka, Yoshiaki Nakamura, Tomohiro Ueda, S. Takeuchi, Y. Yamamoto, S. Arai, T. Tanji, N. Tanaka, and A. Sakai
    • Organizer
      The 32nd International Converence on Thermoelectrics (ICT2013)
    • Place of Presentation
      Kobe Kobe International Conference Center
    • Related Report
      2013 Research-status Report
  • [Book] シリサイド系半導体ナノ構造 (3.7節),シリサイド系半導体の科学と技術―資源・環境時代の新しい半導体と関連物質―2014

    • Author(s)
      中村芳明
    • Total Pages
      23
    • Publisher
      裳華房
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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