| Project/Area Number |
25600027
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
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| Research Institution | Kumamoto University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
ITAYA Kingo 東北大学, 多元物質科学研究所, その他 (40125498)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | ナノ材料 / 高分子構造・物性 / 高分子合成 / 界面反応 / 自己組織化 / エマルション / 走査型ブローブ顕微鏡 |
|---|
| Outline of Final Research Achievements |
As a new class of thermosensitive polymer materials, “Janus” nanofilms were produced by the Cu(I)-catalyzed Huisgen click reaction at water-oil interfaces (interface crick reaction) between thermosensitive polymers and lipophilic or hydrophilic polymers. Because the lipophilic polymer, or hydrophilic polymer and a copper catalyst were present in the oil or aqueous phase, respectively, the crosslinking reaction proceeded only at the phase interface. The thermosensitive “Janus” nanofilms with both hydrophilic and thermosensitive surfaces demonstrated a good performance as an actuater.
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