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Control of crystal growth of organic semiconductors by the Moses effect of bulk superconducting magnet

Research Project

Project/Area Number 25600082
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Crystal engineering
Research InstitutionIwate University

Principal Investigator

YOSHIMOTO Noriyuki  岩手大学, 工学(系)研究科(研究院), 教授 (80250637)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords有機半導体 / 結晶成長 / バルク超伝導体 / 磁気応用
Outline of Final Research Achievements

We have demonstrated that high magnetic field provided by a balk superconducting magnet is effective to control the crystal growth of organic semiconductors from solution phase. In this work, the shape of solution is deformed by magnetic force as so-called the Moses effect, and the thickness of solution became very thin at the center of magnet by the diamagnetic nature of organic solvent. As the result of crystal growth, highly oriented thin films could be obtained. The relationship between the crystallinity and TFT performances in obtained organic semicondutor films is examined.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (23 results)

All 2015 2014 2013

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Open Access: 1 results) Presentation (14 results) (of which Invited: 1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Morphology and microstructure of picene thin-films for air-operating transistors2014

    • Author(s)
      Abdou Karim Diallo, Ryouta Kurihara, Noriyuki Yoshimoto, Christine Videlot-Ackermann
    • Journal Title

      Applied Surface Science

      Volume: 314 Pages: 704-710

    • DOI

      10.1016/j.apsusc.2014.07.085

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] リアルタイム2D-GIXDによる有機半導体超薄膜の成長過程の観察2014

    • Author(s)
      吉本則之、渡辺剛、小金澤智之、菊池護、廣沢一郎
    • Journal Title

      SPring-8利用者情報

      Volume: 19 Pages: 313-317

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 放射光を用いた有機薄膜成長の2次元X線回折その場観察2014

    • Author(s)
      吉本則之,渡辺剛,小金澤智之,菊池護,廣沢一郎
    • Journal Title

      表面科学

      Volume: 35 Pages: 190-195

    • NAID

      130004486888

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal structure of oligothiophene thin films characterized by two-dimensional grazing incidence X-ray diffraction2014

    • Author(s)
      Watanabe, T., Koganezawa, T., Kikuchi, M., Videlot-Ackermann, C., Ackermann, J., Brisset, H., Hirosawa, I., Yoshimoto, N.
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 1S Pages: 01AD01-01AD01

    • DOI

      10.7567/jjap.53.01ad01

    • NAID

      210000143279

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Characterization of aryl-functionalized 2,4,6-tris(2-thienyl)-1,3,5-triazine thin films and their application to organic field-effect transistors2013

    • Author(s)
      T. Hosokai, H. Muraoka, M. Mori, R. Kurihara, S. Ogawa, N. Yoshimoto
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 1S Pages: 01AB15-01AB15

    • DOI

      10.7567/jjap.53.01ab15

    • NAID

      210000143273

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electronic properties and field-effect transistors of oligomers end-capped with benzofuran moieties2013

    • Author(s)
      Mallet, C., Didane, Y., Watanabe, T., Yoshimoto, N., Allain, M., Videlot-Ackermann, C., and Frere, P.
    • Journal Title

      ChemPlusChem

      Volume: 78 Issue: 5 Pages: 459-466

    • DOI

      10.1002/cplu.201300037

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and properties of thieno[3,2-b]thiophene derivatives for application of OFET active layer2013

    • Author(s)
      Ito, H., Yamamoto, T., Yoshimoto, N., Tsushima, N., Muraoka, H., Ogawa, S.
    • Journal Title

      Heteroatom Chemistry

      Volume: 24 Issue: 1 Pages: 25-35

    • DOI

      10.1002/hc.21059

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] α,ω-クオターチオフェン誘導体薄膜の結晶成長に及ぼす末端アルキル基の効果2015

    • Author(s)
      小鹿 曹汰、小金澤 智之、山本 秦平、鈴木 充朗、山田 容子、吉本 則之
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 超高真空下での金単結晶上のペンタセンの薄膜形成過程の構造評価2015

    • Author(s)
      小栗貴文,多田圭佑,渡辺剛,小金澤智之,菊池護,谷正安,廣沢一郎,吉本則之
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機薄膜トランジスタ動作中における硬X線光電子分光測定手法の開発2015

    • Author(s)
      渡辺剛,安野聡,多田圭佑,陰野宏,吉本則之,広沢一郎
    • Organizer
      第28回日本放射光学会年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2015-01-10 – 2015-01-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペンタセンおよびパーフルオロペンタセンと,グラフェンとの相互作用2014

    • Author(s)
      鈴木佳之,吉本則之,長谷川正 之,西館数芽
    • Organizer
      第28回分子シミュレーション討論会
    • Place of Presentation
      仙台
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] In-situ 2D-GIXD観察によるペンタセン蒸着膜の構造温度依存性2014

    • Author(s)
      小栗貴文,多田圭佑,渡辺剛,小金澤智之,菊池 護,中村雅一,廣沢一郎,吉本則之
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペンタセン、フッ素化ペンタセン共蒸着膜形成過程の構造その場観察とデバイス特性2014

    • Author(s)
      多田圭佑,渡辺剛,西田広作,小金澤智之,菊池護,廣沢一郎,吉本則之
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 溶液の接触角制御による有機半導体の一方向成長2014

    • Author(s)
      小鹿曹汰, 神谷亮輔, 山本秦平, 鈴木充朗, 山田容子, 吉本則之
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] その場すれすれ入射小角X線散乱測定によるペンタセン薄膜形成中の膜厚の検討2014

    • Author(s)
      渡辺剛,小金澤智之,菊池護,吉本則之,広沢一郎
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属/ペンタセン接合界面の硬X線光電子分光による検討2014

    • Author(s)
      渡辺剛,広沢一郎,陰地宏,多田圭佑,吉本則之
    • Organizer
      第75回応用物理学会学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Graphene/Ru(0001) におけるグラフェンの電子構造:貴金属挿入の効果2014

    • Author(s)
      西館数芽、吉本則之、長谷川正之
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機分子薄膜の結晶成長と構造解析2014

    • Author(s)
      吉本則之
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 磁場を用いた有機半導体溶液の結晶成長制御2014

    • Author(s)
      神谷亮輔,藤代博之,吉本則之
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 2D-GIXDによる有機薄膜太陽電池形成過程のリアルタイム観察2013

    • Author(s)
      西田広作,渡辺剛,小金澤智之,菊池護,小栗貴文,吉本則之
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 二次元X線回折法によるペンタセン、フッ素化ペンタセンmix相の構造評価2013

    • Author(s)
      渡辺剛,西田広作,小金澤智之,菊池護,広沢一郎,吉本則之
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 単結晶膜の製造方法及び単結晶形成用基板2015

    • Inventor(s)
      菅沼直俊,吉本則之
    • Industrial Property Rights Holder
      三星ディスプレイ株式会社,国立大学法人岩手大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-038413
    • Filing Date
      2015-02-28
    • Related Report
      2014 Annual Research Report 2013 Research-status Report
  • [Patent(Industrial Property Rights)] 分析用小型真空蒸着装置および、蒸着膜の成膜時分析方法2013

    • Inventor(s)
      吉本則之、菊池護
    • Industrial Property Rights Holder
      岩手大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-272473
    • Filing Date
      2013-12-27
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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