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Development of photofragment imaging technique of mass-selected cluster ions for the study of dissociation dynamicss

Research Project

Project/Area Number 25620007
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

MISAIZU Fuminori  東北大学, 理学(系)研究科(研究院), 教授 (20219611)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsクラスター / 光解離反応 / 質量分析 / 画像観測 / 装置開発研究 / 電子励起状態 / 結合エネルギー / 飛行時間質量分析計 / リフレクトロン / 化学反応動力学 / 装置開発
Outline of Final Research Achievements

In this study, we have developed a technique of obtaining images of velocity and angular distributions of photofragment ions from cluster ions, which are important as microscopic models of nanomaterials. We have applied this technique to unveil ultraviolet photodissociation dynamics of gas-phase complex monocations of magnesium-argon and magnesium-fluoromethane. We found that both complexes exhibit fast dissociation just after electronic excitation which is localized on the magnesium monocation. In addition, we have determined a ground-state binding energy for the Mg-Ar complex from this measurement.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (24 results)

All 2015 2014 2013 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Acknowledgement Compliant: 6 results) Presentation (9 results) Remarks (2 results)

  • [Journal Article] Structures and CO-Adsorption Reactivities of Nickel Oxide Cluster Cations Studied by Ion Mobility Mass Spectrometry2015

    • Author(s)
      K. Ohshimo, S. Azuma, T. Komukai, R. Moriyama, and F. Misaizu
    • Journal Title

      J. Phys. Chem. C

      Volume: 印刷中 Issue: 20 Pages: 11014-11021

    • DOI

      10.1021/jp5115674

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photofragment imaging from mass-selected ions using a reflectron mass spectrometer I. Development of an apparatus and application to Mg+-Ar complex2015

    • Author(s)
      H. Hoshino, Y. Yamakita, K. Okutsu, Y. Suzuki, M. Saito, K. Koyasu, K.Ohshimo, and F.Misaizu
    • Journal Title

      Chem. Phys. Lett.

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photofragment imaging from mass-selected ions using a reflectron mass spectrometer II. Formation mechanism of MgF+ in photodissociation of Mg+-FCH3 complex2015

    • Author(s)
      K. Okutsu, K. Ohshimo, H. Hoshino, K. Koyasu, and F. Misaizu
    • Journal Title

      Chem. Phys. Lett.

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 移動管法を使った原子分子科学とその周辺  第5回 移動管法によるイオンの異性体分離を利用した研究2015

    • Author(s)
      小安喜一郎、美齊津文典
    • Journal Title

      しょうとつ

      Volume: 12 Pages: 27-35

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isomer Separation of Iron Oxide Cluster Cations by Ion Mobility Mass Spectrometry2014

    • Author(s)
      K.Ohshimo, T. Komukai, R. Moriyama, and F. Misaizu
    • Journal Title

      J. Phys. Chem. A

      Volume: 118 Issue: 22 Pages: 3899-3905

    • DOI

      10.1021/jp5015687

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Compact Non-Rock-Salt Structures in Sodium Fluoride Cluster Ions at Specific Sizes Revealed by Ion Mobility Mass Spectrometry2014

    • Author(s)
      K.Ohshimo, T. Takahashi, R. Moriyama, and F. Misaizu
    • Journal Title

      J. Phys. Chem. A

      Volume: 118 Issue: 43 Pages: 9970-9975

    • DOI

      10.1021/jp5061396

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Application of Ion Mobility-Mass Spectrometry to the Study of Ionic Clusters2014

    • Author(s)
      K.Ohshimo, T. Komukai, T. Takahashi, N. Norimasa, J. W. J. Wu, R. Moriyama, K. Koyasu, and F. Misaizu
    • Journal Title

      Mass Spectrometry

      Volume: 3 Issue: Special_Issue_3 Pages: S0043-S0043

    • DOI

      10.5702/massspectrometry.S0043

    • NAID

      130004972833

    • ISSN
      2186-5116, 2187-137X
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 移動管法を使った原子分子科学とその周辺 第2回 原子衝突分野におけるイオン移動度実験2014

    • Author(s)
      田沼 肇、美齊津文典
    • Journal Title

      しょうとつ

      Volume: 11 Pages: 104-115

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 移動管法を使った原子分子科学とその周辺  第4回 イオン移動度質量分析法によるクラスターイオンの構造研究2014

    • Author(s)
      大下慶次郎、美齊津文典
    • Journal Title

      しょうとつ

      Volume: 11 Pages: 148-156

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Isomer-separated photodissociation of large sized silicon and carbon cluster ions: Drift tube experiment combined with a tandem reflectron mass spectrometer forSi_<24>^+ - Si_<27>^+ and C_<32>^+ - C_<38>^+2013

    • Author(s)
      R. Moriyama, T. Ohtaki, J. Hosoya, K. Koyasu, and F. Misaizu
    • Journal Title

      Eur. Phys. J. D

      Volume: 67 Issue: 1 Pages: 13-13

    • DOI

      10.1140/epjd/e2012-30535-0

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 移動度分析法によって分離された気相クラスター異性体イオンの分光と反応2013

    • Author(s)
      美齊津文典、小安喜一郎
    • Journal Title

      エアロゾル研究

      Volume: 28 Pages: 113-118

    • NAID

      130003367548

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural transition of zinc oxide cluster cations: Smallest tube like structure at (ZnO)6+2013

    • Author(s)
      K. Koyasu, K. Komatsu, and F. Misaizu
    • Journal Title

      J. Chem. Phys.

      Volume: 139 Issue: 16

    • DOI

      10.1063/1.4826465

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structures of cobalt oxide cluster cations studied by ion mobility mass spectrometry2013

    • Author(s)
      K. Ota, K. Koyasu, K. Ohshimo, and F. Misaizu
    • Journal Title

      Chem. Phys. Lett.

      Volume: 588 Pages: 63-67

    • DOI

      10.1016/j.cplett.2013.10.030

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 直線二段反射型質量分析計を用いた(CO2)2+の光解離画像観測2015

    • Author(s)
      藤本圭太、山﨑謙一郎、奥津賢一、中野元善、大下慶次郎、美齊津文典
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉県船橋市
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 直線二段反射型質量分析計を用いたMg+Ar錯体イオンの光解離画像観測2014

    • Author(s)
      山崎謙一郎、奥津賢一、大下慶次郎、美齊津文典
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島県東広島市
    • Year and Date
      2014-09-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photofragment-ion imaging from mass-selected cluster ions using a linear-type tandem reflectron2014

    • Author(s)
      K. Okutsu, K. Yamazaki, K. Ohshimo, and F. Misaizu
    • Organizer
      17th International Symposium on Small Particles and Inorganic Clusters
    • Place of Presentation
      福岡県福岡市
    • Year and Date
      2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of a photofragment ion imaging apparatus using a linear-type tandem reflectron2014

    • Author(s)
      K. Okutsu, K. Yamazaki, K. Ohshimo, and F. Misaizu
    • Organizer
      第30回化学反応討論会
    • Place of Presentation
      兵庫県姫路市
    • Year and Date
      2014-06-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] 反射型飛行時間質量分析計を用いたMg+FCH3の紫外光解離イオン画像観測2014

    • Author(s)
      奥津賢一、大下慶次郎、美齊津文典
    • Organizer
      東北大学理学研究科6専攻合同シンポジウム
    • Place of Presentation
      東北大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 反射型質量分析計による気相錯体イオンMg+ICH3の光解離画像観測2014

    • Author(s)
      山崎謙一郎、奥津賢一、大下慶次郎、美齊津文典
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 直線二段反射型質量分析計を用いたクラスターイオンの光解離画像観測装置の開 発2014

    • Author(s)
      奥津賢一、山崎謙一郎、大下慶次郎、美齊津文典
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Fragment ion imaging from of Mg+FCH3 gas-phase complex with ultraviolet photodissociation2013

    • Author(s)
      K. Okutsu, H. Hoshino, K. Koyasu, and F. Misaizu
    • Organizer
      第29回化学反応討論会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Photodissociation of Mg+ICH3 complex ions observed by using a reflectron mass spectrometer with an imaging detector2013

    • Author(s)
      K. Yamazaki, K. Okutsu, K. Ohshimo, and F. Misaizu
    • Organizer
      平成25年度化学系学協会東北大会及び日本化学会東北支部70周年記念国際会議
    • Place of Presentation
      東北大学
    • Related Report
      2013 Research-status Report
  • [Remarks] 原子分子クラスターイオンの構造と反応動力学

    • URL

      http://qpcrkk.chem.tohoku.ac.jp/research.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 理論化学研究室のページ

    • URL

      http://qpcrkk.chem.tohoku.ac.jp/index.html

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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