| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Outline of Final Research Achievements |
This study is intended to elucidate the dynamical effects depending on the enantiomer. Rotational and orientational state selections of chiral molecules can be selected by hexapole electric field.
By combination of supersonic expansion of seeded molecular beam with hexapole state selection, control of conformer selection was succeeded for 2-butanol.In addition, we performed the theoretical simulations of photodissociation of an oriented chiral molecule (2-bromobutane) by linearly polarized light. Results show the clear difference between racemic mixture and enantiomer. It was found that the angular distribution of photofragments is characteristic of each enantiomer.
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