Soft X-ray spectroscopy and photochemistry of excited triplet molecules
Project/Area Number |
25620016
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Multi-year Fund |
Research Field |
Physical chemistry
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Research Institution | Hiroshima University |
Principal Investigator |
Hiraya Atsunari 広島大学, 理学(系)研究科(研究院), 教授 (40208856)
|
Project Period (FY) |
2013-04-01 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
|
Keywords | 軟X線分光 / 軟X線光科学 / 励起三重項分子 / 軟X線分光 / 励起三重項 / 有機分子 |
Outline of Final Research Achievements |
Though specific bond scission of molecules is known to occur by soft X-ray irradiation, which bond being cut is fixed by molecules. On the other hand, the molecules excited by ultraviolet changes its reactivity. Ever unknown enhancement of specific bond scission by soft X-ray irradiation of excited triplet molecules (long life-time to emit phosphorescence) formed by ultraviolet irradiation. In addition, deeper insight about the mechanism of the selective bond scission by the soft X-radiation was deepened.
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Report
(4 results)
Research Products
(10 results)