Synthesis of macrocyclic acenequinones as a substructure of zigzag-type carbon nanotubes
| Project/Area Number |
25620022
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 大環状化合物 / ポリアセン / キノン / 多環芳香族 / 自己集合 / ナノチューブ |
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| Outline of Final Research Achievements |
Macrocyclic acenes are of interest because of the unique structure, which can be regarded as a substructure of zigzag-type carbon nanotubes. However, theoretical studies have already revealed that macrocyclic acenes are too unstable to be isolated. In this study, we focused on macrocyclic acenequinones, which could also be useful as carbon nanotube substructure.
We developed synthetic strategy to several kinds of 2,3,9,10-tetrasubstituted pentacenequinones. We found that a pentacenequinone derivative having crown ether moieties forms a macrocyclic acene structure upon binding with larger alkali metal ions (K, Rb, Cs).
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Report
(3 results)
Research Products
(36 results)
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[Journal Article] Oxidation Reactivity of a Structurally and Spectroscopically Well-Defined Mononuclear Peroxocarbonato-Iron(III) Complex2015
Author(s)
Tsugawa, T.; Furutachi, H.; Marunaka, M.; Endo, T.; Hashimoto, K.; Fujinami, S.; Akine, S.; Sakata, Y.; Nagatomo, S.; Tosha, T.; Nomura, T.; Kitagawa, T.; Ogura, T.; Suzuki, M.
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Journal Title
Chem. Lett.
Volume: 44
Issue: 3
Pages: 330-332
DOI
NAID
Related Report
Peer Reviewed
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