• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Highly-controlled asymmetric environment using chiral metal nanoclusters

Research Project

Project/Area Number 25620026
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

KOBAYASHI Shu  東京大学, 理学(系)研究科(研究院), 教授 (50195781)

Project Period (FY) 2013-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords反応有機化学 / 触媒
Research Abstract

We attained the construction of highly-controlled asymmetric environment utilizing chiral metal nanocluster catalysts we originally developed. Asymmetric 1,4-addition reactions of aromatic boronic acids with nitroolefins were developed and it became clear that a chiral diene with amide moiety could give high enantioselectivity. Furthermore, three reactions (alcohol oxidation with molecular oxygen, formation of unsaturated carbon-carbon bond, and asymmetric 1,4-addition reactions of arylboronic acids with unsaturated carbonyl compounds) were accumulated and these reactions were found to proceed continuously with high selectivities by sequential addition of catalysts and substrates. Analysis of chiral nanocluster catalysts was also performed.

Report

(2 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • Research Products

    (6 results)

All 2014 Other

All Presentation (6 results)

  • [Presentation] Development of Asymmetric Synthesis Catalyzed by Biomass Supported Chiral Rhodium Nanoparticles and Study of Structure2014

    • Author(s)
      安川知宏・宮村浩之・小林修
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      愛知
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] 高分子固定化金属ナノ粒子触媒を用いた酸素酸化反応, 不飽和結合形成反応及び不斉1, 4-付加反応の集積化2014

    • Author(s)
      鈴木綾・安川知宏・宮村浩之・小林修
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      愛知
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] キラルRhナノ粒子触媒と有機分子触媒の協調作用による不斉炭素-炭素結合生成反応の開発2014

    • Author(s)
      安川知宏・ 西野浩平・ 宮村浩之・ 小林修
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      愛知
    • Year and Date
      2014-03-28
    • Related Report
      2013 Final Research Report
  • [Presentation] Development of Asymmetric Synthesis Catalyzed by Biomass Supported Chiral Rhodium Nanoparticles and Study of Structure

    • Author(s)
      安川 知宏・宮村 浩之・小林 修
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 高分子固定化金属ナノ粒子触媒を用いた酸 素酸化反応,不飽和結合形成反応及び不斉 1,4-付加反応の集積化

    • Author(s)
      鈴木 綾・安川 知宏・宮村 浩之・小林 修
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知)
    • Related Report
      2013 Annual Research Report
  • [Presentation] キラルRhナノ粒子触媒と有機分子触媒の協調作用による不斉炭素-炭素結合生成反応の開発

    • Author(s)
      安川知宏・西野浩平・宮村浩之・小林 修
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(愛知)
    • Related Report
      2013 Annual Research Report

URL: 

Published: 2014-07-25   Modified: 2016-11-25  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi