Exploration of Antiaromatic Stacking and Preparation of Antiaromatic Liquid Crystals
| Project/Area Number |
25620030
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
SHINOKUBO Hiroshi 名古屋大学, 工学(系)研究科(研究院), 教授 (50281100)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 反芳香族 / ポルフィリン / ノルコロール / スタッキング / 液晶 / 求核置換反応 / 直接官能基化 / パイ電子 / 二次電池 / リチウム電池 |
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| Outline of Final Research Achievements |
Norcorrole Ni(II) complex is a strongly antiaromatic porphyrin analogue, which is enough stable to handle in air. In this research, we prepared norcorrole Ni(II) complexes with various substituents and investigated their structures in the solid state.
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Report
(3 results)
Research Products
(23 results)
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[Journal Article] Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole2014
Author(s)
Takaki Fukuoka, Kenya Uchida, Young Mo Sung, Ji-Young Shin, Shintaro Ishida, Dr. Jong Min Lim, Satoru Hiroto, Ko Furukawa, Dongho Kim, Takeaki Iwamoto, Hiroshi Shinokubo
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Journal Title
Angewandte Chemie, International Edition
Volume: 53
Issue: 6
Pages: 1506-1509
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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