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Exploration of Antiaromatic Stacking and Preparation of Antiaromatic Liquid Crystals

Research Project

Project/Area Number 25620030
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionNagoya University

Principal Investigator

SHINOKUBO Hiroshi  名古屋大学, 工学(系)研究科(研究院), 教授 (50281100)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords反芳香族 / ポルフィリン / ノルコロール / スタッキング / 液晶 / 求核置換反応 / 直接官能基化 / パイ電子 / 二次電池 / リチウム電池
Outline of Final Research Achievements

Norcorrole Ni(II) complex is a strongly antiaromatic porphyrin analogue, which is enough stable to handle in air. In this research, we prepared norcorrole Ni(II) complexes with various substituents and investigated their structures in the solid state.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (23 results)

All 2015 2014 2013 2009 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (16 results) (of which Invited: 8 results) Remarks (2 results)

  • [Journal Article] Photodynamics of [26]- and [28]Hexaphyrin-Bodipy Hybrids2014

    • Author(s)
      J.-Y. Shin, K. Kim, J. M. Lim, T. Tanaka, D. Kim, K. Kim, H. Shinokubo, and A. Osuka
    • Journal Title

      Chem. Eur. J.

      Volume: 20 Issue: 16 Pages: 4574-4582

    • DOI

      10.1002/chem.201400315

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of Curved Hexa-peri-hexabenzocoronenes2014

    • Author(s)
      Ryuichi Yamaguchi, Satoru Hiroto, Hiroshi Shinokubo
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 10 Pages: 1637-1639

    • DOI

      10.1246/cl.140577

    • NAID

      130004693827

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] An Antiaromatic Electrode-Active Material Enabling High Capacity and Stable Performance of Rechargeable Batteries2014

    • Author(s)
      J.-Y. Shin, T. Yamada, H. Yoshikawa, K. Awaga, and H. Shinokubo
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 53 Issue: 12 Pages: 3096-3101

    • DOI

      10.1002/anie.201310374

    • Related Report
      2013 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole2014

    • Author(s)
      Takaki Fukuoka, Kenya Uchida, Young Mo Sung, Ji-Young Shin, Shintaro Ishida, Dr. Jong Min Lim, Satoru Hiroto, Ko Furukawa, Dongho Kim, Takeaki Iwamoto, Hiroshi Shinokubo
    • Journal Title

      Angewandte Chemie, International Edition

      Volume: 53 Issue: 6 Pages: 1506-1509

    • DOI

      10.1002/anie.201309921

    • Related Report
      2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Porphyrin Derivatives with Carbon-Metal Bonds2009

    • Author(s)
      H. Shinokubo
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 67 Issue: 7 Pages: 688-700

    • DOI

      10.5059/yukigoseikyokaishi.67.688

    • NAID

      10025399184

    • ISSN
      0037-9980, 1883-6526
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 反芳香族ノルコロールニッケルの位置選択的な直接官能基化2015

    • Author(s)
      野澤 遼,山本 恵太郎,辛 知映,廣戸 聡,忍久保 洋
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機反応化学とポルフィリン化学の接点を求めて2014

    • Author(s)
      忍久保 洋
    • Organizer
      有機合成化学協会東海支部総合講演会
    • Place of Presentation
      静岡
    • Year and Date
      2014-12-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Synthesis, Property, and Reactivity of Norcorrole Ni(II) Complex2014

    • Author(s)
      忍久保 洋
    • Organizer
      Michinoku International Symposium on Porphyrins, Phthalocyanines and Functional π Molecules
    • Place of Presentation
      蔵王
    • Year and Date
      2014-10-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機反応化学とポルフィリン化学の接点を求めて2014

    • Author(s)
      忍久保 洋
    • Organizer
      愛媛大学大学院理工学研究科講演会
    • Place of Presentation
      松山
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ノルコロールの反応性に関する研究2014

    • Author(s)
      野澤 遼,山本 恵太郎,福岡 嵩規,辛 知映,廣戸 聡,忍久保 洋
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2014-09-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジピリン金属錯体を用いた[32]オクタフィリン金属錯体の合成および物性2014

    • Author(s)
      木戸 裕允,辛 知映,忍久保 洋
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2014-09-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] ノルコロールの反応性に関する研究2014

    • Author(s)
      野澤 遼,山本 恵太郎,福岡 嵩規,辛 知映,廣戸 聡,忍久保 洋
    • Organizer
      第46回構造有機若手の会
    • Place of Presentation
      池田
    • Year and Date
      2014-08-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機反応化学とポルフィリン化学の接点を求めて2014

    • Author(s)
      忍久保 洋
    • Organizer
      岡山大学大学院理学研究科講演会
    • Place of Presentation
      岡山
    • Year and Date
      2014-07-31
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Synthesis, Property, Reactivity, and Assembly of Norcorrole Ni(II) Complexes2014

    • Author(s)
      忍久保 洋
    • Organizer
      8th International Conference on Porphyrins and Phthalocyanines (ICPP-8)
    • Place of Presentation
      Istanbul
    • Year and Date
      2014-06-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ジピリンからポルフィリンへ: ポルフィリン類縁体の新合成法の開発2014

    • Author(s)
      忍久保 洋
    • Organizer
      九州大学先導物質化学研究所講演会
    • Place of Presentation
      福岡
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 反芳香族性ノルコールニッケル錯体の還元反応に関する研究2014

    • Author(s)
      山本 恵太郎
    • Organizer
      第94回 日本化学会春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Research-status Report
  • [Presentation] 有機金属化学的手法による新規ポルフィリン類縁体の合成2013

    • Author(s)
      忍久保 洋
    • Organizer
      第103回有機合成シンポジウム
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Organometallic Route to Novel Porphyrins2013

    • Author(s)
      H. Shinokubo
    • Organizer
      Lecture at National University of Singapore
    • Place of Presentation
      Singapore
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Synthesis and Properties of a Stable Antiaromatic Porphyrinoid "Norcorrole"2013

    • Author(s)
      H. Shinokubo
    • Organizer
      15th Asian Chemical Congress (15ACC)
    • Place of Presentation
      Singapore
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] meso置換反芳香族性ノルコロールの合成と物性2013

    • Author(s)
      木戸 裕允
    • Organizer
      第28回基礎有機化学討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Presentation] 反芳香族性ノルコロールとカルベンの反応2013

    • Author(s)
      福岡嵩規
    • Organizer
      第24回基礎有機化学討論会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
  • [Remarks] 忍久保研究室ホームページ

    • URL

      http://www.apchem.nagoya-u.ac.jp/hshino/top.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 名古屋大学プレスリリース

    • URL

      http://www.nagoya-u.ac.jp/about-nu/public-relations/researchinfo/upload_images/20140220_eng.pdf

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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