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Na+ interrelation into Prussian blue analogues

Research Project

Project/Area Number 25620036
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionUniversity of Tsukuba

Principal Investigator

MORITOMO Yutaka  筑波大学, 数理物質系, 教授 (00283466)

Research Collaborator SHIBATA Takayuki  筑波大学, 数理物質系, 研究員 (30758264)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords二次電池 / 元素戦略 / 配位高分子 / エネルギー貯蔵 / Prussian blue analogues / secondary battery / ion intercalation / プルシャンブルー類似体 / Naイオン二次電池 / Naイオンターカレーション
Outline of Final Research Achievements

We fabricated thin films of manganese and cobalt Prussian blue analogues. WE confirmed that these films shows high capacity and voltage in sodium-ion secondary battery cells. We further determined the host structure and valence state of the transition metals by means of ex situ synchrotron-radiation X-ray diffraction and absorption spectroscopy. By these investigations, we indicated that coordination polymer is a promising cathode material for next-generation secondary battery, sodium-ion secondary battery.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (37 results)

All 2015 2014 2013 Other

All Journal Article (12 results) (of which Peer Reviewed: 11 results,  Open Access: 1 results,  Acknowledgement Compliant: 5 results) Presentation (19 results) (of which Invited: 5 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Fast discharge process of layered cobalt oxides due to high Na+ diffusion2015

    • Author(s)
      T. Shibata, Y. Fukuzumi, W. Kobayashi, and Y. Moritomo
    • Journal Title

      Sci. Rep.

      Volume: 5 Issue: 1 Pages: 9006-9006

    • DOI

      10.1038/srep09006

    • NAID

      120007130325

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Erratum: "Sodium Ion Diffusion in Layered NaxCoO22015

    • Author(s)
      T. Shibata, W. Kobayashi, and Y. Moritomo
    • Journal Title

      Appl. Phys. Express

      Volume: 8 Issue: 2 Pages: 029201-029201

    • DOI

      10.7567/apex.8.029201

    • NAID

      210000137413

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Erratum: "Sodium ion diffusion in layered NaxMnO2 (0.49<= x <=0.75): Comparison with NaxCoO22015

    • Author(s)
      T. Shibata, W. Kobayashi, and Y. Moritomo
    • Journal Title

      Appl. Phys. Express

      Volume: 8 Issue: 2 Pages: 029202-029202

    • DOI

      10.7567/apex.8.029202

    • NAID

      210000137414

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Sodium ion diffusion in layered NaxMnO2 (0.49<= x <=0.75): Comparison with NaxCoO22014

    • Author(s)
      T. Shibata, W. Kobayashi, and Y. Moritomo
    • Journal Title

      Appl. Phys. Express

      Volume: 7 Issue: 6 Pages: 067101-067101

    • DOI

      10.7567/apex.7.067101

    • NAID

      210000137146

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical, structural, and electronic properties of Mn–Co hexacyanoferrates against Li concentration2014

    • Author(s)
      Y. Kurihara and Y. Moritomo
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 53 Issue: 6 Pages: 067101-067101

    • DOI

      10.7567/jjap.53.067101

    • NAID

      210000144048

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ionic model approach to battery voltage of NaMO22014

    • Author(s)
      W. Kobayashi, and Y. Moritomo
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 83 Issue: 10 Pages: 104712-104712

    • DOI

      10.7566/jpsj.83.104712

    • NAID

      210000133312

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ultrafast cation intercalation in nanoporous nickel hexacyanoferrate2014

    • Author(s)
      T. Shibata and Y. Moritomo
    • Journal Title

      Chem Comm.

      Volume: 50 Issue: 85 Pages: 12941-12941

    • DOI

      10.1039/c4cc04564e

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synchrotron-Radiation X-Ray Investigation of Li^+/Na^+ Intercalation into Prussian Blue Analogues2013

    • Author(s)
      Yutaka Moritomo, Masamitsu Takachi, Yutaro Kurihara and Tomoyuki Matsuda
    • Journal Title

      Advances in Materials Science and Engineering

      Volume: Volume2013 Pages: 967285-967285

    • DOI

      10.1155/2013/967285

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Properties of Manganese Hexaqyanoferrates against Li Concentration2013

    • Author(s)
      Yutaro Kurihara, Tomoyuki Matsuda, Yutaka Moritomo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 1R Pages: 17301-17301

    • DOI

      10.7567/jjap.52.017301

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural, Electronic, and Electrochemical Properties of LixCo[Fe(CN)6]0:902.9H2O2013

    • Author(s)
      Masamitsu Takachi, Tomoyuki Matsuda, and Yutaka Moritomo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 4R Pages: 44301-44301

    • DOI

      10.7567/jjap.52.044301

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Redox Reactions in Prussian Blue Analogue Films with Fast Na+ Intercalation2013

    • Author(s)
      M. Takachi, T. Matsuda, and Y. Moritomo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 52 Issue: 9R Pages: 90202-90202

    • DOI

      10.7567/jjap.52.090202

    • NAID

      210000142777

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Li+; Intercalation of Manganese Ferrocyanide as Investigated by In situ Valence-Differential Absorption Spectroscopy2013

    • Author(s)
      Y. Moritomo, K. Wakaume, M. Takachi, X.-H. Zhu, and H. Kamioka
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 82 Issue: 9 Pages: 94710-94710

    • DOI

      10.7566/jpsj.82.094710

    • NAID

      40019788714

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] high Na-ion diffusion constant in cathode materials for SIB2015

    • Author(s)
      Y. Moritomo
    • Organizer
      CENIDE-CNMM-TIMS Joint Symposiu
    • Place of Presentation
      ディスブルク(ドイツ)
    • Year and Date
      2015-03-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Diffusion constant of Li+/Na+ in Prussian Blue analogues2015

    • Author(s)
      M. Takachi Y. Fukuzumi, and Y. Moritomo
    • Organizer
      CENIDE-CNMM-TIMS Joint Symposium
    • Place of Presentation
      ディスブルク(ドイツ)
    • Year and Date
      2015-03-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Niプルシャンブルー類似体における高速インターカレーション2015

    • Author(s)
      柴田 恭幸, 濱口 純, 守友 浩
    • Organizer
      第62回応用物理学会春季学術講演会応用物理学会
    • Place of Presentation
      東海大学(平塚)
    • Year and Date
      2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] P2型NaxCoO2薄膜電極の放電曲線のレート依存性2015

    • Author(s)
      柳田 歩, 柴田 恭幸, 小林 航, 守友 浩
    • Organizer
      第62回応用物理学会春季学術講演会応用物理学会
    • Place of Presentation
      東海大学(平塚)
    • Year and Date
      2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] エネルギー変換・貯蔵部門2015

    • Author(s)
      守友 浩
    • Organizer
      CiRfSEシンポジウム
    • Place of Presentation
      筑波大学(つくば)
    • Year and Date
      2015-03-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] P2型NaxMO2の結晶構造の温度依存性2015

    • Author(s)
      赤羽 隆弘, 柳田 歩, 小林 航, 守友 浩
    • Organizer
      第62回応用物理学会春季学術講演会応用物理学会
    • Place of Presentation
      東海大学(平塚)
    • Year and Date
      2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 層状酸化物AMO2の電子レベルの構造解析2014

    • Author(s)
      守友 浩、柴田恭幸、小林渡、西堀英治
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] プルシャンブルー類似体のイオン拡散係数2014

    • Author(s)
      高地 雅光, 守友 浩
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Co-Mnプルシャンブルー類似体の電気化学特性2014

    • Author(s)
      守友 浩、栗原佑太郎
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2014-11-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] NaxMO2(M=Co,Mn)薄膜における電気化学特性2014

    • Author(s)
      柴田 恭幸, 小林 航, 守友 浩
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2014-11-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオンモデルによるO3型層状酸化物の電位の考察2014

    • Author(s)
      小林 航, 守友 浩
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2014-11-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] O3型NaCoO2薄膜の電気化学特性2014

    • Author(s)
      柴田恭幸,小林 航,守友 浩
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Sodium ion diffusion in layered NaxCoO22014

    • Author(s)
      柴田恭幸
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(札幌)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structural and electronic properties of several cathode materials for sodium-ion secondary batteries2014

    • Author(s)
      Y. Moritomo
    • Organizer
      TNS'14
    • Place of Presentation
      筑波大学(つくば)
    • Year and Date
      2014-07-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Prussian blue analogues as promissing cathode candidates for Na+ secondary battery2013

    • Author(s)
      Y. Moritomo
    • Organizer
      TJSST201
    • Place of Presentation
      チュニス(チュニジア)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Prussiona blue analogues as promissing cathode candidates for Na+ secondary battery2013

    • Author(s)
      Y. Moritomo
    • Organizer
      電池討論会(国際セッション)
    • Place of Presentation
      大阪国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] プルシャンブルー類似体の負の熱膨張効果2013

    • Author(s)
      守友浩
    • Organizer
      物理学会シンポジウム
    • Place of Presentation
      徳島大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] コバルトプルシャンブルー薄膜の電気化学特性2013

    • Author(s)
      高地雅光, 松田智行, 守友 浩
    • Organizer
      電池討論会
    • Place of Presentation
      大阪国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] Prussiona blue analogues as promissing cathode candidates for Li+ and Na+ secondary battery

    • Author(s)
      Y, Moritomo
    • Organizer
      ISIS17
    • Place of Presentation
      仙台国際会議場
    • Related Report
      2013 Research-status Report
  • [Book] 放射性物質の吸着・除染および耐放射線技術における材料・施工・測定の新技術2015

    • Author(s)
      末吉 知カ也、(他117名)、守友 浩
    • Total Pages
      633
    • Publisher
      技術情報協会
    • Related Report
      2014 Annual Research Report
  • [Book] 次世代蓄電池の【最新】材料技術と性能評価2015

    • Author(s)
      佐藤 登 他、守友 浩
    • Total Pages
      829
    • Publisher
      技術情報協会
    • Related Report
      2014 Annual Research Report
  • [Book] 『次世代蓄電池の【最新】材料技術と性能評価』の一部2013

    • Author(s)
      守友 浩、他134名
    • Total Pages
      800
    • Publisher
      (株)技術情報協会
    • Related Report
      2013 Research-status Report
  • [Remarks] 守友研究室

    • URL

      http://www.u.tsukuba.ac.jp/~moritomo.yutaka.gf/

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] ナトリウムイオン二次電池用負極、ナトリウムイオン二次電池、リチウムイオン二次電池用負極、リチウムイオン二次電池2014

    • Inventor(s)
      守友 浩、柴田恭幸
    • Industrial Property Rights Holder
      筑波大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-222946
    • Filing Date
      2014-10-31
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 水溶性放射性物質の除去・濃縮装置および水溶性放射性物質の除去・濃縮方法2014

    • Inventor(s)
      守友 浩、濱口純、柴田恭幸
    • Industrial Property Rights Holder
      筑波大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-259441
    • Filing Date
      2014-12-22
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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