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Creation of methalladithiolene pi-nanosheet

Research Project

Project/Area Number 25620037
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Nishihara Hiroshi  東京大学, 理学(系)研究科(研究院), 教授 (70156090)

Co-Investigator(Kenkyū-buntansha) SAKAMOTO Ryota  東京大学, 大学院理学系研究科, 助教 (80453843)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsメタラジチオレン錯体 / ナノシート / 界面合成 / 導電性 / 金属錯体 / パイ共役ナノシート / 混合原子価状態 / スーパーキャパシター / ジチオレン / 分子エレクトロニクス / ディラック電子系
Outline of Final Research Achievements

In this research project, we conducted the establishment of metal complex nanosheets (thin films with the thickness of single-atom level to nano-meter order) and the evaluation of their physical properties. We developed the fabrication process to form dense and multilayered nanosheet on a substrate, and the new nanosheet synthesis method using the interface between a substrate surface and vapors of a metal ion and a ligand. The conductivity moderation of nanosheet was achieved by the electronic state control. In addition, we created functional nanosheets which show the electrochromic behaviors or the photocurrent generation. These results exhibited that metal complex nanosheets can be new attractive nano materials.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (35 results)

All 2015 2014 2013 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (25 results) (of which Int'l Joint Research: 1 results,  Invited: 23 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Rapid Electron Transport Phenomenon in the Bis(terpyridine)metal Complex Wire: Marcus Theory and Electrochemical Impedance Spectroscopy Study2015

    • Author(s)
      Ryota Sakamoto, Hiroaki Maeda, Hiroshi Nishihara
    • Journal Title

      J. Phys. Chem. Lett.

      Volume: 6 Issue: 19 Pages: 3821-3826

    • DOI

      10.1021/acs.jpclett.5b01725

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochromic Bis(terpyridine)Iron(II) Complex Nanosheets2015

    • Author(s)
      Kenji Takada, Ryota Sakamoto, Shi-Ting Yi, Shunsuke Katagiri, Tetsuya Kambe, Hiroshi Nishihara
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 14 Pages: 4681-4689

    • DOI

      10.1021/ja510788b

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A photofunctional bottom-up bis(dipyrrinato)zinc(II) complex nanosheet2015

    • Author(s)
      Ryota Sakamoto, Ken Hoshiko, Qian Liu, Toshiki Yagi, Tatsuhiro Nagayama, Shinpei Kusaka, Mizuho Tsuchiya, Yasutaka Kitagawa, Wai-Yeung Wong, Hiroshi Nishihara
    • Journal Title

      Nature Commun. 2015, 6,

      Volume: 6 Issue: 1 Pages: 6713-6713

    • DOI

      10.1038/ncomms7713

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π–Nanosheet: A Potential Organic Two-Dimensional Topological Insulator2014

    • Author(s)
      T. Kambe, R. Sakamoto, T. Kusamoto, T. Pal, N. Fukui, K. Hoshiko, T. Shimojima, Z. Wang, K. Ishizaka, S. Hasegawa, F. Liu, and H. Nishihara
    • Journal Title

      Journal of the American Chemical Society

      Volume: 136 Issue: 41 Pages: 14357-14360

    • DOI

      10.1021/ja507619d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Dense and Multi-layered Films of The Nickel Bis (dithiolene) Nanosheet By Means of The Langmuir-Schafer Method2014

    • Author(s)
      K. Hoshiko, Tetsuya Kambe, R. Sakamoto, K. Takada, and H. Nishihara
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 2 Pages: 252-253

    • DOI

      10.1246/cl.130882

    • NAID

      130004867969

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] π-Conjugated Trinuclear Group-9 Metalladithiolenes with a Triphenylene Backbone2013

    • Author(s)
      R. Sakamoto, Tetsuya Kambe, S. Tsukada, K. Takada, K. Hoshiko, Y. Kitagawa, M. Okumura, H. Nishihara
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 13 Pages: 7411-7416

    • DOI

      10.1021/ic400110z

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 界面配位プログラミングによる電子機能ナノ構造体の構築2013

    • Author(s)
      松岡 亮太、坂本 良太、山野井 慶徳、西原 寛
    • Journal Title

      ナノ学会会報

      Volume: 11 Pages: 63-69

    • NAID

      40019741142

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 2D Amino-based pi-conjugated Nickel Complex Nanosheets2015

    • Author(s)
      Eunice Phua, Ryota Sakamoto, Hiroshi Nishihara
    • Organizer
      The 16th International Conference on the Science and Application of Nanotubes (NT15)
    • Place of Presentation
      名古屋大学(愛知県、名古屋市)
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of metal complex pi-nanosheets and their redox and electronic properties2014

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      ACS National Fall Meeting San Francisco
    • Place of Presentation
      サンフランシスコ(アメリカ)
    • Year and Date
      2014-08-14
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Interfacial Coordination Programming of Functional Molecular Networks2014

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      41st International Conference on Coordination Chemistry
    • Place of Presentation
      シンガポール(シンガポール)
    • Year and Date
      2014-07-21
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Interfacial Synthesis of Redox-active Metal Complex Nanosheets2014

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      International Symposium on Synthetic Two-Dimensional Polymers
    • Place of Presentation
      チューリッヒ(スイス)
    • Year and Date
      2014-06-02
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 「ボトムアップ型」金属錯体ナノシート・ナノワイヤ2014

    • Author(s)
      坂本 良太
    • Organizer
      第1回「東北大学リーデイング大学院(物質)」研究会「金属錯体の固体物性最前線ー金属錯体と固体物性物理と生物物性の連携新領域をめざしてー」
    • Place of Presentation
      仙台(宮城)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Coordination Programming of Functional Molecular Wires and Sheets2014

    • Author(s)
      Ryota Sakamoto
    • Organizer
      Asian International Symposium in The 93rd Annual Meeting
    • Place of Presentation
      名古屋(愛知)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Interfacial Coordination Programming of Electro-functional Metal Complex Wires and Nanosheets2014

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      1st Inorganic Chemistry Frontiers International Symposium
    • Place of Presentation
      Beijing(China)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Coordination Programming of Photo- and Electro-Functional Molecular Assemblies2013

    • Author(s)
      Ryota Sakamoto
    • Organizer
      Japan-China young scientist symposium "Frontier of coordination chemistry at the interface of nano and micro"
    • Place of Presentation
      岡崎(愛知)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Coordination Programming of Photo- and Electro-Functional Molecular Assemblies2013

    • Author(s)
      Ryota Sakamoto, Yoshinori Yamanoi, Hiroshi Nishiahra
    • Organizer
      15th Asian Chemical Congress 2013 (15 ACC)
    • Place of Presentation
      Singapore(Singapore)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Interfacial Synthesis of Redox-active Metal Complex Nanowires and Nanosheets

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      Eleventh ISEAC International Discussion Meet on Electrochemistry and its Applications
    • Place of Presentation
      Mumbai(India)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 金属錯体ナノシートの界面配位合成と電子機能

    • Author(s)
      西原 寛
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋(愛知)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 金属錯体ワイヤ及びナノシートの界面合成と電子機能

    • Author(s)
      西原 寛
    • Organizer
      第4回分子アーキテクトにクス研究会
    • Place of Presentation
      東京(東京)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 二相界面を用いたπ共役金属錯体ナノシートの創製

    • Author(s)
      神戸 徹也, 坂本 良太, 西原 寛
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      西原(沖縄)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 配位プログラミング-分子超構造体の科学と化学素子の創製

    • Author(s)
      西原 寛
    • Organizer
      CSJ化学フェスタ 2013
    • Place of Presentation
      東京(東京)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 界面配位プログラミングを用いる機能性分子ネットワークの創製

    • Author(s)
      西原 寛
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京(東京)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 界面配位プログラミングによる錯体分子ネットワークの合成と電子機能

    • Author(s)
      西原 寛
    • Organizer
      2013年度第2回シングルナノパターニング研究グループ講演会
    • Place of Presentation
      東京(東京)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 配位プログラミングによる光・電子機能性分子ネットワークの創製

    • Author(s)
      西原 寛
    • Organizer
      バイオメディカル研究部門 部門セミナー
    • Place of Presentation
      東京(東京)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Interfacial Synthesis of Electrochemically Functional Metal Complex Nanowires and Nanosheets

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      Zing Coordination Chemistry Conference 2013
    • Place of Presentation
      Playa del Carmen(Mexico)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Coordination Programming of Electro-functional Molecular Wires and Sheets

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      The 2nd Japan-France Coordination Chemistry Symposium
    • Place of Presentation
      奈良(奈良)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Synthesis of &pi-Conjugated Metal Complex Nanosheets by Interfacial Coordination Reactions

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      International Symposium on Organic Reaction-11
    • Place of Presentation
      Taipei(Taiwan)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Interfacial Synthesis of Metal Complex Nanowires and Nanosheets

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      4th Asian Conference on Coordination Chemistry
    • Place of Presentation
      Jeju(Korea)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Coordination Programming of π-Conjugated Metal Complex Nanosheets

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      Canada-Japan Joint Symposium on Coordination Chemistry
    • Place of Presentation
      西原(沖縄)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Interfacial Synthesis of Redox-active and Conducting Metal Complex Nanosheets

    • Author(s)
      Hiroshi Nishihara, Ryota Sakamoto, Tetsuya Kambe, Kenji Takada, Ken Hoshiko, Ryota Sakamoto
    • Organizer
      64th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Santiago de Queretaro(Mexico)
    • Related Report
      2013 Research-status Report
  • [Presentation] Interfacial Synthesis of Redox-active Metal Complex Nanowires and Nanosheets

    • Author(s)
      Hiroshi Nishihara
    • Organizer
      UPAC 2013 44th World Chemistry Congress
    • Place of Presentation
      Istanbul(Turkey)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] π-Conjugated Nickel Bisdithiolene Complex Nanosheet

    • Author(s)
      Tetsuya Kambe, Ryota Sakamoto, Hiroshi Nishihara
    • Organizer
      MMC-15 15th IUPAC International Symposium on Macromolecular Complexes
    • Place of Presentation
      Greenville(USA)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Book] 錯体化学会選書9金属錯体の電子移動と電気化学2013

    • Author(s)
      坂本 良太、前田 啓明、西原 寛
    • Total Pages
      400
    • Publisher
      三共出版
    • Related Report
      2013 Research-status Report
  • [Book] Comprehensive Inorganic Chemistry II2013

    • Author(s)
      Ryota Sakamoto, Hiroshi Nishihara
    • Total Pages
      1258
    • Publisher
      Elsevier
    • Related Report
      2013 Research-status Report
  • [Remarks] 東京大学大学院理学系研究科化学専攻無機化学研究室

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/inorg/index.html

    • Related Report
      2015 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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