Creation of methalladithiolene pi-nanosheet
| Project/Area Number |
25620037
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
Nishihara Hiroshi 東京大学, 理学(系)研究科(研究院), 教授 (70156090)
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| Co-Investigator(Kenkyū-buntansha) |
SAKAMOTO Ryota 東京大学, 大学院理学系研究科, 助教 (80453843)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | メタラジチオレン錯体 / ナノシート / 界面合成 / 導電性 / 金属錯体 / パイ共役ナノシート / 混合原子価状態 / スーパーキャパシター / ジチオレン / 分子エレクトロニクス / ディラック電子系 |
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| Outline of Final Research Achievements |
In this research project, we conducted the establishment of metal complex nanosheets (thin films with the thickness of single-atom level to nano-meter order) and the evaluation of their physical properties. We developed the fabrication process to form dense and multilayered nanosheet on a substrate, and the new nanosheet synthesis method using the interface between a substrate surface and vapors of a metal ion and a ligand. The conductivity moderation of nanosheet was achieved by the electronic state control. In addition, we created functional nanosheets which show the electrochromic behaviors or the photocurrent generation. These results exhibited that metal complex nanosheets can be new attractive nano materials.
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Report
(4 results)
Research Products
(35 results)
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[Journal Article] A photofunctional bottom-up bis(dipyrrinato)zinc(II) complex nanosheet2015
Author(s)
Ryota Sakamoto, Ken Hoshiko, Qian Liu, Toshiki Yagi, Tatsuhiro Nagayama, Shinpei Kusaka, Mizuho Tsuchiya, Yasutaka Kitagawa, Wai-Yeung Wong, Hiroshi Nishihara
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Journal Title
Nature Commun. 2015, 6,
Volume: 6
Issue: 1
Pages: 6713-6713
DOI
Related Report
Peer Reviewed / Open Access
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[Journal Article] Redox Control and High Conductivity of Nickel Bis(dithiolene) Complex π–Nanosheet: A Potential Organic Two-Dimensional Topological Insulator2014
Author(s)
T. Kambe, R. Sakamoto, T. Kusamoto, T. Pal, N. Fukui, K. Hoshiko, T. Shimojima, Z. Wang, K. Ishizaka, S. Hasegawa, F. Liu, and H. Nishihara
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Journal Title
Journal of the American Chemical Society
Volume: 136
Issue: 41
Pages: 14357-14360
DOI
Related Report
Peer Reviewed
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