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Control of magnetic and electronic properties of charge-transfer DA chains by doping of insulator species

Research Project

Project/Area Number 25620041
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionTohoku University

Principal Investigator

MIYASAKA Hitoshi  東北大学, 金属材料研究所, 教授 (50332937)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords電荷移動錯体 / 電子ドナー・アクセプター / ドーピング / 磁性 / 伝導性 / 一次元鎖 / 中性―イオン性転移 / 中性ーイオン性転移
Outline of Final Research Achievements

The doping of a redox-inert (insulator) dopant (P) into a D+A- chain in place of neutral D enables the creation of mixed valency A0/A- domains between P units: P-(D+A-)nA-P, where n is directly dependent on the dopant ratio, and charge transfer through the P units leads to electron transport along the framework. This hypothesis was experimentally demonstrated in an ionic DA chain synthesized from a redox-active paddlewheel [Ru2II,II] complex and TCNQ derivative by doping with a redox-inert [Rh2II,II] complex.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (37 results)

All 2015 2014 2013 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (22 results) (of which Invited: 22 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Systematic Tuning and Switching of Neutral and Ionic Phases in a Donor/Acceptor Chain Compound by Doping Dummy Donors and Pressure Application2014

    • Author(s)
      Keita Nakabayashi, Hitoshi Miyasaka
    • Journal Title

      Chem. Eur. J.

      Volume: 20 Issue: 17 Pages: 5121-5131

    • DOI

      10.1002/chem.201304420

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Doping Effect in a Three-Dimensional Donor/Acceptor Magnet: Percolated Magnetic Pathways Formed Dependent on Local Electron Transfers from Dopant to Acceptor2014

    • Author(s)
      Hiroki Fukunaga, Wataru Kosaka, Hitoshi Miyasaka
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 4 Pages: 541-543

    • DOI

      10.1246/cl.131119

    • NAID

      130004868073

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetic Sponge Phenomena Associated with Interchain Dipole-Dipole Interactions in a Series of Ferrimagnetic Chain Compounds Doped with Minor Diamagnetic Species2014

    • Author(s)
      Masaki Nishio, Hitoshi Miyasaka
    • Journal Title

      Inorg. Chem.

      Volume: 53 Issue: 9 Pages: 4716-4723

    • DOI

      10.1021/ic500413j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Coordination Programming in the Design of Porous Coordination Polymers: Tuning of the Electronic Activity of Frameworks for Selective NO Trapping2014

    • Author(s)
      Wataru Kosaka, Kayo Yamagishi, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, Hitoshi Miyasaka
    • Journal Title

      Chem. Lett.

      Volume: 43 Pages: 890-892

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Gate-Opening Gas Adsorption and Host-Guest Interacting Gas Trapping Behavior of Porous Coordination Polymers under Applied AC Electric Fields2014

    • Author(s)
      Wataru Kosaka, Kayo Yamagishi, Jun Zhang, Hitoshi Miyasaka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 35 Pages: 12304-12313

    • DOI

      10.1021/ja504992g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Carrier Concentration Dependent Conduction in Insulator-Doped Donor/Acceptor Chain Compounds2014

    • Author(s)
      Masaki Nishio, Norihisa Hoshino, Wataru Kosaka, Tomoyuki Akutagawa, Hitoshi Miyasaka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 47 Pages: 17715-17718

    • DOI

      10.1021/ja409785a

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: Gate-open performance dependent on inter-chain interactions2013

    • Author(s)
      Wataru Kosaka, Kayo Yamagishi, Hiroki Yoshida, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, Hitoshi Miyasaka
    • Journal Title

      Chem. Commun.

      Volume: 49 Issue: 16 Pages: 1594-1596

    • DOI

      10.1039/c2cc36153a

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Control of Charge Transfer in Donor/Acceptor Metal-Organic Frameworks2013

    • Author(s)
      Hitoshi Miyasaka
    • Journal Title

      Acc. Chem. Res.

      Volume: 46 Issue: 2 Pages: 248-257

    • DOI

      10.1021/ar300102t

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Donor/acceptor neutral aggregation of a paddlewheel-type [Ru2II,II] complex and TCNQ2013

    • Author(s)
      Wataru Kosaka, Yudai Ishii, Hitoshi Miyasaka
    • Journal Title

      Polyhedron

      Volume: 52 Pages: 1213-1218

    • DOI

      10.1016/j.poly.2012.06.040

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Polyoxometalate-based Frameworks with a Linker of Paddlewheel Diruthenium(II, III) Complexes2013

    • Author(s)
      A. Hashikawa, Y. Sawada, Y. Yamamoto, M. Nishio, W. Kosaka, Y. Hayashi, H. Miyasaka
    • Journal Title

      Cryst. Eng. Comm.

      Volume: 15 Issue: 24 Pages: 4852-4859

    • DOI

      10.1039/c3ce40426a

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Axial-Site Modifications of Paddlewheel Diruthenium(II, II) Complexes Supported by Hydrogen Bonding2013

    • Author(s)
      Wataru Kosaka, Naoto Yamamoto, Hitoshi Miyasaka
    • Journal Title

      Inorg. Chem.

      Volume: 52 Issue: 17 Pages: 9908-9914

    • DOI

      10.1021/ic401030r

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets2013

    • Author(s)
      Masaki Nishio, Natsuko Motokawa, Miho Takemura, Hitoshi Miyasaka
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 45 Pages: 15898-15901

    • DOI

      10.1039/c3dt51271a

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Selective NO Trapping in the Pores of Chain-Type Complex Assemblies Based on Electronically Activated Paddlewheel-Type [Ru2II,II]/[Rh2II,II] Dimers2013

    • Author(s)
      Wataru Kosaka, Kayo Yamagishi, Akihiro Hori, Hiroshi Sato, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, Hitoshi Miyasaka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135 Issue: 49 Pages: 18469-18480

    • DOI

      10.1021/ja4076056

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Functional MOFs toward the Synergistic Control of Electrons, Spins, Structures, and Chemical Interactions2015

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      ACS 249th National Meeting
    • Place of Presentation
      Denver, Colorado (USA)
    • Year and Date
      2015-03-22 – 2015-03-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 多次元格子内電子移動制御による機能創発2015

    • Author(s)
      宮坂 等
    • Organizer
      106.未来研究イニシアティブ「分子技術とスピン」
    • Place of Presentation
      大阪大学 豊中キャンパス
    • Year and Date
      2015-03-17 – 2015-03-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ドナー・アクセプター集積体における機能制御2015

    • Author(s)
      宮坂 等
    • Organizer
      第2回東北大学リーデイング大学院研究会 「金属錯体の固体物性最前線 ― 金属錯体と固体物性物理と生物物性の連携新領域を目指して ―」
    • Place of Presentation
      東北大学理学部化学第4講義室(大学院講義室)
    • Year and Date
      2015-02-20 – 2015-02-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional MOFs: Tuning of Charge Tranfer toward the synergistic control of electrons, spins, structures, and chemical interactions2014

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      9th Joint Conference on Chemistry a International Conference (JCC-9)
    • Place of Presentation
      Semarang (Indonesia)
    • Year and Date
      2014-11-12 – 2014-11-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Design of functional MOFs toward the synergistic control of electron, spins, structure, and chemical interactions2014

    • Author(s)
      HItoshi Miyasaka
    • Organizer
      日英錯体化学ジョイントシンポジウム
    • Place of Presentation
      中央大学
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 化学的相互作用/物理応答変換を目指した分子設計とデバイス化への試み2014

    • Author(s)
      宮坂 等
    • Organizer
      研究会「配位シナジー:コンポジット錯体の創成と化学エネルギー操作」
    • Place of Presentation
      筑波大学 東京キャンパス 文京校舎2階 講義室9
    • Year and Date
      2014-08-02
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 錯体物性化学:電子・スピン・構造・化学反応を協奏制御する2014

    • Author(s)
      宮坂 等
    • Organizer
      2014年錯体化学若手の会夏の学校
    • Place of Presentation
      サンシャイン白子(千葉県長生郡白子町)
    • Year and Date
      2014-08-01 – 2014-08-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional MOFs: Design by Tuning of Charge Transfers in Frameworks and Host/Guest Chemistry2014

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      The 41st International Conference on Coordination Chemistry (ICCC-41)
    • Place of Presentation
      Singapore
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional MOF: 電子・スピン・構造・化学反応を協奏制御する2014

    • Author(s)
      宮坂 等
    • Organizer
      首都大学東京 化学セミナー
    • Place of Presentation
      首都大学東京
    • Year and Date
      2014-07-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional MOFs: Design by Tuning of Charge Transfers on Frameworks Using D/A Combinations and Host/Guest Chemistry2014

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      The 14th International Conference on Molecule-Based Magnets (ICMM2014)
    • Place of Presentation
      Saint Petersburg (Russia)
    • Year and Date
      2014-07-05 – 2014-07-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional MOFs: How can we obtain electric responses from specific gas adsorption behavior?2014

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      第3回日本ーカナダ錯体化学二国間会議
    • Place of Presentation
      Whistler, Vancouver (Canada)
    • Year and Date
      2014-05-31 – 2014-06-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional MOFs: Rational Tuning of Spin State for the Design of Molecular Magnetic Materials2014

    • Author(s)
      Hitoshi MIyasaka
    • Organizer
      5th Workshop on “Current Trends in Molecular and Nanoscale Magnetism”
    • Place of Presentation
      Larnaca (Cyprus)
    • Year and Date
      2014-05-26 – 2014-05-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional MOFs: Design by Tuning of Charge Transfers on Frameworks Using D/A Combinations and Host/Guest Chemistry2014

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      International Symposium on Coordination Programming 2014 (ISCP2014)
    • Place of Presentation
      東京大学 伊藤国際学術研究センター
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Functional MOFs:電子・スピン・化学反応を制御する2014

    • Author(s)
      宮坂 等
    • Organizer
      第1回東北大学リーディング大学院(物質)研究会「金属錯体の固体物性最前線―金属錯体と固体物性物理と生物物性の連携新領域をめざして-」
    • Place of Presentation
      仙台、東北大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Functional MOFs:電子・スピン・化学反応を制御する2014

    • Author(s)
      宮坂 等
    • Organizer
      分子研研究会「金属クラスター錯体・高分子状金属錯体を舞台とした構造・機能化学の最前線」
    • Place of Presentation
      分子研・岡崎
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 錯体格子上での電荷マニピュレーション2013

    • Author(s)
      宮坂 等
    • Organizer
      第30回無機分析コロキウム
    • Place of Presentation
      宮城、川渡温泉セミナーハウス
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Manipulation of Charge in Coordination Lattices2013

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      NIMS Conference2013
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 状態スイッチ・相転移の精密制御に立脚した電子・スピン協奏現象の開拓2013

    • Author(s)
      宮坂 等
    • Organizer
      新学術領域研究会「配位シナジー:柔軟な構造と電子状態による機能統合」
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Manipulationof Charge in Coordination Frameworks: Discovery of a Novel Charge Ordered State with D0.75+2A1.5- by a Rational Tune of Donor/Acceptor Characters2013

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      第2回日本ーカナダ錯体化学二国間会議
    • Place of Presentation
      沖縄
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Manipulation of Charge in Coordination Frameworks: Control of N-I Phase Transitions by Chemical Doping and Applying Pressure2013

    • Author(s)
      Hitoshi Miyasaka
    • Organizer
      4th Asian Conference on Coordination Chemistry (ACCC4)
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 錯体格子上での電荷制御―分子固体物性科学へのアプローチ2013

    • Author(s)
      宮坂 等
    • Organizer
      平成25年度金研テクニカルセンター研修講演会
    • Place of Presentation
      東北大金研
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 錯体格子上での電荷制御―金研で分子固体物性に挑戦する2013

    • Author(s)
      宮坂 等
    • Organizer
      第126回東北大学金属材料研究所講演会
    • Place of Presentation
      東北大金研
    • Related Report
      2013 Research-status Report
    • Invited
  • [Book] CSJカレントレビュー16 スピン化学が拓く分子磁性の新展開: 設計から機能化まで(日本化学会編集)2014

    • Author(s)
      宮坂 等
    • Total Pages
      7
    • Publisher
      化学同人
    • Related Report
      2014 Annual Research Report
  • [Remarks] 宮坂研HP

    • URL

      http://www.miyasaka-lab.imr.tohoku.ac.jp/

    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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