| Project/Area Number |
25620043
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
HORIKE Satoshi 京都大学, 工学(系)研究科(研究院), 助教 (70552652)
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| Co-Investigator(Kenkyū-buntansha) |
FOO Maw Lin 東京大学, 大学院理学研究科, 特任助教 (20646765)
犬飼 宗弘 徳島大学, 大学院ソシオテクノサイエンス研究部, 講師 (60537124)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 錯体化学 / イオン伝導体 / 配位高分子 / イオン伝導 / イオン液体 / 能動輸送 |
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| Outline of Final Research Achievements |
We synthesized coordination polymers constructed from metal ions and bridging ligands for solid state ion conductors. Targeted mechanism of ion conductivity is uni-directional ion transport. A coordination polymer from Zn2+ ion showed highly anisotropic proton transport checked by impedance spectroscopy. The conductivity is above 10(-3) S/cm which is on the criteria of application. Doping of Co2+ion into the Zn2+ framework was successful and we were able to control domain structure of Zn2+/Co2+ parts in a single crystal. This would enable to have uni-directional ion transportation.
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