| Project/Area Number |
25620048
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
ITAZAKI Masumi 大阪市立大学, 大学院理学研究科, 講師 (60382032)
KAMEO Hajime 大阪府立大学, 大学院理学系研究科, 助教 (50597218)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | 脱水素反応 / 鉄錯体触媒 / 水素分子生成 / 移動水素化反応 / 二官能性触媒 / 鉄錯体 / ２－プロパノール |
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| Outline of Final Research Achievements |
Hydrogen molecule has attracted considerable attention as a clean energy source. Hydrogen transfer reaction in which hydrogen gas produced by the conversion of alcohol to ketone or aldehyde has been widely investigated. In contrast, it is known to be difficult to get hydrogen gas produced in a hydrogen transfer reaction. In this project, we succeeded in the conversion of 2-pyridylalcohol derivatives to the corresponding ketone or aldehyde. As the reaction takes place without sacrificing the hydrogen acceptors, molecular hydrogen gas can be obtained. The highest turnover number achieved was 67,000 which is the world record in the reactions catalyzed by an iron complex.
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