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Investigation on novel chemical reaction induced at single molecular junction

Research Project

Project/Area Number 25620055
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

KIGUCHI Manabu  東京工業大学, 理工学研究科, 教授 (70313020)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords単分子接合 / 光化学反応 / 金属ナノ構造体 / 単分子化学 / 光増強場
Outline of Final Research Achievements

In this study, we have got some results about photoreaction in metal nanogap. We shine the light to the Platinum nano junction in the presence of cis-1,2-DCE molecule, we observed conductance state whose conductance is 1 Go (=2e^2^/h). As we performed inelastic electron tunneling spectroscopy (IETS), we observed vibration mode which did not observed without molecule. From the conductance and IETS measurements, we conclude that we succeed in the observation of the reaction which induced at Platinum nano junction.We also investigate the photoreaction induced at the nanogap using gold nano particle.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (24 results)

All 2015 2014 2013

All Journal Article (17 results) (of which Peer Reviewed: 17 results,  Acknowledgement Compliant: 7 results) Presentation (7 results) (of which Invited: 6 results)

  • [Journal Article] Photochromic reaction of the diarylethene derivative on Au nanoparticles2015

    • Author(s)
      R. Takahashi, S. Kaneko, S. Fujii and M. Kiguchi
    • Journal Title

      Adv. Nat. Sci.: Nanosci. Nanotechnol

      Volume: 6 Issue: 1 Pages: 015006-015006

    • DOI

      10.1088/2043-6262/6/1/015006

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Simultaneous Measurement of Electrical Conductance and Thermopower of Single Benzenedithiol Molecular Junctions2015

    • Author(s)
      S. Kaneko, Y. Nakamura, R. Matsushita, S. Marques-Gonzalez, M. Kiguchi
    • Journal Title

      Appl. Phys. Exp.

      Volume: 印刷中

    • NAID

      210000137560

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Highly conductive single naphthalene and anthracene molecular junction with well-defined conductance2015

    • Author(s)
      C. Liu, S. Kaneko, Y. Komoto, S. Fujii, and M. Kiguchi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 106 Issue: 10 Pages: 103103-103103

    • DOI

      10.1063/1.4914501

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface enhanced Raman scattering of a single molecular junction2015

    • Author(s)
      R. Matsushita, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 印刷中 Issue: 33 Pages: 21363-21371

    • DOI

      10.1039/c4cp04906c

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of Single Cu Atomic Chain in Nitrogen Atmosphere2015

    • Author(s)
      S. Kaneko, Y. Nakamura, M. Kiguchi, J. Zhang, X. Yang, J. Zhao
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 1 Pages: 862-866

    • DOI

      10.1021/jp510916h

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Temperature dependence of the thermopower and its variation of the Au atomic contact2015

    • Author(s)
      Ryuji Matsushita, Satoshi Kaneko, Shintaro Fujii, Hisao Nakamura, Manabu Kiguchi
    • Journal Title

      Nanotechnology

      Volume: 26 Issue: 4 Pages: 045709-045709

    • DOI

      10.1088/0957-4484/26/4/045709

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extension of photopolymerization region from the nanoscale to the macroscopic scale using a chemically amplified photoresist2014

    • Author(s)
      R. Takahashi, S. Kaneko, S. Fujii, M. Kiguchi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 印刷中 Issue: 2 Pages: 277-282

    • DOI

      10.1246/bcsj.20140243

    • NAID

      130004703939

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Single Linear Aromatic Molecule Junction with High Formation Probability2014

    • Author(s)
      C. Liu, S. Kaneko, Y. Komoto, S. Fujii, M. Kiguchi
    • Journal Title

      Appl. Phys. Exp

      Volume: 7 Issue: 10 Pages: 105201-105201

    • DOI

      10.7567/apex.7.105201

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Highly stable Au atomic contacts covered with benzenedithiol in ambient condition2014

    • Author(s)
      D. Murai, T. Nakazumi, S. Fujii, Y. Komoto, K. Tsukagoshi, C. Motta, M. Kiguchi
    • Journal Title

      PCCP

      Volume: 16 Issue: 29 Pages: 15662-15666

    • DOI

      10.1039/c4cp01950d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Metal atomic contacts under defined environmental conditions2014

    • Author(s)
      T. Nakazumi, D. Murai, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      Trans. Mat. Res. Soc. Jpn.

      Volume: 39 Pages: 225-229

    • NAID

      130005004331

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single molecular resistive switch obtained via sliding multiple anchoring points and varying effective wire length2014

    • Author(s)
      M. Kiguchi, T. Ohto, S. Fujii, K. Sugiyasu, S. Nakajima, M. Takeuchi, and H. Nakamura
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 20 Pages: 7327-7332

    • DOI

      10.1021/ja413104g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal atomic contacts under defined environmental conditions2014

    • Author(s)
      T. Nakazumi, S. Kaneko, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 14 Pages: 7489-7493

    • DOI

      10.1021/jp5012318

    • NAID

      130005004331

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Additive Electron Pathway and Non-additive Molecular Conductance by Using a Multipodal Bridging Compound2014

    • Author(s)
      M. Kiguchi, Y. Takahashi, S. Fujii, M. Takase, T. Narita, M. Iyoda, M. Horikawa, Y. Naitoh, H. Nakamura
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 10 Pages: 5275-5283

    • DOI

      10.1021/jp4100262

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Investigation on the Pyrazine Molecular Junction Studied by Conductance Measurement and Near Edge X-ray Absorption Fine Structure2013

    • Author(s)
      Satoshi Kaneko, Manabu Kiguchi
    • Journal Title

      Fullerenes, Nanotubes and Carbon Nanostructures

      Volume: 22 Issue: 1-3 Pages: 166-172

    • DOI

      10.1080/1536383x.2013.798723

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Single Molecular Bridging of Au Nanogap using Aryl Halide Molecules2013

    • Author(s)
      Yuki Komoto, Shintaro Fujii, Kenji Hara, Manabu Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 117 Issue: 46 Pages: 24277-24282

    • DOI

      10.1021/jp404858x

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Highly Conductive [3×n] Gold-Ion Clusters Enclosed within Self-Assembled Cages2013

    • Author(s)
      Kiguchi, M ; Inatomi, J ; Takahashi, Y ; Tanaka, R ; Osuga, T ; Murase, T ; Fujita, M ; Tada, T ; Watanabe S.
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 52 Issue: 24 Pages: 6202-6205

    • DOI

      10.1002/anie.201301665

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Conductance and SERS Measurement of Benzenedithiol Molecules Bridging Between Au Electrodes2013

    • Author(s)
      R. Matsushita, M. Horikawa, Y. Naitoh, H. Nakamura, M. Kiguchi
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 117 Issue: 4 Pages: 1791-1795

    • DOI

      10.1021/jp3112638

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Investigation on nano scale molecular dynamics using enhanced field at the metal nano gap2014

    • Author(s)
      M. Kiguchi
    • Organizer
      The 7th International Workshop on Advanced Materials Science, Halong
    • Place of Presentation
      Halong (Vietnam)
    • Year and Date
      2014-11-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 機能性分子を用いた単分子素子開発2014

    • Author(s)
      木口学
    • Organizer
      第1回資源研フォーラム
    • Place of Presentation
      東京
    • Year and Date
      2014-10-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Single Molecular Dynamics Using the Surface Enhanced Raman Scattering2014

    • Author(s)
      M. Kiguchi
    • Organizer
      van der Waals colloquium
    • Place of Presentation
      Leiden (Netherlands)
    • Year and Date
      2014-09-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Single Molecular Resistive Switch Showing Three Distinct Conductance States2014

    • Author(s)
      5.M. Kiguchi, S. Fujii, S.Nakajima, T. Ohto, H. Nakamura, K. Sugiyasu, M. Takeuchi
    • Organizer
      ECOSS30
    • Place of Presentation
      Antalya (Turkey)
    • Year and Date
      2014-09-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] 単一分子接合の化学2013

    • Author(s)
      木口学
    • Organizer
      分子科学会
    • Place of Presentation
      京都
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 振動分光による電極間の架橋した単分子のダイナミクスの研究2013

    • Author(s)
      木口学
    • Organizer
      日本表面科学会第76回表面科学研究会
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 単分子計測を利用した電子輸送過程の解明2013

    • Author(s)
      木口学
    • Organizer
      第3回CSJ化学フェスタ2013
    • Place of Presentation
      東京
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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