| Project/Area Number |
25620057
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Functional solid state chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
KUBO TAKASHI 大阪大学, 理学(系)研究科(研究院), 教授 (60324745)
|
|---|
| Project Period (FY) |
2013-04-01 – 2015-03-31
|
| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
|
|---|
| Keywords | OPV / biradicaloid / singlet biradical / singlet fission / シングレットフィッション / 一重項ビラジカル / ビラジカロイド / 太陽電池 / ビスアンテン / 三重項励起子 |
|---|
| Outline of Final Research Achievements |
This study aims for developing highly-efficient OPV organic materials based on biradicaloid molecules, by exploiting singlet fission (SF) phenomenon that produces two triplet excitons from one photon. In this study, we succeeded in the development of efficient synthesis of a biradicaloid, Bisanthene. Furthermore, the transient absorption measurement of a bisanthene film formed on a substrate revealed that the triplet species are generated by the SF mechanism. In the evaluation of the solar cell, a p-n junction was prepared by Bisanthene and fullerene and its solar cell performance was investigated. Solar cell characteristics: short-circuit current 1 mA / cm2, the open-circuit voltage 0.34 V, FF 0.48, and conversion efficiency 0.16%: showed a good performance.
|
