Thermoelectric properties of organic/inorganic hybrid nano-junctions
Project/Area Number |
25620058
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Functional solid state chemistry
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Research Institution | Osaka University |
Principal Investigator |
Yamada Ryo 大阪大学, 基礎工学研究科, 准教授 (20343741)
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Project Period (FY) |
2013-04-01 – 2016-03-31
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Project Status |
Completed (Fiscal Year 2015)
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Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | 熱電変換 / 単分子接合 / 走査型プローブ顕微鏡 / 熱起電力 / STMブレイクジャンクション / 熱電 / ゼーベック係数 / 走査型トンネル顕微鏡 |
Outline of Final Research Achievements |
This study aimed at understanding mechanisms of thermoelectricity in metal/single molecule/metal junctions. For this purpose, a device to measure Seebeck coefficient (S) was developed. Measurements on various molecular junctions revealed useful principles to control the sign of S such as using spin-splitting of molecular orbitals induced by coupling with ferromagnetic electrodes and heteroconjugation anchors. The largest power factor was found in metal-encapsulated C82 in which energy levels of conducting molecular orbital is altered by metal ions inside.
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Report
(4 results)
Research Products
(69 results)
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[Presentation] Effect of metal work function on large-area molecular junctions with single-layer graphene top contacts2015
Author(s)
Mariko Yamaguchi, Takashi Ikuta, Yasushi Kanai, Tatsuhiko Ohto, Ryo Yamada, Yasuhide Ohno, Kenzo Maehashi, Kazuhiko Matsumoto, Hirokazu Tada
Organizer
Pacifichem 2015
Place of Presentation
Honolulu, HW, USA
Year and Date
2015-12-15
Related Report
Int'l Joint Research
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[Presentation] Synthesis and measurements of molecules bearing nonsymmetric single-molecule electric properties2015
Author(s)
Takuji Ogawa, Murni Handayani, Zhijin Chen, Naoya Sakata, Shunri Lee, Fumiya Miyamoto, Tomoko Inose, Ryo Yamada, Hirokazu Tada, Hirofumi Tanaka
Organizer
Pacifichem 2015
Place of Presentation
Honolulu, HW, USA
Year and Date
2015-12-15
Related Report
Int'l Joint Research
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[Presentation] 三脚アンカー分子による単分子接合の伝導キャリア制御2015
Author(s)
Lee See Kei, 家 裕隆, 田中一成, 田代彩, Testai, Henrique Rosa, 山田 亮, 安蘇 芳雄, 夛田 博一
Organizer
表面・界面スペクトロスコピー2015
Place of Presentation
国立女性教育会館,(埼玉県・比企郡嵐山町)
Year and Date
2015-11-27
Related Report
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[Presentation] 三脚型アンカーを用いた単分子接合の熱起電力測定2015
Author(s)
Lee See Kei, Henrique R. Testai, 田中 一成, 田代 彩,家 裕隆, 安蘇芳雄, 山田 亮, 夛田博一
Organizer
第9回領域横断研究会
Place of Presentation
東京大学 理学部本館講堂および小柴ホール(東京都文京区)
Year and Date
2015-11-13
Related Report
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[Presentation] Thermoelectric Voltage Measurements of Pyridine and Thiophene-based Tripodal Anchor Molecular Junctions2015
Author(s)
Henrique R. Testai, See Kei Lee, Yutaka Ie, Kazunari Tanaka, Aya Tashiro, Yoshio Aso, Ryo Yamada, and Hirokazu Tada
Organizer
2nd Japan-Korea Joint Seminar
Place of Presentation
Osaka University, Toyonaka, Osaka, Japan
Year and Date
2015-07-10
Related Report
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[Presentation] 単一分子のキャリア輸送特性の計測2015
Author(s)
Lee See Kei, 田中彰治, 大戸達彦, 山田亮, 夛田博一
Organizer
第18回理論化学討論会
Place of Presentation
大阪大学豊中キャンパス(大阪府・豊中市)
Year and Date
2015-05-20
Related Report
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