| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
|---|
| Outline of Final Research Achievements |
A series of metal-organic molecule-based magnets which included organic molecule as reactants were synthesized, and their crystal structures and magnetic properties were studied. Hydrothermal synthesis of DL-or D,L-AP with Co(II) gave 1D chain structures which magnetic interactions were paramagnetic down to 1.8 K. On the other hand, DL-or L-Glu gave 3D network which showed antiferromagnetic behaviors.
Perovskite structures were proposed as ferromagnetic host molecules. Four new copper(II) complexes were prepared by the reaction of substituted anilinium salts and CuCl2. Magnetic measurement of these complexes showed that three were ferromagnet with the TC= 8 K and one was weakferromagnet with the TN= 9 K.
|
