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Development of Unexplored Liquid Chemistry Based on Metal-Ligand Complexes

Research Project

Project/Area Number 25620069
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

NAKANISHI Takashi  独立行政法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 独立研究者 (40391221)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords液体材料 / 金属錯体 / 白色発光 / エレクトロクロミズム / スピン活性 / 液体 / フタロシアニン / ポルフィリン / エレクトロクロミック / 磁性 / 自己組織化 / 常温液体 / 発光材料 / 磁性材料
Outline of Final Research Achievements

The attachment of low viscosity, bulky but flexible alkyl side chains onto a functional metal-ligand complex core unit leads to a production of novel nonvolatile metal complex liquid materials at room temperature. The employed metal-ligand complexes are single molecular white luminescent Ir complex and spin-active, electrochromic double-decker lutetium phthalocyanine. Both cases the intrinsic molecular function can be transferred into the produced bulk liquid materials.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (43 results)

All 2015 2014 2013 Other

All Journal Article (10 results) (of which Peer Reviewed: 8 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (29 results) (of which Invited: 17 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Alkyl-π engineering in state control toward versatile optoelectronic soft materials2015

    • Author(s)
      Fengniu Lu, Takashi Nakanishi
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 16 Issue: 1 Pages: 014805-014805

    • DOI

      10.1088/1468-6996/16/1/014805

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Directed Assembly of Optoelectronically Active Alkyl-π-Conjugated Molecules by Adding n-alkanes or π-Conjugated Species2014

    • Author(s)
      M. J. Hollamby, M. Karny, P. H. H. Bomans, N. A. J. M. Sommerdjik, A. Saeki, S. Seki, H. Minamikawa, I. Grillo, B. R. Pauw, P. Brown, J. Eastoe, H. Möhwald, and T. Nakanishi
    • Journal Title

      Nature Chem.

      Volume: 6 Issue: 8 Pages: 690-696

    • DOI

      10.1038/nchem.1977

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fullerene assemblies toward photo-energy conversions2014

    • Author(s)
      Yanfei Shen、Takashi Nakanishi
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 16巻 Issue: 16 Pages: 7199-7204

    • DOI

      10.1039/c4cp00221k

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room Temperature Liquid Formulation by Attaching Alkyl Chains on π-Conjugated Molecules2014

    • Author(s)
      Takashi Nakanishi
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 72 Issue: 11 Pages: 1265-1270

    • DOI

      10.5059/yukigoseikyokaishi.72.1265

    • NAID

      130004749124

    • ISSN
      0037-9980, 1883-6526
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 新奇な常温液状有機材料の開発2014

    • Author(s)
      中西尚志
    • Journal Title

      科学と工業

      Volume: 88 Pages: 376-383

    • NAID

      40020233844

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Order from Disorder: π系-アルキル「液体」分子を基材に自己組織化2014

    • Author(s)
      中西尚志
    • Journal Title

      新学術領域研究「柔らかな分子系」ニュースレター

      Volume: (12) Pages: 54-54

    • Related Report
      2014 Annual Research Report
    • Open Access
  • [Journal Article] Controlled self-assembly of alkylated-πcompounds for soft materials–Towards optical and optoelectronic applications2014

    • Author(s)
      Agnieszka Zielinska、Marcin Leonowicz、Hongguang Li、Takashi Nakanishi
    • Journal Title

      Current Opinion in Colloids & Interface Science

      Volume: 19巻 Issue: 2 Pages: 131-139

    • DOI

      10.1016/j.cocis.2014.03.007

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] The power of branched chains : optimizing functional molecular materials2013

    • Author(s)
      Martin J. Hollamby、Takashi Nakanishi
    • Journal Title

      J. Mater. Chem. C

      Volume: 1巻 Issue: 39 Pages: 6178-6183

    • DOI

      10.1039/c3tc31381f

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nonvolatile functional molecular liquids2013

    • Author(s)
      Sukumaran Santhosh Babu、Takashi Nakanishi
    • Journal Title

      Chem. Commun

      Volume: 49巻 Issue: 82 Pages: 9373-9382

    • DOI

      10.1039/c3cc45192e

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] アルキル鎖によって誘導されるπ共役系有機ソフト材料の開発2013

    • Author(s)
      中西尚志
    • Journal Title

      表面

      Volume: 51 Pages: 378-379

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] π-Conjugated Molecule Based Room Temperature Liquid Materials2015

    • Author(s)
      Takashi Nakanishi
    • Organizer
      MANA International Symposium 2015
    • Place of Presentation
      EPOCHAL TSUKUBA (Tsukuba, Ibaraki)
    • Year and Date
      2015-03-11 – 2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Controlling Self-assembly of Spin-active Molecules towards Multifunctional Soft-materials2015

    • Author(s)
      ZIELINSKA Agnieszka、Mercin Leonowicz、中西尚志
    • Organizer
      MANA International Symposium 2015
    • Place of Presentation
      EPOCHAL TSUKUBA (Tsukuba, Ibaraki)
    • Year and Date
      2015-03-11 – 2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] π共役分子の常温液体化:発光機能と自己組織化制御2015

    • Author(s)
      中西尚志
    • Organizer
      光材料講演会
    • Place of Presentation
      横浜国立大学化学棟711講義室(横浜市保土ヶ谷区常盤台)
    • Year and Date
      2015-03-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] アルキル化π共役分子「液体」の化学2015

    • Author(s)
      中西尚志
    • Organizer
      学習院大学理学部セミナー
    • Place of Presentation
      学習院大学南7号館セミナー室7(東京都豊島区目白)
    • Year and Date
      2015-01-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 精密分子設計による光応答を指向した超分子材料の開拓2014

    • Author(s)
      中西尚志
    • Organizer
      柔らかな分子系 第2回公開シンポジウム
    • Place of Presentation
      大阪大学会館(大阪府豊中市)
    • Year and Date
      2014-11-28 – 2014-11-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Room Temperature Functional Organic Liquids2014

    • Author(s)
      Takashi Nakanishi
    • Organizer
      第11回JGFoSシンポジウム
    • Place of Presentation
      Bremen (Germany)
    • Year and Date
      2014-10-31 – 2014-11-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] 次世代ソフトマテリアル:機能性「液体」の設計指針2014

    • Author(s)
      中西尚志
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船堀(東京都江戸川区船堀)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 機能性有機液体の自己組織化2014

    • Author(s)
      中西尚志
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス(長崎市文教町)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Novel directed assembly technique toward soft materials based optoelectronic applications2014

    • Author(s)
      Takashi Nakanishi
    • Organizer
      5th WUT-NIMS-HHT Joint Seminar
    • Place of Presentation
      Warsaw (Poland)
    • Year and Date
      2014-09-18 – 2014-09-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Ultimate-soft π-Molecular Liquid Materials2014

    • Author(s)
      Takashi Nakanishi
    • Organizer
      2nd V4-JST Workshop on Advanced Materials
    • Place of Presentation
      Warsaw (Poland)
    • Year and Date
      2014-09-17 – 2014-09-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Multifunctional Soft-materials Based on Controlled Self-assembly of Spin-active Molecules2014

    • Author(s)
      ZIELINSKA Agnieszka、Mercin Leonowicz、中西尚志
    • Organizer
      EMRS 2014
    • Place of Presentation
      Warsaw (Poland)
    • Year and Date
      2014-09-15 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] アルキル-π型両親媒性液状分子からの分子集合体形成2014

    • Author(s)
      中西尚志、Martin James Hollamby
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学神楽坂校舎(東京都新宿区神楽坂)
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Self-Assemblies of Alkylated Fullerenes toward Photo-energy Conversions2014

    • Author(s)
      Takashi Nakanishi
    • Organizer
      The 15th IUMRS-International Conference in Asia
    • Place of Presentation
      Fukuoka University,Fukuoka
    • Year and Date
      2014-08-25 – 2014-08-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Functional Organic Liquid Materials2014

    • Author(s)
      Takashi Nakanishi
    • Organizer
      Samsung Advanced Institute of Technology Seminar
    • Place of Presentation
      Seoul (Korea)
    • Year and Date
      2014-08-20 – 2014-08-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] An Exotic Liquid Matter: Functional Organic Liquids2014

    • Author(s)
      Takashi Nakanishi, Ken Okamoto
    • Organizer
      MASA 2014
    • Place of Presentation
      WPI-MANA Auditorium,Tsukuba, Ibaraki
    • Year and Date
      2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Alkyl-π Liquid Systems: Uncommon But Attractive Organic Soft Materials2014

    • Author(s)
      Takashi Nakanishi
    • Organizer
      Frontier Molecular Science Forum
    • Place of Presentation
      Institute for Molecular Science, Okazaki, Aichi
    • Year and Date
      2014-07-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Self-assembly Control of Spin-active Molecules Towards Soft-materials2014

    • Author(s)
      ZIELINSKA Agnieszka、Marcin Leonowicz、中西尚志
    • Organizer
      NIMS Conference 2014
    • Place of Presentation
      Tsukuba International Conference Center,Tsukuba, Ibaraki
    • Year and Date
      2014-07-01 – 2014-07-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] 分子材料創製:自己組織化および非組織化戦略2014

    • Author(s)
      中西尚志
    • Organizer
      理研セミナー
    • Place of Presentation
      理研フロンティア中央研究棟3階会議室(埼玉県和光市)
    • Year and Date
      2014-06-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Functional Macromolecular Liquids as A NewType of Liquid Matter2014

    • Author(s)
      Takashi Nakanishi
    • Organizer
      6th Internationak Symposium on Polymer Chemistry (PC2014)
    • Place of Presentation
      SHANGHAI (CHINA)
    • Year and Date
      2014-06-04 – 2014-06-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 精密分子設計による光応答を指向した超分子材料の開拓2014

    • Author(s)
      中西尚志
    • Organizer
      新学術領域「柔らかな分子系」第3回全体合宿会議
    • Place of Presentation
      八ヶ岳ロイヤルホテル(山梨県北杜市)
    • Year and Date
      2014-06-03 – 2014-06-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] π共役分子常温液体2014

    • Author(s)
      中西尚志
    • Organizer
      日本化学会第94回春季年会
    • Place of Presentation
      名古屋大学東山キャンパス、名古屋
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 光・電子機能性分子材料の自己組織化メカニズムと応用展開2013

    • Author(s)
      中西尚志
    • Organizer
      サイエンス&テクノロジー技術セミナー
    • Place of Presentation
      大田区産業プラザ(PiO)、東京都
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Just Kicked-off Room Temperature Functional Liquid Chemistry2013

    • Author(s)
      Takashi Nakanishi
    • Organizer
      Norway-NIMS Workshop on Advanced Materials and Nanotechnology
    • Place of Presentation
      MANA-WPI Bildg. Tsukuba, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Nonvolatile, Room Temperature Functional Organic Liquids2013

    • Author(s)
      Takashi Nakanishi
    • Organizer
      WUT-NIMS-HHT 4th Joint Seminar
    • Place of Presentation
      Epocal Tsukuba, Tsukuba, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 分子材料創製に向けた自己組織化 vs. 非組織化2013

    • Author(s)
      中西尚志
    • Organizer
      第2回エキゾチック自己組織化材料シンポジウム
    • Place of Presentation
      名古屋大学ベンチャービジネスラボラトリ、名古屋
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 自己組織化制御に基づく巨視的分子材料:モスアイ様構造体および発光性液体2013

    • Author(s)
      中西尚志
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学角間キャンパス、金沢市角間町
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 未踏機能性分子“液体”の探索 -自己組織化から非組織化へのパラダイムシフト2013

    • Author(s)
      中西尚志
    • Organizer
      新化学技術推進協会 先端化学・材料技術部会新素材分科会講演会
    • Place of Presentation
      新化学技術推進協会、東京都千代田区
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 非組織化機能性材料2013

    • Author(s)
      中西尚志
    • Organizer
      第23回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館、横浜
    • Related Report
      2013 Research-status Report
  • [Presentation] Functional Organic Molecular Liquids2013

    • Author(s)
      Takashi Nakanishi
    • Organizer
      CEMS International Symposium on Supramolecular Chemistry and Functions
    • Place of Presentation
      Takeda Hall, The University of Tokyo, Japan
    • Related Report
      2013 Research-status Report
  • [Book] Fullerenes and Other Carbon-Rich Nanostructures2014

    • Author(s)
      Yanfei Shen, Takashi Nakanishi, Yuming Zhao, Guang Chen, Anna Troeger, Vito Sgobba, Dirk M. Guldi, Delphine Felder-Flesch, Andrés de la Escosura, Olga Trukhina, Tomás Torres, Riccardo Marega, Davide Giust, Davide Bonifazi, Stephanie Frankenberger, Johanna A. Januszewski, Rik R. Tykwinski
    • Total Pages
      257
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report
  • [Book] フラーレン誘導体・内包技術の最前線2014

    • Author(s)
      松尾豊(監修)、大澤映二、大町遼、篠原久典、金鉄男、山本嘉則、小久保研、武田洋平、南方聖司、内山幸也、五十嵐望紀、森山広思、田島右副、前田優、赤坂健、岡田洋史、河地和彦、笠間泰彦、上野裕、中西尚志、他
    • Total Pages
      247
    • Publisher
      シーエムシー出版
    • Related Report
      2014 Annual Research Report
  • [Remarks] 物質・材料研究機構 中西チームHP

    • URL

      http://www.nims.go.jp/macromol/nakanishi/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 中西チームHP

    • URL

      http://www.nims.go.jp/macromol/nakanishi/index.html

    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

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