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Search for superconducting phase in electronic ferroelectric iron oxides

Research Project

Project/Area Number 25620071
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

Yoshii Kenji  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究主幹 (90354985)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI Tatsuo  岡山大学, 自然科学研究科, 教授 (80205468)
YONEDA Yasuhiro  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究主幹 (30343924)
SAITOH Hiroyuki  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究主幹 (20373243)
FUKUDA Tatsuo  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究副主幹 (80354984)
MATSUMURA Daiju  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 量子ビーム応用研究センター, 研究副主幹 (30425566)
Co-Investigator(Renkei-kenkyūsha) IKEDA Naoshi  岡山大学, 自然科学研究科, 教授 (00222894)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsマルチフェロイック / 電子強誘電体 / 量子揺らぎ / 超伝導 / 三角格子 / Resonating Valence Bond
Outline of Final Research Achievements

We have searched for a superconducting phase in electronic ferroelectric multiferroic RFe2O4 (R: rare earths). Electrical resistivity measurements were performed under high pressures up to 4 GPa to increase the interactions between the Fe ions inside the Fe-O plane. Although the pressure was raised up to 4 GPa, the system remained semiconducting. However, a slight change was observed for YFe2O4 around 1-2 GPa; the activation energy was slightly decreased at higher pressures. Also, the elemental substitution at R site was attempted. We found that the magnetic transition temperature (250 K) was increased by 5-10 K by the substitution of the large R3+ ion (Dy3+). This result is interesting from the viewpoint of a search for room temperature multiferroic materials.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (16 results)

All 2015 2014

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (10 results) (of which Invited: 3 results)

  • [Journal Article] Elemental Substitution effects in Multiferroic RFe2O4 (R: rare earths)2015

    • Author(s)
      Kenji Yoshii, Takashi Funae, Masaichiro Mizumaki, Hiroki Ejiri, Naoshi Ikeda, Hiroyuki Saitoh, Daiju Matsumura
    • Journal Title

      Phys. Stat. Sol. (c)

      Volume: 12 Issue: 6 Pages: 841-844

    • DOI

      10.1002/pssc.201400250

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Structure of BaFeO3 studied by X-ray Spectroscopy2015

    • Author(s)
      Masaichiro Mizumaki, Hiroshi Fujii, Kenji Yoshii, Naoaki Hayashi, Takashi Saito, Yuichi Shimakawa, Takayuki Uozumi, Mikio Takano
    • Journal Title

      Phys. Stat. Sol. (c)

      Volume: 12 Issue: 6 Pages: 818-821

    • DOI

      10.1002/pssc.201400252

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel electrothermodynamic power generation2015

    • Author(s)
      Kim, Y.a , Kim, J.a, Yamanaka, S.a, Nakajima, A.a, Ogawa, T.a, Serizawa, T.a, Tanaka, H.a , Baba, M.b, Fukuda, T.c, Yoshii, K.c, Takeda, M.b, Yamada, N.b, Nakayama, T.b, Niihara, K.b a
    • Journal Title

      Advanced Energy Materials

      Volume: n Issue: 13 Pages: 1401942-1401942

    • DOI

      10.1002/aenm.201401942

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Elemental substitution effects in multiferroic RFe2O4 (R: rare earths)2015

    • Author(s)
      Kenji Yoshii, Takashi Funae, Masaichiro Mizumaki, Hiroki Ejiri, Naoshi Ikeda, Hiroyuki Saitoh, Daiju Matsumura
    • Journal Title

      Phys.Stat.Sol.(c)

      Volume: 印刷中

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of BaFeO3 studied by X‐ray spectroscopy2015

    • Author(s)
      Masaichiro Mizumaki, Hitoshi Fujii, Kenji Yoshii, Naoaki Hayashi, Takashi Saito, Yuichi Shimakawa, Takayuki Uozumi, Mikio Takano
    • Journal Title

      Phys.Stat.Sol.(c)

      Volume: 印刷中

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Current-Induced Enhancement of Magnetic Anisotropy in Spin-Charge-Coupled Multiferroic YbFe2O42014

    • Author(s)
      Kenji Yoshii, Daiju Matsumura, Hiroyuki Saitoh, Takashi Kambe, Mamoru Fukunaga, Yuji Muraoka, Naoshi Ikeda, Shigeo Mori
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 83

    • NAID

      210000133125

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] パイロクロア型ニオブ酸化物におけるNb四面体の電荷クラスター状態の探索2015

    • Author(s)
      鳥越秀平,青石優平,村川寛,松村大樹,吉井賢資,米田安宏,樹神克明,池田一貴,大友季哉, 富安啓輔,中尾裕則,野上由夫,花咲徳亮
    • Organizer
      日本物理学会第70回年会
    • Place of Presentation
      早稲田大学 (東京都 新宿区)
    • Year and Date
      2015-03-23
    • Related Report
      2014 Research-status Report
  • [Presentation] Sr置換したBaFeO3の磁気熱量効果2015

    • Author(s)
      吉井賢資,水牧仁一朗,林直顕,高野幹夫
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学 (東京都 新宿区)
    • Year and Date
      2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] 新規強磁性体BaFeO3の磁気的性質と放射光分光測定2014

    • Author(s)
      吉井賢資,水牧仁一朗,林直顕, 松村大樹, 高野幹夫
    • Organizer
      第55回真空に関する連合講演会
    • Place of Presentation
      大阪府立大学I-siteなんば(大阪市 浪速区)
    • Year and Date
      2014-11-18
    • Related Report
      2014 Research-status Report
  • [Presentation] X-ray absorption study of perovskite cobaltite Pr1-xSrxCoO32014

    • Author(s)
      K. Yoshii, D. Matsumura, T. Fukuda
    • Organizer
      The 7th International Symposium of Surface Science (ISSS-7)
    • Place of Presentation
      くにびきメッセ(島根県 松江市)
    • Year and Date
      2014-11-03
    • Related Report
      2014 Research-status Report
  • [Presentation] Magnetic properties and magnetocaloric effect of field-induced ferromagnet BaFeO32014

    • Author(s)
      K. Yoshii
    • Organizer
      3rd International Conference and Exhibition on Materials Science & Engineering
    • Place of Presentation
      San Antonio, USA
    • Year and Date
      2014-10-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Elemental substitution effects in multiferroic RFe2O4 (R: rare earths)”2014

    • Author(s)
      K. Yoshii, M. Mizumaki, T. Funae, H. Ejiri, N. Ikeda and D. Matsumura
    • Organizer
      19th International Conference on Ternary and Multinary Compounds (ICTMC-19)
    • Place of Presentation
      朱鷺メッセ(新潟市 中央区)
    • Year and Date
      2014-09-03
    • Related Report
      2014 Research-status Report
  • [Presentation] Electronic structure of BaFeO3 studied by X-ray spectroscopy2014

    • Author(s)
      M. Mizumaki, K. Yoshii, N. Hayashi, T. Saito, Y. Shimakawa, T. Uozumi and M. Takano
    • Organizer
      19th International Conference on Ternary and Multinary Compounds (ICTMC-19)
    • Place of Presentation
      朱鷺メッセ(新潟市 中央区)
    • Year and Date
      2014-09-02
    • Related Report
      2014 Research-status Report
  • [Presentation] Magnetic properties and magnetocaloric effect of field-induced ferromagnet BaFeO32014

    • Author(s)
      K. Yoshii, N. Hayashi, M. Mizumaki, D. Matsumura, M. Takano
    • Organizer
      EMN Summer Meeting (Energy Materials Nanotechnology)
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-06-09
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 放射光を利用した表面分析相談2014

    • Author(s)
      吉井賢資、寺岡有殿
    • Organizer
      第56回 表面科学基礎講座「表面・界面分析の基礎と応用」
    • Place of Presentation
      大阪大学 コンベンションセンター(大阪府吹田市)
    • Year and Date
      2014-06-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Magnetic properties and magnetocaloric effect of field-induced ferromagnet BaFeO32014

    • Author(s)
      Kenji Yoshii, Naoaki Hayashi, Masaichiro Mizumaki, Daiju Matsumura, Mikio Takano
    • Organizer
      EMN Summer Meeting (Energy Materials Nanotechnology)
    • Place of Presentation
      カンクン(メキシコ)
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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