Development of Advanced Molecular Transformations by 'Organobase/Chiral Lewis Acid' Concerted Binary Catalytic System
| Project/Area Number |
25620073
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Tohoku University |
|---|
Principal Investigator |
TERADA Masahiro 東北大学, 理学(系)研究科(研究院), 教授 (50217428)
|
|---|
| Project Period (FY) |
2013-04-01 – 2016-03-31
|
| Project Status |
Completed (Fiscal Year 2015)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
|
|---|
| Keywords | 不斉合成 / 触媒 / 有機塩基 / 物質変換 / 環境調和 / 反応場 / 塩基触媒 / 分子認識 |
|---|
| Outline of Final Research Achievements |
The purpose of this study is the development of concerted binary catalytic system which combines activation of reactant by organobase and stereocontrol by chiral Lewis acid. The proposed system is aimed at the design of the chiral art complex to realize highly stereoselective transformations, where two type of catalytic system was investigated. 1) In the development of organobase/chiral metal phosphate salts concerted binary catalytic system, combination of organobase and alkaline earth metal or rare earth metal salts as a central metal species were investigated. 2) In the development of organobase/chiral Schiff base metal salt concerted binary catalytic system, combination of organobase and alkaline metal salts as a central metal species was investigated.
|
Report
(4 results)
Research Products
(9 results)
