| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Outline of Final Research Achievements |
The purpose of this study is the development of concerted binary catalytic system which combines activation of reactant by organobase and stereocontrol by chiral Lewis acid. The proposed system is aimed at the design of the chiral art complex to realize highly stereoselective transformations, where two type of catalytic system was investigated. 1) In the development of organobase/chiral metal phosphate salts concerted binary catalytic system, combination of organobase and alkaline earth metal or rare earth metal salts as a central metal species were investigated. 2) In the development of organobase/chiral Schiff base metal salt concerted binary catalytic system, combination of organobase and alkaline metal salts as a central metal species was investigated.
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