| Project/Area Number |
25620093
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
MORI Hideharu 山形大学, 理工学研究科, 教授 (00262600)
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| Co-Investigator(Kenkyū-buntansha) |
NAKABAYASHI Kazuhiro 山形大学, 大学院理工学研究科, 助教 (30613765)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | 精密ラジカル重合 / コア架橋型微粒子 / 有機半導体 / 架橋反応 / ブロック共重合体 / 自己組織化 / 有機・無機ハイブリッド / 高分子合成 / ナノ材料 |
|---|
| Outline of Final Research Achievements |
Core cross-linked nanoparticles with electron-transporting cores have been developed by the combination of the synthesis of reactive block copolymers by RAFT polymerization, formation of polymeric nanostructures by self-assembly, and situ-selective cross-coupling reactions. We have successfully synthesized donor-acceptor type nanoparticles by Suzuki coupling reaction, perylene and naphthalene bisimide-based nanoparticles by imidization, thermoresponsive nanoparticles with optoelectronic cores by imine formation, and hybrid nanoparticles using silsesquioxane-based chain transfer agent, respectively.
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