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Single-Molecule Imaging of the Matter Transportation along a Polymer Chain

Research Project

Project/Area Number 25620096
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer chemistry
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

SHINOHARA Ken-ichi  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 准教授 (10292244)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords1分子イメージング / 分子モーター / らせん高分子 / 高速AFM / 熱ゆらぎ / 拡散係数 / PIV / 分子動力学 / 高分子モーター
Outline of Final Research Achievements

The fast-scanning atomic force microscope (FS-AFM) for single-molecule imaging to measure the phenomenon that matter was transported along a polymer chain was produced. The method to measure the micro-Brownian motion was developed. The phenomenon that matter (short chain) was transported along one helical chain (long chain) of poly(substituted phenylacetylene) by single-molecule imaging using FS-AFM was observed, and diffusion coefficient were measured.
In addition, the following results were also provided. (1)A temperature control imaging experiment, (2)The molecular dynamics simulation of the matter transportation phenomenon, (3)The understanding of the matter transportation phenomenon by the visualization analysis (PIV) of a solvent flow generated at a long-polymer-chain neighborhood, (4)Control of the matter transportation.
A molecular walk (a molecular motor principle) in an organic solvent was demonstrated. I want to create the non-aqueous solution-based artificial life function.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (22 results)

All 2015 2014 2013 Other

All Journal Article (4 results) Presentation (14 results) (of which Invited: 4 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] PIV Analysis of Solvent Flow around a Macromolecular Chain of a Chiral Helix2014

    • Author(s)
      Ken-ichi Shinohara, Yuu Makida
    • Journal Title

      Polym. Prepr. Jpn.

      Volume: 63 Pages: 2125-2126

    • Related Report
      2014 Annual Research Report
  • [Journal Article] A Short Polymer Chain Walks Processively with the 3-nm Step along a Long Chain of a Synthetic Helical Polymer Driven by a Thermal Fluctuation in a Non-Aqueous Media2014

    • Author(s)
      Ken-ichi Shinohara, Yuu Makida
    • Journal Title

      Polym. Prepr. Jpn.

      Volume: 63 Pages: 5357-5358

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Single-Molecules Imaging of a Dynamic Structure in a Supramolecular Polymer Chain Self-Assembled Pentacene/γ-Cyclodextrin Inclusion Complex2014

    • Author(s)
      Ken-ichi Shinohara, Yuu Makida, Nobuyuki Aoki
    • Journal Title

      Polym. Prepr. Jpn.

      Volume: 63 Pages: 5437-5438

    • Related Report
      2014 Annual Research Report
  • [Journal Article] ここまでできるポリマー1分子のイメージング!2013

    • Author(s)
      篠原 健一
    • Journal Title

      高分子

      Volume: 62 Pages: 673-674

    • Related Report
      2013 Research-status Report
  • [Presentation] Single-Molecule Imaging of a Polymer2015

    • Author(s)
      Ken-ichi Shinohara
    • Organizer
      9th Japanese-French Frontier of Science Symposium (JFFoS), Japan Society for the Promotion of Science (JSPS)
    • Place of Presentation
      Kyoto Brighton Hotel, Kyoto, Japan
    • Year and Date
      2015-01-22 – 2015-01-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ポリマー1分子の直視:高分子鎖一本の構造動態と顕微機能解析2014

    • Author(s)
      篠原 健一
    • Organizer
      株式会社東ソー分析センター 第8回高分子セミナー
    • Place of Presentation
      ヒルトン名古屋, 愛知県名古屋市
    • Year and Date
      2014-12-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Single-Molecule Imaging of a Synthetic Polymer and a Macromolecular Machine2014

    • Author(s)
      Ken-ichi Shinohara
    • Organizer
      Vietnam Malaysia International Chemical Congress (VMICC)
    • Place of Presentation
      Daewoo Hotel Hanoi, Hanoi, Vietnam
    • Year and Date
      2014-11-07 – 2014-11-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] A Short Polymer Chain Walks Processively with the 3-nm Step along a Long Chain of a Synthetic Helical Polymer Driven by a Thermal Fluctuation in a Non-Aqueous Media2014

    • Author(s)
      Ken-ichi Shinohara
    • Organizer
      XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Royton Sapporo, Sapporo, Hokkaido, Japan
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Direct Observation of the Polymer Chain Dynamics Undergoing Main-Chain Cleavage by Single-Molecule Imaging2014

    • Author(s)
      Manjit Singh Grewal, Ken-ichi Shinohara
    • Organizer
      XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Royton Sapporo, Sapporo, Hokkaido, Japan
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] ポリマー1分子の直視:高分子鎖一本のイメージングと顕微機能解析2014

    • Author(s)
      篠原 健一
    • Organizer
      日本分析化学会 高分子分析研究懇談会、第373例会(夏期合宿)
    • Place of Presentation
      ラフォーレ倶楽部伊東温泉, 静岡県伊東市
    • Year and Date
      2014-07-04 – 2014-07-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ポリマー1分子の直視:キラルらせんπ共役高分子鎖一本のイメージングと動態解析

    • Author(s)
      篠原 健一、巻田 優
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      京都市
    • Related Report
      2013 Research-status Report
  • [Presentation] ポリマー1分子の直視:低密度ポリエチレン長鎖分岐構造の動態イメージング

    • Author(s)
      篠原 健一、柳澤 正弘、巻田 優、栗林 浩、笠原 達也
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      京都市
    • Related Report
      2013 Research-status Report
  • [Presentation] ポリマー1分子の直視:メンチル基を有するキラル置換フェニルアセチレンポリマーの1分子イメージング

    • Author(s)
      グレワール マンジット、巻田 優、篠原 健一
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      京都市
    • Related Report
      2013 Research-status Report
  • [Presentation] オリゴチオフェンユニットを側鎖に有するらせん状ポリイソシアニドの合成とキラル構造制御

    • Author(s)
      高木 遊学、井改 知幸、前田 勝浩、加納 重義、篠原 健一
    • Organizer
      高分子学会年次大会
    • Place of Presentation
      京都市
    • Related Report
      2013 Research-status Report
  • [Presentation] ポリマー1分子の直視:LDPE長鎖分岐の構造と動態の直接観測

    • Author(s)
      篠原 健一、柳澤 正弘、宮﨑 洋介、巻田 優
    • Organizer
      高分子学会高分子討論会
    • Place of Presentation
      金沢市
    • Related Report
      2013 Research-status Report
  • [Presentation] ポリマー1分子の直視:キラル高分子鎖の動態イメージングと熱ゆらぎ駆動型分子マシンの機能解析

    • Author(s)
      篠原 健一、巻田 優
    • Organizer
      高分子学会高分子討論会
    • Place of Presentation
      金沢市
    • Related Report
      2013 Research-status Report
  • [Presentation] ポリマー1分子の直視:キラルらせん高分子鎖が基板上で形成する構造体のイメージング

    • Author(s)
      グレワール マンジット、巻田 優、篠原 健一
    • Organizer
      高分子学会高分子討論会
    • Place of Presentation
      金沢市
    • Related Report
      2013 Research-status Report
  • [Presentation] オリゴチオフェンユニットを側鎖に有するらせん状ポリイソシアニドの合成とその応用

    • Author(s)
      高木 遊学、篠原 健一、井改 知幸、前田 勝浩、加納 重義
    • Organizer
      高分子学会高分子討論会
    • Place of Presentation
      金沢市
    • Related Report
      2013 Research-status Report
  • [Remarks] Polymer Chemistry :: JAIST 篠原健一研究室

    • URL

      http://www.jaist.ac.jp/ms/labs/shinohara/

    • Related Report
      2014 Annual Research Report
  • [Remarks] マテリアルサイエンス研究科の篠原准教授の論文が高分子学会会誌「高分子」の特集ページに掲載

    • URL

      http://www.jaist.ac.jp/news/update/2013/post-379.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 北陸先端科学技術大学院大学 篠原研究室

    • URL

      http://www.jaist.ac.jp/ms/labs/shinohara/

    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 高分子鎖の動態解析方法、高分子の製造方法、高分子 、合成高分子の製造方法及び合成高分子2013

    • Inventor(s)
      篠原 健一
    • Industrial Property Rights Holder
      国立大学法人北陸先端科学技術大学院大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-12-26
    • Related Report
      2013 Research-status Report
    • Overseas

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Published: 2014-07-25   Modified: 2019-07-29  

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