| Project/Area Number |
25620111
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Analytical chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
KUBO TAKUYA 京都大学, 工学(系)研究科(研究院), 准教授 (20374994)
|
|---|
| Project Period (FY) |
2013-04-01 – 2015-03-31
|
| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
|
|---|
| Keywords | クロマトグラフィー / ナノ炭素材料 / 表面化学 / フラーレン / 多環式芳香族類 / πスタッキング / HPLC / 炭素材料 |
|---|
| Outline of Final Research Achievements |
To develop a new separation medium modified with C60-fullerene and evaluate its retention properties, a specific agent, perfluorophenyl azide (PFPA) was employed for the interface for the immobilization of C60-fullerene. After the research period, a new capillary column, which was prepared with a silica monolith modified with high density C60-fllerenes, was successfully prepared, and the column showed the specific retentions based on the π stacking. Additionally, the column provided the unique spherical recognition due to the attached C60-fullerene.
|
