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Development of an edge emission device using organic semiconductors in solution and its application to photometric micro-flow analysis

Research Project

Project/Area Number 25620117
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Analytical chemistry
Research InstitutionKyushu University

Principal Investigator

IMATO Toshihiko  九州大学, 工学(系)研究科(研究院), 教授 (50117066)

Co-Investigator(Renkei-kenkyūsha) ISHIMATSU Ryoichi  九州大学, 大学院工学研究院, 助教 (90512781)
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords液体半導体 / 電気化学発光 / マイクロフロー分析
Outline of Final Research Achievements

Integrated microchips detecting practical analytes such as environmental pollutants and biological samples are very useful. Usually, the detecting system in the microchip is based on the change of absorbance or fluorescence intensity using a small LED as a light source. We expect that light-emitting materials in solution by applying voltage are very useful instead of using LEDs because it is possible to change excitation wavelength easily by injecting different photoluminescent materials to the light emitting device. Here, we studied possibility of using light-emitting solutions as light source for the detection system on microchips. As candidates for the light emitting solution, thermally activated delayed-fluorescent molecules with high quantum yield of photoluminescence, and Eu and Tb complexes with narrow photoluminescence spectra were employed, and the light emitting characteristics were investigated. Moreover, narrowing emission spectra by edge emission was investigated.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (13 results)

All 2015 2014 2013

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results) Presentation (7 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Photometric flow injection determination of phosphate on a PDMS microchip using an optical detection system assembled with an organic light emitting diode and an organic photodiode2015

    • Author(s)
      Rong Liu, Ryoichi Ishimatsu, Masayuki Yahiro, Chihaya Adachi, Koji Nakano, Toshihiko Imato
    • Journal Title

      Talanta

      Volume: 132 Pages: 96-105

    • DOI

      10.1016/j.talanta.2014.08.057

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fluorometric flow-immunoassay for alkylphenol polyethoxylates on a microchip containing a fluorescence detector comprised of an organic light emitting diode and an organic photodiode2015

    • Author(s)
      Rong Liu, Ryoichi Ishimatsu, Masayuki Yahiro, Chihaya Adachi, Koji Nakano, Toshihiko Imato
    • Journal Title

      Talanta

      Volume: 134 Pages: 37-47

    • DOI

      10.1016/j.talanta.2014.10.055

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrogenerated Chemiluminescence of Donor-Acceptor Molecules Displaying Thermally Activated Delayed Fluorescence2014

    • Author(s)
      R. Ishimatsu, S. Matsunami, T. Kasahara, J. Mizuno, T. Edura, C. Adachi, K. Nakano, T. Imato
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 53 Issue: 27 Pages: 6996-6996

    • DOI

      10.1002/anie.201402615

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Solvent Effect on Thermally Activated Delayed Fluorescence by 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene2013

    • Author(s)
      Ryoichi Ishimatsu, Shigeyuki Matsunami, Katsuyuki Shizu, Chihaya Adachi, Koji Nakano, Toshihiko Imato
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 117 Issue: 27 Pages: 5607-5612

    • DOI

      10.1021/jp404120s

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] An organic thin film photodiode as a portable photodetector for the detection of alkylphenol polyethoxylates by a flow fluorescence-immunoassay on magnetic microbeads in a microchannel2013

    • Author(s)
      Ryoichi Ishimatsu, Azusa Naruse, Rong Liu, Koji Nakano, Masayuki Yahiro, Chihaya Adachi, Toshihiko Imato
    • Journal Title

      Talanta

      Volume: 117 Pages: 139-145

    • DOI

      10.1016/j.talanta.2013.08.044

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Development of photometric and fluorometric detectors assembled with an organic light emitting diode and an organic thin film based photodiode and its application on flow analysis2014

    • Author(s)
      Rong Liu
    • Organizer
      2014 China-Japan-Korea Symposium on Analytical Chemistry
    • Place of Presentation
      中国・瀋陽
    • Year and Date
      2014-08-22 – 2014-08-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electrogenerated Chemiluminescence of Molecules Displaying Delayed Fluorescence2014

    • Author(s)
      Ryoichi Ishimatsu
    • Organizer
      International Conference on Electrochemical Sensors 2014
    • Place of Presentation
      ハンガリー・ブダペスト
    • Year and Date
      2014-06-15 – 2014-06-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有限要素法を用いたシミュレーションによる電気化学発光の解析2014

    • Author(s)
      石松亮一
    • Organizer
      第74 回分析化学討論会
    • Place of Presentation
      郡山市 日本大学工学部
    • Year and Date
      2014-05-24 – 2014-05-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 熱活性型遅延蛍光材料を用いた電気化学発光:フロー光源への応用の基礎検討2013

    • Author(s)
      石松 亮一, 松波 成行, 江面 知彦, 笠原 崇史, 水野 潤, 中野 幸二, 安達 千波矢, 今任 稔彦
    • Organizer
      日本分析化学会第76回分析化学討論会
    • Place of Presentation
      北海道大学函館キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 熱活性型遅延蛍光材料による電気化学発光を光源に用いるフロー蛍光分析法の開発2013

    • Author(s)
      石松亮一, 笠原崇史, 松波成行, 水野 潤, 江面知彦 , 安達千波矢, 中野幸二, 今任稔彦
    • Organizer
      日本分析化学会第 62 年会
    • Place of Presentation
      近畿大学東大阪キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Electrogenerated Chemiluminescence with Thermally Activated Delayed Fluorescent Materials and its Application to Fluorometric Detection as a Light Source2013

    • Author(s)
      Ryoichi Ishimatsu, Shigeyuki Matsunami, Chihaya Adachi, Koji Nakano, Toshihiko Imato
    • Organizer
      18 th International Conference on Flow Injection Analysis
    • Place of Presentation
      Porto, Portugal
    • Related Report
      2013 Research-status Report
  • [Presentation] Photometric Flow Injection Determination of Phosphate on a PDMS Microchip Equipped with an Optical System Assembled with an Organic Light Emitting Diode and an Organic Photodiode2013

    • Author(s)
      Rong Liu, Masayuki Yahiro, Chiyaya Adachi, Ryoichi Ishimatsu, Koji Nakano, Toshihiko Imato
    • Organizer
      The Twelfth Asian Conference on Analytical Sciences
    • Place of Presentation
      Fukuoka
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 発光素子2013

    • Inventor(s)
      石松亮一 松波成行 江面知彦 安達千波矢 今任稔彦  水野潤
    • Industrial Property Rights Holder
      石松亮一 松波成行 江面知彦 安達千波矢 今任稔彦  水野潤
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-186736
    • Filing Date
      2013-09-09
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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