Development and application of environmental-friendly technique for increasing the sensitivity of ICP atomic emission spectrometry
| Project/Area Number |
25620118
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Analytical chemistry
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| Research Institution | Fukui University of Technology |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 誘導結合プラズマ / ICP / ICP発光分光分析法 / ICP質量分析法 / 静電シールド / 高感度化 / 材料分析 / 環境分析 / ICP-AES / ICP-MS / スペクトル干渉 / ステンレス鋼 / ボルツマンプロット / バックグラウンド等価濃度 |
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| Outline of Final Research Achievements |
In order to increase the sensitivity of ICP atomic emission spectrometry, an electrostatic shield was applied. By grounding the shield and optimizing plasma operating parameters, background equivalent concentration (BEC) of several elements was improved approximately 4 to 10 times compared to that obtained with a conventional method. The close examinations of intensity distribution along a plasma radius and emission spectra showed that the improvement of BEC was found to be brought by remarkable decrease of background intensities. Electrostatic shields made of different materials were applied to ICP mass spectrometry and the effects of the materials were systematically investigated. As a result, SUS304 was found to be superior in sensitivity, durability and cost.
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Report
(3 results)
Research Products
(4 results)
