Development of New Electronic Materials Based on PAH-Transition Metal Hybrid Compounds
| Project/Area Number |
25620158
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic and hybrid materials
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| Research Institution | University of Tsukuba |
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Principal Investigator |
FUCHIBE Kohei 筑波大学, 数理物質系, 准教授 (10348493)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 多環式芳香族炭化水素 / 半導体 / フッ素 / プリンタブル / 触媒 / スタッキング / H-F相互作用 / フルオロアルケン / 有機半導体 / 環化反応 / パラジウム / インジウム / ジフルオロアルケン / ジフルオロアレン / 環化 |
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| Outline of Final Research Achievements |
Synthetic method for the regioselectively fluorinated polycyclic aromatic hydrocarbons (pinpoint-fluorinated PAHs) was developed. 1,1-Difluoroallenes and 1,1-difluoroalkenes were used as starting materials and the positions for the fluorine-introduction were perfectly controlled. The synthesized pinpoint-fluorinated PAHs were soluble in organic solvents and some pinpoint-fluorinated PAHs exhibited P-type semiconducting behavior. The pinpoint-fluorinated PAHs are a new category of organic semiconductors that can be used for printable organic electronic devices.
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Report
(3 results)
Research Products
(30 results)
