Research Project
Grant-in-Aid for Challenging Exploratory Research
We report the interesting thermal properties of the adamantane-based ionic liquids (ILs). The ion salts with steric molecules such as adamantane carboxylates and imidazolium cations were prepared. We found that assembly of ion pairs to the adamantane core can improve the thermal stability and lower melting temperatures. Finally, the thermally-stable ionic liquids can be obtained based on the steric core. The mechanism study on the thermal properties of synthesized ILs revealed that the tetrahedral-like distribution of ion pairs assisted by the steric core should be of essential for expressing characteristic thermal properties.
All 2014 2013 Other
All Journal Article (26 results) (of which Peer Reviewed: 26 results, Acknowledgement Compliant: 3 results) Presentation (8 results) (of which Invited: 8 results)
RSC Adv.
Volume: 4 Issue: 53 Pages: 28107-28110
10.1039/c4ra02575j
120005661548
J. Mater. Chem. A
Volume: 2 Issue: 3 Pages: 624-630
10.1039/c3ta14039c
Journal of Polymer Science Part A: Polymer Chemistry
Volume: 52 Issue: 18 Pages: 2588-2595
10.1002/pola.27274
120005661550
Org. Biomol. Chem.
Volume: 12 Issue: 33 Pages: 6500-6506
10.1039/c4ob01115e
120005661551
Macromolecules
Volume: (印刷中)(Early View) Issue: 7 Pages: 2316-2323
10.1021/ma5002047
Volume: (印刷中)(Early View) Issue: 7 Pages: 2268-2278
10.1021/ma500082e
Tetrahedron Lett.
Volume: 55 Issue: 9 Pages: 1635-1659
10.1016/j.tetlet.2014.01.092
Polym. J.
Volume: 46 Issue: 3 Pages: 195-199
10.1038/pj.2013.81
Volume: 3 Issue: 7 Pages: 2422-2427
10.1039/c2ra22683a
Synth. Met.
Volume: 180 Pages: 49-53
10.1016/j.synthmet.2013.07.030
J. Mater. Chem.
Volume: 1 Issue: 29 Pages: 4437-4444
10.1039/c3tc30276h
Org. Lett.
Volume: 15 Issue: 10 Pages: 2366-2369
10.1021/ol400730n
J. Polym. Sci. Part A: Polym. Chem.
Volume: 51 Issue: 17 Pages: 3583-3589
10.1002/pola.26757
Volume: 46 Issue: 8 Pages: 2969-2975
10.1021/ma400368e
Colloids Surf., A
Volume: 428 Pages: 65-69
10.1016/j.colsurfa.2013.03.048
Bioorg. Med. Chem.
Volume: 21 Issue: 10 Pages: 2678-2681
10.1016/j.bmc.2013.03.029
Volume: 46 Issue: 7 Pages: 2599-2605
10.1021/ma400015d
J. Am. Chem. Soc.
Volume: 135 Issue: 11 Pages: 4211-4214
10.1021/ja400287y
Polymer Chemistry
Volume: (印刷中) Issue: 20 Pages: 5237-5242
10.1039/c3py00215b
Volume: 21 Issue: 10 Pages: 2715-2719
10.1016/j.bmc.2013.03.050
Cheaistry - A European Journal
Volume: 19 Issue: 14 Pages: 4506-4512
10.1002/chem.201203703
Journal of Polyimer Science, Part A : Polymer Chemistry
Volume: 51 Issue: 8 Pages: 1726-1733
10.1002/pola.26547
Volume: 163 Issue: 23 Pages: 13-18
10.1002/pola.23684
Compos. Interface.
Volume: 20 Issue: 1 Pages: 27-32
10.1080/15685543.2013.762891
120005466677
Volume: 20 Issue: 9 Pages: 557-564
10.1080/15685543.2012.762862
Bioorg. Med. Chem. Lett.
Volume: 23 Issue: 1 Pages: 281-286
10.1016/j.bmcl.2012.10.105