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Development of auto-degradable hybrids and application for recycling technology

Research Project

Project/Area Number 25620162
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic and hybrid materials
Research InstitutionKyoto University

Principal Investigator

CHUJO Yoshiki  京都大学, 工学(系)研究科(研究院), 教授 (70144128)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsハイブリッド材料 / ハイブリッド
Outline of Final Research Achievements

The photo-triggered molecular release from the organic-inorganic polymer hybrids is presented in this manuscript. Initially, the preparation of the auto-degradable polymer is explained with the photo-cleavable group at the end of the polymer main-chain. The silica-based dye-loaded hybrids containing these polymers were fabricated. It was found that by UV irradiation, the end capping was removed, and then the auto-degradation occurs through the polymer main-chain. Finally, the molecular release of the loaded dyes was accomplished in various media by the UV irradiation. In particular, it was shown that both of hydrophobic and hydrophilic dyes can be applied in this system.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (13 results)

All 2014 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results) Presentation (6 results) (of which Invited: 6 results)

  • [Journal Article] Adamantane Ionic Liquids2014

    • Author(s)
      Tanaka, K.; Hiraoka, T.; Ishiguro, F.; Jeon, J.-H.; Chujo, Y.
    • Journal Title

      RSC Adv.

      Volume: 4 Issue: 53 Pages: 28107-28110

    • DOI

      10.1039/c4ra02575j

    • NAID

      120005661548

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Sulfonic Acid-Containing POSS and Its Filler Effects for Enhancing Thermal Stabilities and Lowering Melting Temperatures of Ionic Liquids2014

    • Author(s)
      Jeon, J.-H.; Tanaka, K.; Chujo, Y.
    • Journal Title

      J. Mater. Chem. A

      Volume: 2 Issue: 3 Pages: 624-630

    • DOI

      10.1039/c3ta14039c

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transformation of Sulfur to Organic–inorganic Hybrids Employed by Networks and Their Application for the Modulation of Refractive Indices2014

    • Author(s)
      Tanaka, K.; Yamane, H.; Mitamura, K.; Watase, S.; Matsukawa, K.; Chujo, Y.
    • Journal Title

      Journal of Polymer Science Part A: Polymer Chemistry

      Volume: 52 Issue: 18 Pages: 2588-2595

    • DOI

      10.1002/pola.27274

    • NAID

      120005661550

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] л-Conjugated Polymers Composed of BODIPY or Aza-BODIPY Derivatives Exhibiting High Electron Mobility and Low Threshold Voltage in Electron-Only Devices2014

    • Author(s)
      Yoshii, R. ; Yamane, H. ; Nagai, A. ; Tanaka, K. ; Taka, H. ; Kita, H. ; Chujo, Y.
    • Journal Title

      Macromolecules

      Volume: (印刷中)(Early View) Issue: 7 Pages: 2316-2323

    • DOI

      10.1021/ma5002047

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Conjugated Polymers Based on Tautomeric Units : Regulation of Main-Chain Conjugation and Expression of Aggregation Induced Emission Property via Boron-Complexation2014

    • Author(s)
      Yoshii, R. ; Tanaka, K. ; Chujo, Y.
    • Journal Title

      Macromolecules

      Volume: (印刷中)(Early View) Issue: 7 Pages: 2268-2278

    • DOI

      10.1021/ma500082e

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Production of Three Radical Cations from a Single Photon Using a Photo Acid Generator2014

    • Author(s)
      Tanaka, K.; Ohashi, W.; Okada, H.; Chujo, Y.
    • Journal Title

      Tetrahedron Lett.

      Volume: 55 Issue: 9 Pages: 1635-1659

    • DOI

      10.1016/j.tetlet.2014.01.092

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Dye Dispersibility in Silica Hybrids through Local Heating Induced by the Imidazolium Group under Microwave Irradiation2014

    • Author(s)
      Kajiwara, Y.; Tanaka, K.; Chujo, Y.
    • Journal Title

      Polym. J.

      Volume: 46 Issue: 3 Pages: 195-199

    • DOI

      10.1038/pj.2013.81

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Unique Optical Materials Based on POSS2014

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      Silicon-Containing Polymers and Composites
    • Place of Presentation
      San Diego, U.S.A.
    • Year and Date
      2014-12-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Modulation of Thermal Properties of Ionic Liquids Based on POSS2014

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      Asian Chemical Conference
    • Place of Presentation
      ハノイ、ベトナム
    • Year and Date
      2014-11-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Unique Thermal Properties of POSS Ionic Materials2014

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      Asian Chemical Conference
    • Place of Presentation
      クアラルンプール、マレーシア
    • Year and Date
      2014-11-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Development of POSS-based Functional Materials

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      KIPS-ESPCI 2013 Meeting
    • Place of Presentation
      フランス、パリ
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Design of Advanced Materials Based on POSS

    • Author(s)
      Kazuo Tanaka, Yoshiki Chujo
    • Organizer
      BIT’s 3rd Annual World Congress of Nano Science & Technology-2013
    • Place of Presentation
      中国、西安
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] POSSネットワークポリマーを基盤とした光駆動型人工酵素の開発

    • Author(s)
      田中一生、ジョン=ジョンファン、中條善樹
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2014-07-25   Modified: 2019-07-29  

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